Epoxidation of cyclohexene on modified Ti-containing mesoporous MCM-41

Ti-MCM-41, B-Ti-MCM-41 and Ti-grafted MCM-41 were synthesized, characterized and studied in the epoxidation of cyclohexene. The synthetic methods and the effect of water in the oxidant are discussed.     

ADSORPTION OF SULFOXIDES ON SOLID FROM AQUEOUS SOLUTIONS Ⅲ.THE ADSORPTION ON CARBON BLACK

The adsorption of decylmethylsulfoxide (DEMS) onto carbon black and the effects of temperature, salt (NaCl) and acid (HCl) have been measured.Typical two plateaux type adsorption isotherms were obtained. Applying the two step model of surfactant adsorption on solid/liquld interface and the general adsorption isotherm equation[9]the experimental results were interpreted qualitatively and quantitatively.     

On the stability of the polaron in one dimensional disordered systems

A one-dimensional disordered system of electrons described by a tight binding model interacting with vibrational degrees of freedom (in harmonic approximation) is considered. A stable configuration is determined by a numerical minimization of the total energy which is based on the adiabatic approximation. The behaviour of the electron density (charge density wave) and the density of states is analysed. The localization properties are investigated as well. In contrast to the corresponding disordered system with vanishing electron-phonon coupling the present model has an energy gap. The formation of the gap and the polaron band is shown to be quite different for both onsite and intersite types of coupling terms. For large disorder, the lattice distortion and the gap disappear if only the vibrational contribution to the intersite coupling is important. They increase, however, if only the vibrational contribution to the site energies is taken into account. In both cases the localization length decreases upon increasing the electron-phonon coupling energy. The results are discussed with respect to low dimensional organic materials and amorphous semiconductors.     

Delay Model for a Cycling Transport Through Porous Medium

A solute transport through a porous medium is examined provided that the fluid leaving the porous sample returns back in a continuous way. The porous medium is thus included into a closed hydrodynamic circuit. This cycling process is suggested as an experimental tool to determine porous medium parameters describing transport. In the present paper the mathematical theory of this method is developed. For the advective type of transport with solute retention and degradation in porous medium, the system of transport equations in a closed circuit is transformed to a delay differential equation. The exact analytical solution to this equation is obtained. The solute concentration manifests both the oscillatory and monotonous behaviors depending on system parameters. The number of oscillation splashes is shown to be always finite. The maximum/minimum points are determined as solutions of a polynomial equation whose degree depends on the unknown solution itself. The cyclic methods to determine porous medium parameters as porosity and retention rate are developed.     

Singular nature of nonlinear macroscale effects in high-rate flow through porous mediaNature singulière des effets macroscopiques non linéaires dans un écoulement à hautes vitesses en milieux poreux

The quadratic law of laminar flow through porous media at high Reynolds numbers, which is well confirmed by the multiple experimental data, is shown to give rise to three fundamental paradoxes. All them can be resolved by assuming the singular structure of flow. The singularity is produced by the formation of jet brunches which invade the stagnant zones and sharply loss their kinetic energy. The numerical simulation confirms this effect. To cite this article: M. Panfilov et al., C. R. Mecanique 331 (2003).     

Influence of the heterogeneity of the solutions on the parameters of miscible displacement in saturated porous medium

The aim of this study is the investigation of the effects of density and viscosity contrasts on miscible displacements when the regime is stable. It has been possible to quantify these effects by using an empirical model which takes into account both the physical properties of the liquids and the hydrodynamic parameters in different configurations of a miscible displacement involving distilled water and a calcium chloride solution. The introduction of a method for measuring electrical conductivities within the porous medium itself (without disturbing the flow) has enabled us to monitor the change in the mixing zone throughout the entire length of the flow path. A stability criterion based on hydrodynamic parameters has been established that depends on two dimensionless numbers.     

Coupled Groundwater Flow and Transport in Porous Media. A Conservative or Non-conservative Form?

A new formulation for the modeling of density coupled flow and transport in porous media is presented. This formulation is based on the development of the mass balance equation by using the conservative form. The system of equations obtained by coupling the flow and transport equations using a state equation is solved by a combination of the mixed hybrid finite element method (MHFEM) and the discontinuous finite element method (DFEM). The former is applied in order to solve the flow equation and the dispersive part of the transport equation, whilst the latter is used to solve the advective part of the transport equation. Although the advantages of the MHFEM are known (efficiency calculation of velocity field and continuity of fluxes from one element to an adjacent one), its application in a classical development form (volumetric fluxes as unknowns) leads to the non-conservative version of the mass balance equation. The associated matrix of the system of equations obtained by hybridization is positive definite but non-symmetrical. By using a new approach (mass fluxes as unknowns) the conservative form of the continuity equation is preserved and the associated matrix of the system of equations obtained by hybridization becomes symmetrical. When applied to Elder's problem involving a strong density contrast, this new approach, with a lower calculation cost, leads to similar or identical results to those found in the specialized literature. The comparison between the conservative and non-conservative formulations solved with the same MHFEM and DFEM combination emphasizes the rigor and the pertinence of this new approach. Furthermore, we show the existence of a limit refinement defining the stability of the numerical solution for Elder's problem.