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91.
有机金属聚合物的研究近几年得到了很大的发展,含金属Si、Ge、Sn的有机聚合物表现出特殊的导电性、非线性光学性等。我们合成了含Si、Ge、Sn的有机金属聚合物的中间体芳基硅烷、锗烷、锡烷。合成路线如下:a:R=Me,M=Si;b:R=Ph,M=Si;c:R=Ph,M=Ge;d:R=Ph,M=Sn1 实验部分1 1 仪器和试剂原料均为化学纯,所有溶剂都经过严格的无水、无氧处理,所有反应均与Schlenk操作线连接;质谱:HENLETTPACKARDMS5989;1HNMR:BRUKERAC80MHz;熔点测量:LEITZBIOMED… 相似文献
92.
J. Arnaud 《Optical and Quantum Electronics》1995,27(4):225-238
The theory presented shows that light emitted by low-temperature semiconductors under intense optical pumping (with fluctuations at the shot-noise level, SNL) should be amplitude-squeezed down to half the SNL at nonzeri frequencies. Amplitude squeezing may also be obtained at zero frequency when spontaneous carrier recombination is significant. It is essential that the optical gain depends on photon emission rate, e.g. as a result of spectral-hole burning. A commuting-number theory that agrees exactly with quantum theory for large particle numbers is employed. Comparison is made with results previously reported for three-level atom lasers. 相似文献
93.
94.
When laser diodes are driven by high-impedance electrical sources, the variance of the number of photo-detection events counted over large time durations is less than the average number of events (sub-Poissonian light). This paper presents a Monte-Carlo simulation that keeps track of each level occupancy (0 or 1) in the conduction and valence bands, and of the number of light quanta in the optical cavity. When there is good electron–lattice thermal contact, the electron and hole temperatures remain equal to that of the lattice. In that case, the elementary laser-diode noise theory results are accurately reproduced by the simulation. But when the thermal contact is poor (or, almost equivalently, at high power levels), new effects occur (spectral-hole burning, temperature fluctuations, statistical fluctuations of the optical gain) that are difficult to handle theoretically. Our numerical simulation shows that the frequency domain over which the photo-current spectral density is below the shot-noise level becomes narrower as the optical power increases. 相似文献
95.
96.
A Bis‐Sulfonyl O,C,O Aryl Pincer Ligand and its Tin(II) Complex: Synthesis,Structural Studies,and DFT Calculations 下载免费PDF全文
Mohammad El Ezzi Romaric Lenk Dr. David Madec Dr. Jean‐Marc Sotiropoulos Sonia Mallet‐Ladeira Dr. Annie Castel 《Angewandte Chemie (International ed. in English)》2015,54(3):805-808
The efficiency of the deprotonated aryl bis‐sulfone [2,6‐{(p‐tolyl)SO2}2C6H3]? as an O,C,O‐coordinating pincer‐type ligand was described. The bis‐sulfone precursor was synthesized using a straightforward palladium‐catalyzed cross‐coupling reaction. As a result of directed ortho metalation (DoM) through sulfonyl groups, a selective lithiation of the aryl group was achieved and the corresponding carbanion was isolated and its structure determined by single‐crystal X‐ray diffraction analysis. A heteroleptic tin(II) complex has been prepared by a nucleophilic substitution reaction. Crystallographic analysis and DFT calculations indicate that the bis‐sulfonyl moiety acts as a new O,C,O‐coordinating pincer‐type ligand with intramolecular S?O coordination to a tin(II) center. The cis form with the two nonbonded oxygen atoms of the sulfonyl groups on the same side is preferentially obtained. 相似文献
97.
Eliminating the contribution of interfering compounds is a key step in chemical analysis. In complex media, one possible approach is to perform a preliminary separation. However purification is often demanding, long, and costly; it may also considerably alter the properties of interacting components of the mixture (e.g. in a living cell). Hence there is a strong interest for developing separation-free non-invasive analytical protocols. Using photoswitchable probes as labelling and titration contrast agents, we demonstrate that the association of a modulated monochromatic light excitation with a kinetic filtering of the overall observable is much more attractive than constant excitation to read-out the contribution from a target probe under adverse conditions. An extensive theoretical framework enabled us to optimize the out-of-phase concentration first-order response of a photoswitchable probe to modulated illumination by appropriately matching the average light intensity and the radial frequency of the light modulation to the probe dynamics. Thus, we can selectively and quantitatively extract from an overall signal the contribution from a target photoswitchable probe within a mixture of species, photoswitchable or not. This simple titration strategy is more specifically developed in the context of fluorescence imaging, which offers promising perspectives. 相似文献
98.
We study the decimation to a sublattice of half the sites of the one-dimensional Dyson–Ising ferromagnet with slowly decaying long-range pair potentials of the form , deep in the phase transition region ( and low temperature). We prove non-Gibbsianness of the decimated measures at low enough temperatures by exhibiting a point of essential discontinuity for the (finite-volume) conditional probabilities of decimated Gibbs measures. This result complements previous work proving conservation of Gibbsianness for fastly decaying potentials () and provides an example of a “standard” non-Gibbsian result in one dimension, in the vein of similar results in higher dimensions for short-range models. We also discuss how these measures could fit within a generalized (almost vs. weak) Gibbsian framework. Moreover we comment on the possibility of similar results for some other transformations. 相似文献
99.
In squeeze flow rheometry, the main problem is the boundary condition between the squeezed material and the plates. Therefore, the crucial assumption is to know the location and the shape of the sample part where wall slip may or may not occur. This question is investigated from experimental results. For this, squeeze flow experiments are carried out to visualize the flow pattern at the walls. Influence of boundary conditions is particularly studied using different plate surface condition. As a result, with wall slipping conditions, we propose a flow modelling divided into two zones: a circular central zone of the sample sticks on the plates and, beyond that zone, the sample slips at the plates with friction. 相似文献
100.