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This paper focuses on dynamic, continuous-time production control problems in the fashion industry. Similar to the classical news-vendor problem, we consider a single product-type and the cumulative demand for items is not known until the end of the production horizon and therefore must be forecasted. Since there are periodic updates before a single selling season, actual demand during a period of time can only be determined by the end of the period. If the overall demand is overestimated, excessive inventory holding and production costs are paid and surpluses are sold at low prices at the end of the production horizon. If it is under-estimated, then sales are lost. The objective is to dynamically determine production orders which minimize overall expected costs. Since the optimal feedback for such a problem is characterized by thresholds evolving with time and system states, there is a significant computational burden in determining them. With the aid of the variational analysis and a decomposition, we derive a closed-form solution for the thresholds. A numerical study carried out to compare the decomposition and straightforward simulation-based solutions indicates the high accuracy of the suggested approach while the computational burden is dramatically reduced. 相似文献
64.
R. Kunz W. Möslinger P. Walden und W. Seifert 《Fresenius' Journal of Analytical Chemistry》1902,41(8):509-513
Ohne Zusammenfassung 相似文献
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W E Seifert A Ballatore R M Caprioli 《Rapid communications in mass spectrometry : RCM》1989,3(4):117-122
The techniques of continuous-flow fast-atom bombardment (CF-FAB) and tandem mass spectrometry (MS/MS) are combined and applied to the analysis of small molecular mass drugs (mol.wt less than 500 Da). The approach involves the interfacing of a CF-FAB inlet with a triple-stage quadrupole mass spectrometer, enabling the acquisition of collision-activated decomposition mass spectra of the drugs after FAB ionization. The relationship between a stable sample surface on the CF-FAB probe tip and the quality of the mass spectrum is discussed, as are practical methods for obtaining and maintaining surface stability. CF-FAB MS/MS spectra for several drugs are presented, including penicillin G, phentolamine, cocaine and benzoylecgonine. Minimum detection limits range from 50-500 pg injected, depending on the compound. The reproducibility of the integrated areas of peaks from repetitive injections is approximately five per cent. Data are also presented for the direct CF-FAB MS/MS analysis of cocaine and benzoylecgonine in spiked urine samples. 相似文献
67.
Regina Luschtinetz Augusto F. Oliveira Hélio A. Duarte Gotthard Seifert 《无机化学与普通化学杂志》2010,636(8):1506-1512
Density‐functional based calculations were used to investigate self‐assembled monolayers of different alkylphosphonic acids on corundum α‐Al2O3 (0001), bayerite β‐Al(OH)3 (001) and boehmite γ‐AlOOH (010) surface models. Mono‐, bi‐, and tridentate adsorption modes were considered. In addition, the organization of single adsorbed molecules was compared to the organization at full surface coverage. The height (thickness) of the self‐assembled monolayers is always shorter than the length of the phosphonic acid molecules due to tilting of the alkyl chains. Tilt angles at full surface coverage are very similar to the tilt angle of a single adsorbed molecule, which indicates that the density of the self‐assembled monolayers is limited by the density of adsorption sites. The lateral interactions between alkyl chains are evidenced by small torsions of the adsorbed molecules, which may serve to minimize the repulsion forces between interchain hydrogen atoms. Similar tilt angles were obtained for mono‐, bi‐, and tridentate adsorptions. Hence, the coordination mode cannot be characterized by the molecule tilting. 相似文献
68.
Theodor Milek Patrick Duchstein Gotthard Seifert Prof. Dr. Dirk Zahn Dr. 《Chemphyschem》2010,11(4):847-852
A recently developed atomistic simulation scheme for investigating ion aggregation from solution is transferred to the morphogenesis of metal clusters grown from the vapor and layers deposited on a substrate surface. Both systems are chosen as benchmark models for intense motif reorganization during aggregate/layer growth. The applied simulation method does not necessarily involve global energy minimization after each growth event, but instead describes crystal growth as a series of structurally related configurations which may also include local energy minima. Apart from the particularly favorable high‐symmetry configurations known from experiments and global energy minimization, we also demonstrate the investigation of transient structures. In the spirit of Ostwald’s step rule, a continuous evolution of the aggregate/layer structure during crystal growth is observed. 相似文献
69.
Lienemann J Schüller A Blauth D Seifert J Wethekam S Busch M Maass K Winter H 《Physical review letters》2011,106(6):067602
The coherence for diffraction effects during grazing scattering of fast hydrogen and helium atoms from a LiF(001) surface with energies up to some keV is investigated via the coincident detection of two-dimensional angular distributions for scattered projectiles with their energy loss. For keV H atoms, we identify electronic excitations of the target surface as the dominant mechanism for decoherence, whereas for He atoms this contribution is small. The suppression of electronic excitations owing to the band gap of insulators plays an essential role for preserving quantum coherence and thus for the application of fast atom diffraction as a surface analytical tool. 相似文献
70.
Seifert U 《Physical review letters》2011,106(2):020601
We consider nanosized artificial or biological machines working in steady state enforced by imposing nonequilibrium concentrations of solutes or by applying external forces, torques, or electric fields. For unicyclic and strongly coupled multicyclic machines, efficiency at maximum power is not bounded by the linear response value 1/2. For strong driving, it can even approach the thermodynamic limit 1. Quite generally, such machines fall into three different classes characterized, respectively, as "strong and efficient," "strong and inefficient," and "balanced." For weakly coupled multicyclic machines, efficiency at maximum power has lost any universality even in the linear response regime. 相似文献