首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   139篇
  免费   6篇
  国内免费   1篇
化学   71篇
力学   6篇
综合类   1篇
数学   25篇
物理学   43篇
  2022年   2篇
  2021年   6篇
  2020年   7篇
  2019年   6篇
  2018年   5篇
  2017年   1篇
  2016年   10篇
  2015年   4篇
  2014年   7篇
  2013年   8篇
  2012年   10篇
  2011年   8篇
  2010年   4篇
  2009年   7篇
  2008年   8篇
  2007年   8篇
  2006年   5篇
  2005年   2篇
  2004年   3篇
  2003年   4篇
  2002年   5篇
  2000年   4篇
  1999年   1篇
  1998年   1篇
  1997年   1篇
  1996年   3篇
  1995年   2篇
  1994年   1篇
  1993年   2篇
  1992年   2篇
  1991年   1篇
  1989年   1篇
  1986年   1篇
  1985年   1篇
  1982年   1篇
  1981年   1篇
  1980年   1篇
  1976年   1篇
  1974年   1篇
排序方式: 共有146条查询结果,搜索用时 15 毫秒
101.
We explore the possibility of passive error correction in the toric code model. We first show that even coherent dynamics, stemming from spin interactions or the coupling to an external magnetic field, lead to logical errors. We then argue that Anderson localization of the defects, arising from unavoidable fluctuations of the coupling constants, provides a remedy. This protection is demonstrated by using general analytical arguments that are complemented with numerical results which show that self-correcting memory can in principle be achieved in the limit of a nonzero density of identical defects.  相似文献   
102.
The regiospecific nucleophilic substitution during the ruthenium catalyzed allylic alkylation of 1,3-unsymmetrical disubstituted allylic esters was demonstrated. The nucleophile was selectively introduced at the position originally substituted with leaving group in the 2-DPPBA or ip-pybox ligated [RuCl(2)(p-cymene)](2) catalyzed allylic alkylation of 1,3-unsymmetrical disubstituted allylic esters. The chirality of the optically active allylic esters was also transferred to the alkylated products.  相似文献   
103.
In the classic economic order quantity model the purchasing cost of an order should be paid at the time of its receipt. Sometimes, retailers ask purchasers to pay all or a fraction of the purchasing cost in advance and sometimes allow them to divide the prepayment into several equal-sized parts. In this paper, economic order quantity model for a deteriorating product with and without shortage under consecutive prepayments are developed. Numerical examples illustrate the proposed models and solution method and sensitivity analysis provides some managerial insights for managers.  相似文献   
104.
In this work, Macro-Reversible addition fragmentation termination (RAFT) agents based on poly(ethylene glycol) (PEG) possessing different molecular weights and bearing benzoyl xanthate moieties were synthesized by the reaction of PEG potassium xanthate salts with benzoyl chloride, 4-methyl benzoyl chloride and 4-chloro benzoyl chloride. Controlled free radical polymerization of the styrene were carried out in the presence of these macro-RAFT agents using 2,2′-azobisizsobutyronitrile (AIBN) as an initiator to yield PS-b-PEG-b-PS block copolymers. The linear kinetic plot ln [M]o/[M] vs. polymerization time indicated that was first order with reference to monomer concentration. The block copolymerization possessed controlled/living character. The controlled character of the RAFT polymerization of the styrene was confirmed by the formation of narrow polydispersity of the polymers, linear increases in the molecular weight with polymerization time and molecular weight of the products that agreed well with theoretical values. Polymers having relatively narrow molecular weight distributions and predetermined number average molecular weights were obtained by the RAFT polymerization of the styrene. However, molecular weights of the polymers deviated from the theoretical values when low molecular weight RAFT agents are used. The results indicate that PEG benzoyl xanthate RAFT agents can more efficiently control the polymerization comparing methyl or chlorobenzoyl derivatives. The block copolymers were characterized by spectroscopic and GPC methods.  相似文献   
105.
Surface morphology of bisphenol‐A polycarbonate (BAPC) thin films, with thickness ranging from 30 to 1000 nm on silicon substrates was studied by atomic force microscopy. The films were prepared by spincasting from 1,2‐dichloroethane solutions of 0.25–5.0 wt % BAPC. Even though longer annealing than 250 h was necessary for complete crystallization for bulk BAPC, high crystallinity was observed for 30 nm thick film after annealing at 200 °C for 48 h in vacuum. Positron annihilation lifetime spectroscopy measurements showed that the free volume hole size in 30 nm thick film was larger than that of bulk at 200 °C. Comparison of the BAPC concentration in the precursor solution with the overlap concentration suggests that the high crystallinity of the 30 nm BAPC film is due to less entangled chains caused by rapid removal of the solvent from the dilute solution. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2010  相似文献   
106.
Plasma-polymerized C60 thin films were investigated in the form of a field effect transistor (FET) structure. In the FET device, the C60 polymer acts as a p-type semiconductor, whereas C60 is an n-type semiconductor. Its conduction mechanism can be described as due to variable range hopping. As a sensing device, the C60 polymer can behave as a gas sensor for electrophoric gases and can also be operated as a photo-sensing device in air. Received: 21 April 2001 / Accepted: 23 July 2001 / Published online: 2 October 2001  相似文献   
107.
Beyer et al. gave a sufficient condition for the high dimensional phenomenon known as the concentration of distances. Their work has pinpointed serious problems due to nearest neighbours not being meaningful in high dimensions. Here we establish the converse of their result, in order to answer the question as to when nearest neighbour is still meaningful in arbitrarily high dimensions. We then show for a class of realistic data distributions having non-i.i.d. dimensions, namely the family of linear latent variable models, that the Euclidean distance will not concentrate as long as the amount of ‘relevant’ dimensions grows no slower than the overall data dimensions. This condition is, of course, often not met in practice. After numerically validating our findings, we examine real data situations in two different areas (text-based document collections and gene expression arrays), which suggest that the presence or absence of distance concentration in high dimensional problems plays a role in making the data hard or easy to work with.  相似文献   
108.
In this paper, a multi-buyer multi-vendor supply chain problem is considered in which there are several products, each buyer has limited capacity to purchase products, and each vendor has warehouse limitation to store products. In this chain, the demand of each product is stochastic and follows a uniform distribution. The lead-time of receiving products from a vendor to a buyer is assumed to vary linearly with respect to the order quantity of the buyer and the production rate of the vendor. For each product, a fraction of the shortage is backordered and the rest are lost. The ordered product quantities are placed in multiple of pre-defined packets and there are service rate constraints for the buyers. The goal is to determine the reorder points, the safety stocks, and the numbers of shipments and packets in each shipment of the products such that the total cost of the supply chain is minimized. We show that the model of this problem is of an integer nonlinear programming type and in order to solve it a harmony search algorithm is employed. To validate the solution and to compare the performance of the proposed algorithm, a genetic algorithm is utilized as well. A numerical illustration and sensitivity analysis are given at the end to show the applicability of the proposed methodology in real-world supply chain problems.  相似文献   
109.
110.
The hydrogen physisorption properties in single-walled carbon nanotube (SWNT) based materials were characterized. The SWNTs were highly purified and three useful pores for hydrogen physisorption were activated. Hydrogen was physisorbed in intra-tube pores at room temperature and the capacity was estimated to be about 0.3–0.4 wt.% at room temperature. The adsorption capacity can be explained by the Langmuir model. The intra-tube pores have large adsorption potential and this induces hydrogen physisorption at comparatively higher temperatures. This fact indicates the importance of fabricating sub-nanometer ordered pores for this phenomena. PACS 51.30.+i; 51.90.+r; 81.05.Tp; 81.07.De  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号