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121.
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Structural Effects in Visible‐Light‐Responsive Metal–Organic Frameworks Incorporating ortho‐Fluoroazobenzenes
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Dr. Sonia Castellanos Dr. Alexis Goulet‐Hanssens Fangli Zhao Alla Dikhtiarenko Alexey Pustovarenko Prof. Stefan Hecht Prof. Jorge Gascon Prof. Freek Kapteijn Dr. David Bléger 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(2):746-752
The ability to control the interplay of materials with low‐energy photons is important as visible light offers several appealing features compared to ultraviolet radiation (less damaging, more selective, predominant in the solar spectrum, possibility to increase the penetration depth). Two different metal–organic frameworks (MOFs) were synthesized from the same linker bearing all‐visible ortho‐fluoroazobenzene photoswitches as pendant groups. The MOFs exhibit different architectures that strongly influence the ability of the azobenzenes to isomerize inside the voids. The framework built with Al‐based nodes has congested 1D channels that preclude efficient isomerization. As a result, local light–heat conversion can be used to alter the CO2 adsorption capacity of the material on exposure to green light. The second framework, built with Zr nodes, provides enough room for the photoswitches to isomerize, which leads to a unique bistable photochromic MOF that readily responds to blue and green light. The superiority of green over UV irradiation was additionally demonstrated by reflectance spectroscopy and analysis of digested samples. This material offers promising perspectives for liquid‐phase applications such as light‐controlled catalysis and adsorptive separation. 相似文献
124.
Alexey V. Borisov Alexander A. Kilin Ivan S. Mamaev 《Regular and Chaotic Dynamics》2011,16(6):653-662
In this paper we develop a new model of non-holonomic billiard that accounts for the intrinsic rotation of the billiard ball.
This model is a limit case of the problem of rolling without slipping of a ball without slipping over a quadric surface. The
billiards between two parallel walls and inside a circle are studied in detail. Using the three-dimensional-point-map technique,
the non-integrability of the non-holonomic billiard within an ellipse is shown. 相似文献
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In the present record a model for the gas-phase reactions during the chemical vapor deposition (CVD) processes of group 13-15 materials is presented, based on the results of extensive quantum-chemical modeling. Thermodynamic criteria have been introduced to evaluate the importance of a range of association reactions. For the organometallic and hydride derivatives, association processes are found to be favorable both thermodynamically and kinetically. Formation of high mass association products takes place under CVD conditions, including laser-assisted CVD. Structural and thermodynamic properties of the most important ring and cluster intermediates have been predicted. The stoichiometry-controlled synthesis of the 13-15 ternary alloys and nanoparticles using cluster compounds as single-source precursors is predicted to be viable. The association pathway described may be generalized to the CVD reactions of many binary materials (12-16, 13-16, 13-15, 14-15, 14-16). 相似文献
127.
Laminar-turbulent transition in circular Couette flow is discussed. Phenomenological equations are proposed describing the breakdown of azimuthal waves coherency. The correspondence is established between the flow turbulization and the stochastic attractor in the phase space of these equations. Evolution of attractor structure is investigated experimentally in terms of motion in some effective phase space. It is shown that during the transition to turbulence the increase in number of degrees of freedom is combined with the stochastic behaviour of rapid motion envelopes. 相似文献
128.
The dynamics of the ferromagnetic order parameter in thin magnetic films is strongly affected by the magnetomechanical coupling at certain resonance frequencies. By solving the equation of motion of the coupled mechanical and magnetic degrees of freedom we show that the magnetic field induced magnetization switching can be strongly accelerated by the lattice and illustrate the possibility of magnetization reversal by mechanical actuation. 相似文献
129.
Tissue water content is an important diagnostic parameter that can be used for estimation of water loss in muscles such as common dehydration during high endurance exercises. It could be also applied for evaluation of the increased fluids content in the tissue caused by the variety of pathological conditions or edemas. Ultrasonic method for tissue water content monitoring is based on the premise that the speed of a bulk or compression sound wave is determined mainly by the molecular content of the tissue. Most soft tissues, including muscles that consist of about 70-80% water, exhibit shift of the ultrasound velocity associated with the change in their water content. In the present paper, we tested the feasibility of assessing changes in tissue water content by measurements of ultrasound velocity in ex vivo animal muscle tissues. An increase in the ultrasound velocity correlated with the volumetric water loss in the tissue was observed when other tissue components (proteins, fat) remained constant. Possibility to assess muscle dehydration with 1% accuracy was confirmed in model dehydration experiments, where ultrasound velocity slope of about 3 m/s per 1% of water loss was revealed at measurement error less than 2 m/s. Hence, the ultrasonic approach can provide basis for a convenient, lightweight system in sports medicine for monitoring total body hydration during long-term endurance exercise in hot conditions, as well as for edemas monitoring and other medical applications. 相似文献
130.
A remarkable analogy is established between the well-known spin Hall effect and the polarization dependence of Rayleigh scattering of light in microcavities. This dependence results from the strong spin effect in elastic scattering of exciton polaritons: if the initial polariton state has a zero spin and is characterized by some linear polarization, the scattered polaritons become strongly spin polarized. The polarization in the scattered state can be positive or negative dependent on the orientation of the linear polarization of the initial state and on the direction of scattering. Very surprisingly, spin polarizations of the polaritons scattered clockwise and anticlockwise have different signs. The optical spin Hall effect is possible due to strong longitudinal-transverse splitting and finite lifetime of exciton polaritons in microcavities. 相似文献