Weak itinerant magnetism as inhibited superconductivity

Thep-state pairing idea proposed recently to explain the ferromagnetism of ZrZn₂ is described in more detail, and the underlying soft-mode hypothesis is examined in relation with experiments, in particular the discovery of antiferromagnetism in TiBe₂. The key result, namely an electron-phonon contribution to the Stoner factor given essentially by the mass enhancement factor, is used to explain the behaviour of the Curie pointT _m and to predict an isotope effect.p-state superconductivity with a transition temperature determined by is predicted in TiBe₂ and, above the critical pressure whereT _m =0, also in ZrZn₂.Work in La Jolla supported by NSF/DMR 77-08469.     

On the Fourier transformation on spaces of (p,q)-multipliers

LetG denote a locally compact abelian topological group. The aim of the present paper is to prove an “intermediate” result between two well-known results ofL. Hörmander andG. I. Gaudry concerning the structure of the spaces ?_G?μ?t ^p,q (G).     

垃圾气化分析及其对中国实现碳中和与无废城市建设的贡献

气化是实现化学利用碳资源(尤其是煤)生产化学品和燃料的关键工艺.目前,全球拥有超过272套气化装置,主要应用于煤化工,尤其在中国.由于在一个化工厂通过技术集成达到工业规模的集中生产可实现减少二氧化碳排放并促进碳密集型行业的循环经济,如废物管理、化学和交通行业,因此,近年来全球对垃圾气化的兴趣日益浓厚,尤其是那些在煤气化...     

Topochemical Reactions in Langmuir-Blodgett Multilayers

Abstract

The topochemical polymerization of diacetylenes and.the dimerization of cinnamic acid derivatives have been studied in Langmuir-Blodgett-multilayers. The resulting polymer films are of controlled thickness and morphology and exhibit excellent stability. Structure, morphology and phase changes occuring in monomer and polymer films have been investigated using spectroscopic methods, electron and x-ray diffraction. Possible applications of the polymer films are discussed.     

Angular Benzoperylenetetracarboxylic Bisimides

Benzoperylene derivatives with two angularly attached dicarboxylic imide rings, which were prepared by the Diels–Alder‐Reaction, exhibit strong fluorescence and their free peri positions allow either control of the UV/Vis spectra through their substituents or form anchor positions for the attachment of functional units. The angular chromophore 3 may be used both for fluorescent labeling such as for primary amines or enzymes or as building blocks for more complex assemblies where they may act as energy donors for FRET or electron acceptors in PET such as for photovoltaic solar cells.     

A DIRECT ROUTE TO ORTHO-HYDROXY PHENYL DITHIOPHOSPHINIC ACIDS

Abstract

Through a direct and selective deprotection of 1 (R=methyl) with boron tribromide substituted o-hydroxy-dithiophosphinic acid 1 was prepared under mild conditions in excellent yield.