Bi‐Microporous Metal–Organic Frameworks with Cubane [M4(OH)4] (M=Ni,Co) Clusters and Pore‐Space Partition for Electrocatalytic Methanol Oxidation Reaction

Embedding cubane [M₄(OH)₄] (M=Ni, Co) clusters within the matrix of metal–organic frameworks (MOFs) is a strategy to develop materials with unprecedented synergistic properties. Herein, a new material type based on the pore‐space partition of the cubic primitive minimal‐surface net (MOF‐14‐type) has been realized. CTGU‐15 made from the [Ni₄(OH)₄] cluster not only has very high BET surface area (3537 m² g^?1), but also exhibits bi‐microporous features with well‐defined micropores at 0.86 nm and 1.51 nm. Furthermore, CTGU‐15 is stable even under high pH (0.1 m KOH), making it well suited for methanol oxidation in basic medium. The optimal hybrid catalyst KB&CTGU‐15 (1:2) made from ketjen black (KB) and CTGU‐15 exhibits an outstanding performance with a high mass specific peak current of 527 mA mg^?1 and excellent peak current density (29.8 mA cm^?2) at low potential (0.6 V). The isostructural cobalt structure (CTGU‐16) has also been synthesized, further expanding the application potential of this material type.     

Lithium Bonds in Lithium Batteries

Lithium bonds are analogous to hydrogen bonds and are therefore expected to exhibit similar characteristics and functions. Additionally, the metallic nature and large atomic radius of Li bestow the Li bond with special features. As one of the most important applications of the element, Li batteries afford emerging opportunities for the exploration of Li bond chemistry. Herein, the historical development and concept of the Li bond are reviewed, in addition to the application of Li bonds in Li batteries. In this way, a comprehensive understanding of the Li bond in Li batteries and an outlook on its future developments is presented.     

基于大科学装置的空间金属组学和单细胞/单颗粒金属组学

金属组学是综合研究生命体内（(特别是细胞内）)自由或络合的全部金属原子的分布、含量、化学种态及其功能的一门学科,而大科学装置为金属组学研究提供了强有力的工具。本综述本文首先介绍了金属组学发展简史,然后介绍了基于大科学装置的同步辐射技术、中子技术、质子技术及缪子技术等,最后概述了基于大科学装置的空间金属组学、单细胞/单颗粒金属组学的应用示例。基于大科学装置的中子活化技术（NAA）NAA、X-射线荧光光谱（XRF）以及质子激发X射线谱（PIXE ）等技术是开展非原位空间金属组学研究的有力手段,而XRF、PIXE以及缪子X射线荧光谱（MXA）为开展原位空间金属组学提供了有力工具,特别是基于XRF的技术,其空间分辨率可低至10 nm级别,是开展原位单细胞/单颗粒金属组学的利器。 新一代同步辐射光源、质子源及缪子源将为空间金属组学、特别是时空金属组学研究提供更强有力工具。     

关于人膝关节生物力学模型的研究现状

建立人膝关节模型是生物力学研究领域中最具挑战性的课题之一．本文对人膝关节生物力学模型的研究现状予以简单的评估和综述．结果显示:目前用于研究人膝关节的大部分模型,均属静力或准静力模型;仅建立了极少的人膝关节解剖基生物动力模型,且均属二维动力模型．因此,建立一个三维真实人膝关节生物动力模型是目前迫在眉睫的工作      

g-C3N4/CeO2异质结材料的制备及其光催化性能的研究

以三聚氰胺、硝酸铈为原料,通过高温煅烧法制备了不同CeO₂含量的片层状g-C₃N₄/CeO₂,通过XRD、FT-IR、XPS等对系列g-C₃N₄-CeO₂材料进行了表征,考察了材料在可见光(λ≥420nm)条件下降解盐酸四环素(TC)的光催化活性。与单纯的g-C₃N₄相比,g-C₃N₄/CeO₂-30%具有更优异的光催化性能,这是由于g-C₃N₄-CeO₂间的异质结作用促进了光生电子和空穴分离。自由基捕获实验证实·O^-₂在催化反应过程中起到主要作用,并提出了相应的光催化机理。     

Periodical structures on the surface of stainless steel melt

Short-wave periodical structures were observed on the surface of a cooled stainless steel melt. It is shown that the excitation of these structures is caused by the instability of the solidification front.     

Bool阵的逆阵

We give a characterization of a regular Boolean matrix and prove that AB = I Implies that BA = I, where A and B are Boolean matrices whose elements belong to a Boolean algebra of a set with more than two elements.     

基于透明质酸构筑的药物递送载体及其应用

传统纳米药物控释载体主要通过细胞胞吞作用实现药物递送,其主要过程为被动靶向机制,因此会影响纳米载体在肿瘤组织的富集和治疗效果.近年来生物大分子透明质酸因其优异的水溶性、生物相容性、可降解性和肿瘤靶向性备受科研工作者青睐,已被广泛用于药物控释载体的构筑中,并成为靶向肿瘤治疗纳米载体领域的研究热点.本文根据透明质酸基纳米载...     

用光波导光模光谱技术研究DNA-DNA结合蛋白相互作用

探讨了应用光波导光模光谱(Optical waveguide lightmode spectroscopy,OWLS)技术研究DNA-DNA结合蛋白相互作用的可行性和灵敏性。以固定在传感器芯片表面的DNA探针为捕捉分子,溶液中同时含有探针结合序列和NF—κB结合位点序列的寡核苷酸与NF-κB亚单位p50同源二聚体形成的DNA-蛋白质复合物为检测分子,用光波导光模光谱检测技术建立非标记DNA-DNA结合蛋白相互作用检测研究体系。利用这一体系对不同样品中NF-κB p50浓度和具不同NF-κB结合位点序列的寡核苷酸与NF-κB p50亲合和力进行检测。样品中低至0．33 nmol/1的NF-κB p50被光波导光模光谱检测出,不同的NF-κB结合序列与NF-κB p50亲合力有显著的差异。研究发现,光波导光模光谱技术可以用于DNA-DNA结合蛋白相互作用研究,所建立的非标记检测研究体系可以进行样品中结合蛋白含量高灵敏检测和核酸序列与结合蛋白的亲合力的检测研究。