Rheological determination of polymer-filler affinity

An experimental method to quantify the affinity of polymers for certain fillers is presented. In this method, the relative viscosity of filled and unfilled polymer systems as determined by capillary rheometry is taken as a measure of the thickness of the adsorbed layer of polymeric material on the filler surface and hence of the affinity of the polymer for the filler. A styrene-butadienestyrene block copolymer is thus found to have a higher affinity for talc than do polypropylene and an ethylene-propylene-diene terpolymer.     

Vibrations and stability of cylindrical panels with elliptical cross section

Summary The free vibrations of cylindrical panels with elliptical cross section subjected to an initial stress state are investigated. The buckling problem of the panel under the stress state considered is studied as special case of the free vibration problem.

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Übersicht Es wird die freie Schwingung offener Zylinderschalen mit elliptischem Querschnitt behandelt, die sich in einem Anfangspannungszustand befinden. Das Schalenbeulproblem wird als Spezialfall der freien Schwingung untersucht.

     

Relation between steady shear flow and dynamic rheology

Summary The relationships between steady shear flow and dynamic rheology are investigated at relatively high shear rates and frequencies. A useful empirical relationship in this region predicts that the magnitude of the complex dynamic viscosity | ^*| should be compared with the shear viscosity at equal values of frequency and shear rate (Cox-Merz-rule). Polystyrenes (PS) and Polyacrylamides (PAAm) have been investigated over a wide range of concentration and molecular weight. Only in case of PAAm/H₂O solutions we have found that the results do not coincide with Cox-Merz-rule. As far as we know this is the first time that deviations from Cox-Merz-rule were observed in a homogeneous system. A molecular interpretation is given.

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Zusammenfassung Die Beziehung zwischen der Scherviskosität und der komplexen (dynamischen) Viskosität bei relativ hohen Schergeschwindigkeiten und Frequenzen wurde untersucht. Eine geeignete empirische Beziehung in diesem Bereich sagt aus, daß der Betrag der komplexen Viskosität | ^*| mit der Scherviskosität bei gleichen Werten von Frequenz und Schergeschwindigkeit vergleichbar ist (Cox-Merz-Regel). Polystyrole (PS) and Polyacrylamide (PAAm) wurden über einen weiten Bereich der Konzentration und des Molekulargewichts untersucht. Nur im Fall der PAAm/H₂O-Lösungen wurden Abweichungen von der Cox-Merz-Regel gefunden. Soweit uns bekannt, ist es das erste Mal, daß Abweichungen von der Cox-Merz-Regel in einem homogenen System gefunden wurden. Eine molekulare Erklärung wird gegeben.

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Presented at the IUPAC 26^th International Symposium on Macromolecules, Mainz, September 17–21, 1979.

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With 4 figures and 1 table     

Single-phase heat transfer characteristics of concentric-tube thermosyphon

An experimental study has been conducted to evaluate the influence of the presence of inner tube and the Rayleigh number on free convective heat transfer in an open thermosyphon. Water and fluorocarbon R-11 refrigerant as the working fluids were utilized. Heat transfer results using the concentric geometry were given for modified Rayleigh number from 3.6×10² to 4.1 × 10⁷ which encompasses the regions of similarity, impeded and boundary layer flow conditions. It was found that the presence of the inner tube markedly increases the overall heat transfer coefficient of open thermosyphon by a factor as large as 2 to 10 in the turbulent impeded and boundary layer regimes.

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Wärmeübergang in einem Thermosyphon aus konzentrischem Rohr bei einphasiger Strömung

Zusammenfassung Es wurde experimentell untersucht, wie der Einbau eines Innenrohres und wie die Rayleigh-Zahl auf die freie Konvektion in einem offenen Thermosyphon, gefüllt mit Wasser oder dem Kältemittel R 11, einwirkt. Der untersuchte Bereich bei konzentrischer Geometrie lag bei modifizierten Rayleigh-Zahlen von 3,6 · 10² bis 4,1 · 10⁷ und umfaßte damit die Regionen der Grenzschichtströmung. Es ergab sich, daß der Einbau eines Innenrohres den Gesamtwärmeübergang eines offenen Thermosyphons im Bereich der behinderten turbulenten Strömungen und Grenzschichtströmungen um den Faktor 2 bis 10 steigert.

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Nomenclature a inner radius of heated tube, D/2 - A_in sectional space area of inner tube, d _i ² /4 - A_an sectional space area of annulus, (D^2-d ₀ ² )/4 - C_p specific heat - d_i inner diameter of inner tube - d₀ outer diameter of inner tube - D inner diameter of heated tube - g gravitational acceleration - L tube length of thermosyphon - Nu_a Nusselt number based on inner radius of heated tube - Nu_r Nusselt number based on equivalent heattransfer radius - Nu_x Nusselt number, defined in equation (1) - Pr Prandtl number, defined in equation (3) - q heat flux from heated tube - r equivalent heat-transfer radius, defined in equation (4) - Ra_a modified Rayleigh number based on inner radius of heated tube - Ra_r modified Rayleigh number based on equivalent heat-transfer radius - Ra_x modified Rayleigh number, defined in equation (2) - T_e temperature of entrance-fluid - T_w temperature of heated surface - T temperature difference between heated wall and entrance-fluid, T_w-T_e Greek Symbols coefficient of volumetric expansion - thermal diffusivity - thermal conductivity - viscosity - kinematic viscosity     

Effects of the interaction between radiation and a disintegrating vitreous material

This article considers the disintegration of a vitreous semitransparent material at the critical point in a stream of radiating gas. A study is made of the effect on the rate of disintegration of the indeterminacy of the effect of interaction between the radiation and the gaseous disintegration products and of the spectral distribution of the density of the radiation flux of the gas with respect to the semitransparancy of the material. An analysis of the error of the gray approximation with calculation of the disintegration of materials with a semitransparency window is also given.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 133–137, September–October, 1978.     

Differentiation along arbitrary orientations

A prevalent problem of mechanics is the differentiation of experimental information with respect to various directions, including the determination of cross derivatives. Simple methods for evaluating such derivatives along straight and curved directions are described. The concepts are demoinstrated at boundary and internal locations of in-plane and transversely loaded plates.     

Contact Stress Distribution Under a Rigid Cylinder Rolling Over a Prestressed Strip

A nonsymmetric quasistationary problem for a strip with initial stresses is solved under the linearized theory of elasticity for harmonic and Bartenev–Khazanovich potentials. The Hankel integral transform is used to solve the differential equations that describe the stress–strain state of the strip. The dependences of the normal and tangential stresses and stress intensity factors on the elongation are plotted     

Electroelastic analysis for a piezoelectric layer with surface electrodes

An electroelastic analysis of a transverse isotropic piezoelectric layer with surface electrodes is made. The piezoelectric layer is infinite long along the poling direction, and the top surface is perfectly bonded to a rigid electrode. The problem is solved via the conformal mapping technique for two cases of elastic boundary conditions on the bottom surface with two spaced electrodes, and the distribution of the electrostatic field in the entire piezoelectric layer is determined in an explicit analytic form, respectively. It is found that for the bottom surface electrodes with vanishing stiffness, the induced strain is singular, but no stress. Instead, for the bottom electrodes with stiffness as infinity, the induced stress is singular, but no strain.     

Stability of the Sliding Mode in Nonstationary Automatic-Control Systems with Variable Structure

The paper addresses the stability of the sliding mode in nonstationary automatic-control systems of variable structure. The parameters of dynamic states are assumed to vary arbitrarily and continuously within a given bounded domain. The existence and stability conditions for the sliding mode on the switching hyperplane are established. They define nonstationary sets that contain phase velocity vectors directed away from the sliding hyperplane. The sets do not have common points with the switching hyperplane, except for the origin, for the known extreme values of the discontinuous coefficients of logical controls. This is the essence of the necessary and sufficient conditions for the stable sliding mode of the automatic-control system. The general results are used to analyze the stability conditions for the sliding mode in a nonstationary automatic-control system with a variable structure of the third order