全文获取类型
收费全文 | 12997篇 |
免费 | 2795篇 |
国内免费 | 2670篇 |
专业分类
化学 | 9755篇 |
晶体学 | 331篇 |
力学 | 840篇 |
综合类 | 197篇 |
数学 | 1491篇 |
物理学 | 5848篇 |
出版年
2024年 | 60篇 |
2023年 | 351篇 |
2022年 | 629篇 |
2021年 | 719篇 |
2020年 | 702篇 |
2019年 | 677篇 |
2018年 | 585篇 |
2017年 | 585篇 |
2016年 | 686篇 |
2015年 | 838篇 |
2014年 | 933篇 |
2013年 | 1161篇 |
2012年 | 1272篇 |
2011年 | 1232篇 |
2010年 | 933篇 |
2009年 | 990篇 |
2008年 | 1054篇 |
2007年 | 836篇 |
2006年 | 815篇 |
2005年 | 647篇 |
2004年 | 477篇 |
2003年 | 336篇 |
2002年 | 331篇 |
2001年 | 290篇 |
2000年 | 286篇 |
1999年 | 200篇 |
1998年 | 146篇 |
1997年 | 99篇 |
1996年 | 89篇 |
1995年 | 69篇 |
1994年 | 64篇 |
1993年 | 61篇 |
1992年 | 52篇 |
1991年 | 30篇 |
1990年 | 38篇 |
1989年 | 28篇 |
1988年 | 27篇 |
1987年 | 24篇 |
1986年 | 22篇 |
1985年 | 19篇 |
1984年 | 17篇 |
1983年 | 14篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1971年 | 2篇 |
1966年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
81.
New low-lying isomeric structures of Ar(n)HF clusters are reported for n=6-13. They were determined using simulated annealing and evolutionary programming, for pairwise additive intermolecular potential energy surfaces. New global minima were found for the clusters with n=7, 10, 11. The new lowest-energy structure of Ar(7)HF and several new local minima for n=6, 7 clusters have the HF bound on a threefold surface site, consistent with the recent spectroscopic data for Ar(n)HF clusters in helium nanodroplets. A new type of low-energy local minima were determined for n=9-13 clusters. 相似文献
82.
LI Chun-Bao Chen Yi LI Song-Lin ZHANG Wen-Qin CUI Yi JI Xiu-Jie ZHENG Peng-Wu 《结构化学》2002,21(5):470-472
1 INTRODUCTION (9S,13R,14S)-7,8-Didehydro-3,7-dimethoxy-4-hydroxy-17-methylmorphinan-6-one I is an impor- tant natural product that was used to ease pain, decrease blood pressure and diminish inflammation. In order to study the stereochemistry of the reduction of I with potassium boronhydride, the crystal structure of the title compound II was determined by X-ray diffraction method. 2 EXPERIMENTAL 2. 1 Instrument The melting point was measured on a Yanagimoto MP-500 apparatus… 相似文献
83.
84.
The precise location of C C bonds in bioactive molecules is critical for a deep understanding of the relationship between their structures and biological roles. However, the traditional ultraviolet light-based approaches exhibited great limitations. Here, we discovered a new type of visible-light activated [2 + 2] cycloaddition of carbonyl with C C bonds. We found that carbonyl in anthraquinone showed great reactivities towards C C bonds in lipids to form oxetanes under the irradiation of visible-light. Combined with tandem mass spectrometry, this site-specific dissociation of oxetane enabled precisely locating the C C bonds in various kinds of monounsaturated and polyunsaturated lipids. The proof-of-concept applicability of this new type of [2 + 2] photocycloaddition was validated in the global identification of unsaturated lipids in a complex human serum sample. 86 monounsaturated and polyunsaturated lipids were identified with definitive positions of C C bonds, including phospholipids and fatty acids even with up to 6 C C bonds. This study provides new insights into both the photocycloaddition reactions and the structural lipidomics.A new visible-light activated [2 + 2] cycloaddition reaction was discovered and enabled pinpointing carbon–carbon double bonds in lipids. 相似文献
85.
Redl FX Black CT Papaefthymiou GC Sandstrom RL Yin M Zeng H Murray CB O'Brien SP 《Journal of the American Chemical Society》2004,126(44):14583-14599
We have investigated the structural, magnetic, and electronic properties of nonstoichiometric iron oxide nanocrystals prepared by decomposition of iron(II) and iron(0) precursors in the presence of organic solvents and capping groups. The highly uniform, crystalline, and monodisperse nanocrystals that were produced enabled a full structural and compositional survey by electron microscopy and X-ray diffraction. The complex and metastable behavior of nonstoichiometric iron oxide (wüstite) at the nanoscale was studied by a combination of Mossbauer spectroscopy and magnetic characterization. Deposition from hydrocarbon solvents with subsequent self-assembly of iron oxide nanocrystals into superlattices allowed the preparation of continuous thin films suitable for electronic transport measurements. 相似文献
86.
本文首先运用考虑非期望产出的SBM-SupSBM模型估计我国各省市绿色技术创新效率并进行分类:稳定上升类、平稳类、大幅度波动类以及下降类。之后从企业内部和外部两方面对绿色技术创新效率提升的影响因素提出假设,着重考虑大幅度波动类别省份的效率提升。运用面板数据模型各影响因素进行验证,结论显示:企业规模对绿色技术创新效率波动较大的省份起到显著的抑制作用,环境规制和技术进步对绿色技术创新效率波动较大的省份作用不明显。针对分析结果,提出结论:在提升绿色技术创新效率的过程中,应注重企业规模和技术进步的协同作用,以及技术的开放程度。 相似文献
87.
88.
Hao Yu 《Probability Theory and Related Fields》1993,95(3):357-370
Summary With the help of an extension of Hoeffding's equality, we develop a way for estimating the covariance structures for empirical functions of associated sequences in terms of covariances of the original random variables. Based on these estimations, a Glivenko-Cantelli lemma for associated sequences and weak convergence for empirical processes of stationary associated sequences are obtained, all under the conditions on covariances of the original random variables.This research has been supported partially by a scholarship from the Faculty of Graduate Studies and Research of Carleton University, Ottawa, and by an NSERC Canada grant of M. Csörg 相似文献
89.
90.