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11.
The novel bis(cyclohexylaminium) cyclohexylaminebis(orotate–N,O)cuprate(II) dihydrate, (C6H15N)2[Cu(C5H2N2O4)2(C6H14N)] · 2H2O, has been prepared and characterized by elemental analysis, magnetic measurements, FT-IR and UV–Vis spectroscopy, thermal analysis and X-ray diffraction. The Cu(II) complex crystallizes in the monoclinic space group P21/c. The copper atom in the five-coordinated (chaH)2[Cu(HOr–N,O)2(cha)] · 2H2O is chelated by a deprotonated pyrimidine nitrogen atom and carboxylate oxygen atom as a bis(bidentate) ligand and the cyclohexylamine ligand completes the square-pyramidal coordination. The thermal decomposition of the complex has been predicted by the help of thermal analysis (TG, DTG and DTA). 相似文献
12.
Fac‐bis(ethanolamine)orotatonickel(II), [Ni(HOr)(ea)2] and mer‐bis(ethanolamine)orotatocopper(II) dihydrate, [Cu(HOr)(ea)2]· 2H2O were synthesized and characterized by elemental analysis, FT‐IR, UV‐Vis Spectroscopy and thermal analysis. In addition, their solid‐state structures were determined by single crystal X‐ray diffraction studies. Both the fac‐[Ni(HOr)(ea)2] (1) and mer‐[Cu(HOr)(ea)2]·2H2O (2) complexes are isomorphous and crystallize in the triclinic space group . The Ni2+ and Cu2+ ions are coordinated by two neutral ea ligands and one orotate dianion in a distorted octahedral fashion. The ea ligand acts as a bidentate donor through the amine N and hydroxyl O atoms, while orotate dianion is coordinated through deprotonated N3 pyrimidine atom and carboxylate oxygen atom as a bidentate ligand. Thermal decompositions of the complexes are studied in over the range 20–600 °C on heating in a static air atmosphere. 相似文献
13.
Okan Zafer Yeşilel Dr. Hümeyra Paşaoğlu Kamber Akdağ Orhan Büyükgüngör 《无机化学与普通化学杂志》2007,633(10):1731-1734
The new orotate complex of cadmium(II) with quinoxaline, mer‐[Cd(HOr)(H2O)3(QX)]·2H2O, was synthesized and characterized by elemental analysis, FT–IR spectroscopy, thermal analysis and single crystal X–ray diffraction techniques. The complex crystallizes in the triclinic system, space group . The Cd2+ ion exhibits a distorted octahedral coordination by one bidentate orotate, one monodentate quinoxaline and three aqua ligands. The uncoordinated water molecules link the orotate, quinoxaline and aqua ligands via O–H···O, O–H···N hydrogen bonds. Thus, an extensive network of hydrogen bonds stabilizes the crystal structure and form an infinitive three dimensional lattice. The decomposition reaction takes place in the temperature range 20–700 °C in the static air atmosphere. 相似文献
14.
The electrochemical behavior of some podands at a benzo[c]cinnoline modified glassy carbon electrode
Aybüke A. ?sb?r Zafer Üstünda? Selen B?lge Amgalan Natsagdorj Emine Kiliç Zeynel Kiliç 《Analytica chimica acta》2005,547(1):59-63
This paper describes the grafting of benzo[c]cinnoline (BCC) molecules on glassy carbon (GC) electrode surface. The attachment of BCC molecules to carbon substrate is induced by the electrochemical reduction of the corresponding diazonium salt. The modification of GC with BCC diazonium salt was done in aprotic solution and proved by blocking of dopamine electron transfer. The presence of BCC at the GC surface was characterized by cyclic voltammetry and X-ray photoelectron spectroscopy (XPS). On modified surface, the electrochemical behavior of two different types of podands and the catalytic effects of the GC-BCC surface were studied. The XPS was used to monitor element characteristics of the adsorbates on the GC surface and confirm the attachment of BCC molecules to the GC surface. 相似文献
15.
Bekzat ABDIKADYR Alp KILI Onur ALEV Serkan BÜYÜKK
SE Zafer Ziya
ZTÜRK 《Turkish Journal of Chemistry》2021,45(2):295
Pristine and WO3 decorated TiO2 nanorods (NRs) were synthesised to investigate n-n-type heterojunction gas sensing properties. TiO2 NRs were fabricated via hydrothermal method on fluorine-doped tin oxide coated glass (FTO) substrates. Then, tungsten was sputtered on the TiO2 NRs and thermally oxidised to obtain WO3 nanoparticles. The heterostructure was characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) spectroscopy. Fabricated sensor devices were exposed to VOCs such as toluene, xylene, acetone and ethanol, and humidity at different operation temperatures. Experimental results demonstrated that the heterostructure has better sensor response toward ethanol at 200 °C. Enhanced sensing properties are attributed to the heterojunction formation by decorating TiO2 NRs with WO3. 相似文献
16.
A Riesz space E is said to have b-property if each subset which is order bounded in E~~ is order bounded in E. The relationship between b-property and completeness, being a retract and the absolute weak topology |σ|(E~, E) is studied. Perfect Riesz spaces are characterized in terms of b-property. It is shown that b-property coincides with the Levi property in Dedekind complete Frechet lattices.
相似文献
17.
The Ramanujan Journal - We compute Fourier series expansions of weight 2 and weight 4 Eisenstein series at various cusps. Then we use results of these computations to give formulas for the... 相似文献
18.
In this paper we give new oscillation criteria for forced super- and sub-linear differential equations by means of nonprincipal solutions. 相似文献
19.
Now it is well known, antioxidant may affect the interaction of anticancer drugs and DNA. This study aims to investigate the interaction between Idarubicin and DNA and the effect of caffeic acid on this interaction. Disposable, inexpensive, easy handle electrodes were used in this study to investigate the interaction of idarubicin and DNA electrochemically. Idarubicin (IDR) is an anthracyline antitumor antibiotic, which used against one or more types of leukemia. Electrochemical behaviour of IDR was investigated by using cyclic voltammetry. The interaction between anticancer drug, IDR and calf thymus double‐stranded DNA (ctdsDNA) was investigated by using differential pulse voltammetry (DPV) technique in the absence and presence of caffeic acid. 相似文献
20.
Moamen S. Refat Lamia A. El-Zayat Okan Zafer Yeşilel 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2010,75(2):745-752
Electron donor–acceptor interaction of morpholine (morp) with chloranilic acid (cla) and picric acid (pa) as π-acceptors was investigated spectrophotometrically and found to form stable charge-transfer (CT) complexes (n–π*) of [(Hmorp)2(cla)] and [(Hmorp)(pa)]2. The donor site involved in CT interaction is morpholine nitrogen. These complexes are easily synthesized from the reaction of morp with cla and pa within MeOH and CHCl3 solvents, respectively. 1HNMR, IR, elemental analyses, and UV–vis techniques characterize the two morpholinium charge-transfer complexes. Benesi–Hildebrand and its modification methods were applied to the determination of association constant (K), molar extinction coefficient (?). The X-ray crystal structure was carried out for the interpretation the predict structure of the [(Hmorp)(pa)]2 complex. 相似文献