Design criteria for tetradentate phenanthroline-derived heterocyclic ligands to separate Am(Ⅲ) from Eu(Ⅲ)

To design novel phenanthroline-derived soft ligands for selectively separating minor actinides from lanthanides, four tetradentate phenanthroline-derived heterocyclic ligands(BTPhen, BPyPhen, BPzPhen, and BBizPhen) were constructed and their complexation behaviors with Am(ⅡI) and Eu(ⅡI) were systematically investigated by density functional theory(DFT) coupled with relativistic small-core pseudopotential. In all the 1:1-type species, the metal ion is in the center of the cavity and coordinates with two nitrogen atoms(N1 and N1′) of the phenanthroline skeleton and the other two nitrogen atoms(N2 and N2′) of the auxiliary groups. The bond lengths of Am–N are comparable to or even shorter than those of Eu–N bonds because the ionic radii of Am(ⅡI) are larger than those of Eu(ⅡI). Additionally, the negative ΔΔGAm/Eu value for the reaction of [M(H2O)4-(NO3)3] + L → ML(NO3)3 + 4H2 O indicates that the complexation reaction of Am(ⅡI) is more energetically favorable than that of Eu(ⅡI); this can be considered as an important design criterion to screen phenanthroline-derived ligands for MA(ⅡI) extraction. According to this criterion, the selectivity of tetradentate phenanthroline-derived ligands for separating Am(ⅡI) over Eu(ⅡI) follows the order of BTPhen BBizPhen BPyPhen BPzPhen.     

磁致伸缩-压电联合激励凹筒型发射换能器

设计制作了一种新型磁致伸缩-压电联合激励凹筒型发射换能器,采用稀土超磁致伸缩材料Terfenol-D与PZT压电陶瓷作为联合激励元件,模拟计算与实测结果均表明,与采用单一振子激励的凹筒型发射换能器相比,此种新型换能器在保持尺寸小、频率低等优点的同时,显著拓宽了工作频带并提高了辐射声功率.换能器外型尺寸为φ88 mm×316 mm,水中谐振频率1.30 kHz,-3 dB带通Q值1.43,谐振频率下发射电压响应级135.1 dB.     

Robust tracking for MIMO nonlinear time-dependent mismatched uncertain systems: non-adaptive versus adaptive control

This paper considers the problem of robust output-tracking controlfor multi-input multi-output (MIMO) nonlinear systems in thepresence of mismatched time-dependent uncertainties. It firstgeneralizes the stable combined-variable perturbation method(SCVPM) which was proposed by Li et al. (1996) to derive a newrobust controller and its adaptive version for MIMO systemsto track a desired trajectory. It is shown that both controllersnot only stabilize the closed-loop systems but also guaranteethat the tracking errors remain in an O() neighbourhood of theorgin, where is a small design parameter of the controller.Moreover, the adaptive robust controller is only based on thenominal system, and no a priori data on the uncertainties areneeded. Therefore, it is more feasibly implemented than thenon-adaptive controller.     

氚核磁共振波谱在氚标记甾族化合物制备中的应用

本文介绍了十一种氚化甾族化合物的氚核磁共振谱。我们依照英国放化中心和英国萨里大学报道数据,(甾体骨架上的CH及CH_2各位置的谱线归属,应用了定位标记化合物作为对照)归属了其氚在化合物中标记的位置,根据其积分曲线定出了各位氚的相对百分含量。同时图谱中又提供了立体构型的信息,为氚化甾族化合物制备过程中,催化剂的选择,实验条件的控制及反应机理等研究提供了理论依据。     

Copper oxide nanoarray based on the substrate of Cu applied for the chemical sensor of hydrazine detection

This communication reports on a novel amperometric hydrazine sensor of CuO nanoarray based on a Cu substrate. Copper oxide nanoarray was directly grown on Cu substrates using a one-step facile hydrothermal method and was characterized using scanning electron microscopy and X-ray powder diffraction. The electrochemical study has shown that the CuO nanoarray exhibits higher catalytic effect on the hydrazine than the normal CuO nanoparticles. This may be attributed to the special structure of the nanomaterials esp. the substrate of the electric Cu. And the amperometric response showed that the CuO nanoarray modified glassy carbon electrode has a low detection and a high sensitivity for hydrazine.     

Optimum design and sensitivity analysis of piezoelectric truss structures

This paper is concerned with the optimum design and sensitivity analysis methods of piezoelectric intelligent trusses on the structural stiffness and free-vibration frequency. On the basis of the finite element method and taking into account the mechanical-electric coupling effect under electric load and mechanical load, the computational formula of sensitivities of structural displacement and free-vibration frequency with respect to the size and shape design variables are proposed. A new kind of design variable of the electric voltage and the calculating method of displacement sensitivity with respect to the electric voltage variable is presented. The new method for structural deformation control by optimizing the voltages of piezoelectric active bars is given. The numerical methods of optimum design and sensitivity analysis for piezoelectric truss structures are implemented in JIFEX software. Numerical examples demonstrate the effectiveness of the methods and the program. Project supported by the Special Funds for National Key Basic Research of China (No. G1999032805) and the Foundation for University Key Teachers by the Ministry of Education of China.     

Boltzmann-Poisson系统解的动量及能量估计

In this paper, the properties of the solutions of Boltzmann-Poisson system in three dimensions are considered. The estimates of the energies (the kinetic and the potential energies) and the γ-th moments with γ∈[2,3) are obtained. The latter answers an open problem.     

多维随机变量的线性相关性

本文研究了n维随机变量分量间的线性相关性,给出了衡量线性相关性程度的量以及具有(在概率1意义下)严格线性关系的充分必要条件.     

一类带输入时滞的线性时滞系统的新型自适应控制

针对一类带输入时滞且状态时滞常数未知的线性时滞系统,基于LMI方法,采用一种Lyapunov-Krasovskii函数和新型带记忆的状态反馈控制,突破以往自适应控制对估计值的大小限制,研究了一种新型的对该类系统未知状态时滞常数进行自适应控制的控制器设计问题,并且通过带记忆控制器中的常数的适当选取使得带记忆控制始终能反映未知时滞,仿真例子显示了该种方法的有效性.