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61.
G. Märkl H. Baier P. Hofmeister F. Kees C. Soper 《Journal of organometallic chemistry》1979,173(2):125-169
The 1(Z),4(Z)-1,5-dilithium-3R-3-methoxypenta-1,4-dienes, available by cleavage of 1,1-di-n-butyl-4R-4-methoxy-1-stannacyclohexane-2,5-dienes with n-BuLi in ether, react with dichlorosilanes (R′R″ SiCl2; R′, R″ = H, alkyl, aryl, alkoxy) to give 1R′,1R″,4R-4-methoxy-1-silacyclohexa-2,5-dienes.Claevage of the ether group with BBr3, BCl3 or PCl3 gives 6-chloro(bromo)-1-silacyclohexa-2,4-dienes or 1,5-dichloro-1-silacyclohexane-2,4-dienes, respectively.Ether cleavage of 4R-4-methoxy-1-silacyclohexa-2,5-dienes with sodium results in the formation of 4R-1-silacyclohexadienyl anions, which can be hydrolyzed to give 1-silacyclohexa-2,4-dienes which reach further with trichloromethylsilane to give 6-trimethylsilyl-1-silacyclohexa-2,4-dienes.Phase transfer-catalyzed conversion of 1-chlorosilacyclohexadienes into the fluoro derivatives as well as further substitution reactions of 1-chlorosilacyclohexadienes are described.The 1H NMR, 13C NMR, IR and mass spectra of the silacyclohexadienes are discussed. 相似文献
62.
A Sodium Oxocobaltate(II) Sulfate: Na8[CoO3][SO4]2 Na8[CoO3][SO4]2 has been obtained from a redox reaction between cobalt metal and CdO in the presence of Na2SO4 and Na2O at 550 °C (15 d) as red single crystals. The structure has been determined from single crystal data (IPDS‐data, T = 170 K, Cmcm, Z = 4, a = 806.88(9) pm, b = 2232.1(3) pm, c = 705.97(9) pm, Rall = 0.047). Magnetic properties and spectroscopic investigations are reported and discussed within the Angular‐Overlap‐Model. 相似文献
63.
We analyze the time-dependent spectrum of eigenvalues of the correlation matrix for multivariate EEG data at the transition to epileptic seizures. By a mechanism of level repulsion between states at both edges of the spectrum of the correlation matrix, relevant information about quantitative correlation changes is reflected in the largest and smallest eigenvalues and corresponding eigenvectors. By the application of measures from random matrix theory we provide evidence that statistically relevant information can be obtained both at the upper and the lower end of the spectrum. In addition, information about spatial characteristics of correlation changes can be extracted. 相似文献
64.
In this paper, we present ab initio two-electron model calculations of laser-induced single and double ionization of the hydrogen molecule in a linearly polarized laser field with static nuclei located along the polarization axis. Within the model, the center-of-mass motion of the two electrons is restricted along the polarization axis of the field, while the relative electron motion is unrestricted. The results of numerical simulations allow us to identify and characterize the mechanisms leading to single and double ionization in an intense few-cycle laser pulse. The role of the rescattering mechanism on the ionization processes is analyzed in particular. 相似文献
65.
In the present paper we succeeded in studying structural phase transitions from an atomistic point of view by positron annihilation Doppler broadening. This differs and is complementary to conventionally used diffraction experiments with large coherence lengths. In the exemplary case of the 1140 K order-disorder transition in decagonal Al71.5Ni14Co14.5 quasicrystals the importance of this atomistic approach and its wide scope of application is demonstrated. 相似文献
66.
An analytically solvable model of the single excitation diffractive type is investigated. It is assumed that a factorizable Pomeron (α P (0)=1) excites a cluster, which subsequently decays through a multiperipheral mechanism with pure meson exchanges. Thus various charge structures can be incorporated. For the charged particle multiplicity distribution in inelasticp-p scattering Wroblewski's law, i. e. the experimentally found linear dependence of the dispersion on the mean multiplicity, is derived. 相似文献
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69.
The inclusive two-particle cross section for the production of largep T photons and opposite side charged hadrons in proton-proton collisions is examined in detail in the framework of QCD. The model, with the parametrization as in our previous work, agrees with the measured single photon spectra. Quantitative predictions are made for two-particle distributions to be measured at the ISR. The contributions due to the photon bremsstrahlung and the effects coming from the intrinsic constituent motion are estimated. It is shown that indeed the direct subprocess gluon+quark→photon+quark gives the dominant contribution in the experimentally relevant region of phase space, and that direct information about the gluon structure function can be obtained from such measurements. 相似文献
70.
Jason R. Stokes Michael W. Boehm Stefan K. Baier 《Current Opinion in Colloid & Interface Science》2013,18(4):349-359
Texture and mouthfeel arising from the consumption of food and beverages are critical to consumer choice and acceptability. While the food structure design rules for many existing products have been well established, although not necessarily understood, the current drive to produce healthy consumer acceptable food and beverages is pushing products into a formulation space whereby these design rules no longer apply. Both subtle and large scale alterations to formulations can result in significant changes in texture and mouthfeel, even when measurable texture-related quantities such as rheology are the same. However, we are only able to predict sensations at the initial stages of consumption from knowledge of material properties of intact food.Research is now on going to develop strategies to capture the dynamic aspects of oral processing, including: from a sensory perspective, the recent development of Temporal Dominance Sensation; from a material science perspective, development of new in vitro techniques in thin film rheology and tribology as well as consideration of the multifaceted effect of saliva. While in vivo, ex vivo, imitative and empirical approaches to studying oral processing are very insightful, they either do not lend themselves to routine use or are too complex to be able to ascertain the mechanism for an observed behaviour or correlation with sensory. For these reasons, we consider that fundamental in vitro techniques are vital for rational design of food, provided they are designed appropriately to capture the important physics taking place during oral processing. We map the oral breakdown trajectory through 6 stages and suggest a dynamic multi-scale approach to capture underlying physics. The ultimate goal is to use fundamental insights and techniques to design new food and beverages that are healthy yet acceptable to consumers. 相似文献