Scepticism,context and modal reasoning

I analyze some classical solutions of the skeptical argument and some of their week points (especially the contextualist solution). First I have proposed some possible improvement of the contextualist solution (the introduction of the explicit-implicit belief and knowledge distinction beside the differences in the relevance of some counter-factual alternatives). However, this solution does not block too fast jumps of the everyday context (where empirical knowledge is possible) into skeptical context (where empirical knowledge is impossible). Then I analyze some formal analogies between some modal arguments on the contingency of empirical facts (and the world as whole) and the skeptical arguments against empirical knowledge. I try to show that the skeptical conclusion “Empirical knowledge does not exist” is logically coherent with the thesis that they are empirical facts and that we have true belief on them. In order to do that without contradictions I have to accept a non-classical definition of knowledge: S knows that p:= S is not justified to allow that non-p. Knowledge and justified allowance function here as some pseudo-theoretical concepts which allow only some partial and conditional definitions by some “empirical” terms and logical conditions.     

Reagents for Detection of Carboxylate Anion Ligands after Chromatographic Separation of Zinc Carboxylato Complexes

JPC – Journal of Planar Chromatography – Modern TLC - Reagents for detection of carboxylate anions as components of zinc carboxylato mixed-ligand complexes, after chromatographic...     

Coordinate-free Characterization of the Symmetry Classes of Elasticity Tensors

We formulate coordinate-free conditions for identifying all the symmetry classes of the elasticity tensor and prove that these conditions are both necessary and sufficient. Also, we construct a natural coordinate system of this tensor without the a priory knowledge of the symmetry axes.     

Ionization of aniline and its N-methyl and N-phenyl substituted derivatives by (free) electron transfer to n-butyl chloride parent radical cations

The electron transfer from aniline and its N-methyl as well as N-phenyl substituted derivatives (N-methylaniline, N,N-dimethylaniline, diphenylamine, triphenylamine) to parent solvent radical cations was studied by electron pulse radiolysis in n-butyl chloride solution. The ionization results in the case of aniline (ArNH2) and the secondary aromatic amines (Ar2NH, Ar(Me)NH) in the synchronous and direct formation of amine radical cations, as well as aminyl radicals, in comparable amounts. Subsequently, ArNH2*+ deprotonates in a delayed reaction with the present nucleophile Cl-, and forms further ArNH*. In contrast, tertiary aromatic amines such as triphenylamine and dimethylaniline yield primarily the corresponding amine radical cations Ar3N*+ or Ar(Me2)N*+, only. The persistent Ar3N*+ forms a charge transfer complex (dimer) with the parent amine molecule, whereas Ar(Me2)N*+ deprotonates to carbon-centered radicals Ar(Me)NCH2*.     

Introduction to time-of-flight secondary ion mass spectrometry application in chromatographic analysis

New on-line analytical system coupling thin layer chromatography (TLC) and high selective identification unit-time of flight secondary ion mass spectrometry (TOF-SIMS) is introduced in this article. Chromatographic mixture separation and analyte surface deposition followed with surface TOF-SIMS analysis on-line allows to identify the analytes at trace and ultratrace levels. The selected analytes with different detectability and identification possibility were analysed in this hyphenated unit (Methyl Red indicator, Terpinolen and Giberrelic acid). Here, the chromatographic thin layer plays a universal role: separation unit, analyte depositing surface and TOF-SIMS interface, finally. Two depositing substrates and TOF-SIMS compatible interfaces were tested in above-mentioned interfacing unit: modified aluminium backed chromatographic thin layer and monolithic silica thin layer. The sets of positive and negative ions TOF-SIMS spectra obtained from different SIMS modes of analysis were used for analyte identification purposes. SIMS enables analyte detection with high mass resolution at the concentration level that is not achieved by other methods.     

The Possibility of TLC-FID Detection in Oligosaccharide Analysis

JPC – Journal of Planar Chromatography – Modern TLC - Thin layer chromatography with flame-ionization detection has been used for analysis of oligosaccharides. We report preliminary...