排序方式: 共有164条查询结果,搜索用时 93 毫秒
11.
JPC – Journal of Planar Chromatography – Modern TLC - The objective of this study was the use of solid-phase extraction and planar chromatography with diode-array detection for analysis... 相似文献
12.
We propose a new classification method for the prediction of drug properties, called random feature subset boosting for linear discriminant analysis (LDA). The main novelty of this method is the ability to overcome the problems with constructing ensembles of linear discriminant models based on generalized eigenvectors of covariance matrices. Such linear models are popular in building classification-based structure-activity relationships. The introduction of ensembles of LDA models allows for an analysis of more complex problems than by using single LDA, for example, those involving multiple mechanisms of action. Using four data sets, we show experimentally that the method is competitive with other recently studied chemoinformatic methods, including support vector machines and models based on decision trees. We present an easy scheme for interpreting the model despite its apparent sophistication. We also outline theoretical evidence as to why, contrary to the conventional AdaBoost ensemble algorithm, this method is able to increase the accuracy of LDA models. 相似文献
13.
Arkadiusz Lewandowski 《Journal of Geometric Analysis》2018,28(3):2466-2476
We prove that given a family \((G_t)\) of strictly pseudoconvex domains varying in \(\mathcal {C}^2\) topology on domains, there exists a continuously varying family of peak functions \(h_{t,\zeta }\) for all \(G_t\) at every \(\zeta \in \partial G_t\). 相似文献
14.
Arkadiusz Pawlik Jakub Kozik Tomasz Krawczyk Michał Lasoń Piotr Micek William T. Trotter Bartosz Walczak 《Discrete and Computational Geometry》2013,50(3):714-726
Several classical constructions illustrate the fact that the chromatic number of a graph may be arbitrarily large compared to its clique number. However, until very recently no such construction was known for intersection graphs of geometric objects in the plane. We provide a general construction that for any arc-connected compact set $X$ X in $\mathbb{R }^2$ R 2 that is not an axis-aligned rectangle and for any positive integer $k$ k produces a family $\mathcal{F }$ F of sets, each obtained by an independent horizontal and vertical scaling and translation of $X$ X , such that no three sets in $\mathcal{F }$ F pairwise intersect and $\chi (\mathcal{F })>k$ χ ( F ) > k . This provides a negative answer to a question of Gyárfás and Lehel for L-shapes. With extra conditions we also show how to construct a triangle-free family of homothetic (uniformly scaled) copies of a set with arbitrarily large chromatic number. This applies to many common shapes, like circles, square boundaries or equilateral L-shapes. Additionally, we reveal a surprising connection between coloring geometric objects in the plane and on-line coloring of intervals on the line. 相似文献
15.
Applying Mechanochemistry for Bottom‐Up Synthesis and Host–Guest Surface Modification of Semiconducting Nanocrystals: A Case of Water‐Soluble β‐Cyclodextrin‐Coated Zinc Oxide 下载免费PDF全文
Piotr Krupiński Arkadiusz Kornowicz Dr. Kamil Sokołowski Anna M. Cieślak Prof. Janusz Lewiński 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(23):7817-7823
Mechanochemistry has recently emerged as an environmentally friendly solventless synthesis method enabling a variety of transformations including those impracticable in solution. However, its application in the synthesis of well‐defined nanomaterials remains very limited. Here, we report a new bottom‐up mechanochemical strategy to rapid mild‐conditions synthesis of organic ligand‐coated ZnO nanocrystals (NCs) and their further host–guest modification with β‐cyclodextrin (β‐CD) leading to water‐soluble amide‐β‐CD‐coated ZnO NCs. The transformations can be achieved by either one‐pot sequential or one‐step three‐component process. The developed bottom‐up methodology is based on employing oxo‐zinc benzamidate, [Zn4(μ4‐O)(NHOCPh)6], as a predesigned molecular precursor undergoing mild solid‐state transformation to ZnO NCs in the presence of water in a rapid, clean and sustainable process. 相似文献
16.
Arkadiusz Jadczyk 《Advances in Applied Clifford Algebras》2007,17(2):201-240
Using the Clifford algebra formalism we extend the quantum jumps algorithm of the Event Enhanced Quantum Theory (EEQT) to
convex state figures other than those stemming from convex hulls of complex projective spaces that form the basis for the
standard quantum theory. We study quantum jumps on n-dimensional spheres, jumps that are induced by symmetric configurations
of non-commuting state monitoring detectors. The detectors cause quantum jumps via geometrically induced conformal maps (M?bius
transformations) and realize iterated function systems (IFS) with fractal attractors located on n-dimensional spheres. We
also extend the formalism to mixed states, represented by “density matrices” in the standard formalism, (the n-balls), but
such an extension does not lead to new results, as there is a natural mechanism of purification of states. As a numerical
illustration we study quantum fractals on the circle (one-dimensional sphere and pentagon), two–sphere (octahedron), and on
three-dimensional sphere (hypercubetesseract, 24 cell, 600 cell, and 120 cell). The attractor, and the invariant measure on
the attractor, are approximated by the powers of the Markov operator. In the appendices we calculate the Radon-Nikodym derivative
of the SO(n + 1) invariant measure on Sn under SO(1, n + 1) transformations and discuss the Hamilton’s “icossian calculus” as well as its application to quaternionic realization
of the binary icosahedral group that is at the basis of the 600 cell and its dual, the 120 cell.
As a by-product of this work we obtain several Clifford algebraic results, such as a characterization of positive elements
in a Clifford algebra
as generalized Lorentz “spin–boosts”, and their action as M?bius transformation on n-sphere, and a decomposition of any element
of Spin+(1, n + 1) into a spin–boost and a spin–rotation, including the explicit formula for the pullback of the SO(n + 1) invariant Riemannian metric with respect to the associated M?bius transformation. 相似文献
17.
18.
19.
Arkadiusz Lewandowski 《Archiv der Mathematik》2018,111(5):503-511
We give the parameter version of a localization theorem for the Bergman metric near the boundary points of strictly pseudoconvex domains. The approximation theorem for square integrable holomorphic functions on such domains in the spirit of Graham-Kerzman is proved in the hereby paper, as well. 相似文献
20.
Arkadiusz Józefczak Tomasz Hornowski Miko?aj ?abowski Peter Kop?anský Andrzej Szlaferek 《Journal of magnetism and magnetic materials》2009,321(10):1505-1508
The aim of this study was to investigate the influence of poly(ethylene glycol) surface-active coating on the magnetic and thermal properties of biocompatible magnetic liquids. The data were analyzed using the high-temperature approximation model taking into account polydispersity of a system. Heating ability of the PEG-stabilized magnetic fluids was determined by the calorimetric measurement of specific absorption rate (SAR) at a frequency of 750 kHz and a magnetic field of 0-2 kA/m. MF-Oleate/PEG heating properties were found to be comparable to the ones of MF-Oleate. The PEG shell thus does not seem to effect the thermal characteristics and SAR values and might make the magnetic fluid useful for application in hyperthermia treatment. 相似文献