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101.
2,6-Diacetylpyridine bis(benzoylhydrazone) (H2DPBH) is proposed as a ligand for the extraction of uranium(VI). Complete extraction from aqueous solutions into dichloromethane is achieved with a ligand/metal mole ratio of < for 10?5?10?4 M uranyl ion. Potentiometric measurements indicate that the extracted species is UO2 (DPBH). Uranium can be determined in the extract by spectrophotometric measurements at 420 nm and by differentail pulse polarography (Ep = ?0.67 V) with tetraethylammonium bromide as supporting electrolyte. For both methods, the detection limit is about 2 × 10?6 M in the extract. 相似文献
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Alessandro Bencini Myriam G. Uytterhoeven Claudia Zanchini 《International journal of quantum chemistry》1994,52(4):903-918
Spin-polarized Xα–SW calculations of [Fe6(μ3?S)8(PH3)6]2+ as a model of the cluster [Fe6(μ3?S)8(PEt3)6] (BPh4)2 have been performed. The highest occupied energy levels are well separated from empty levels, and up to a maximum of eight electrons can be unpaired, giving a maximum spin state with S = 4. This electronic state is consistent with the magnetic data of [Fe6(μ3?S)8(PEt3)6](BPh 4)2, which have been interpreted using the Heisenberg–Dirac–Van Vleck exchange spin Hamiltonian. The S = 4 state arises from the magnetic coupling between five low-spin (Si = 1/2) and one intermediate-spin (S = 3/2) iron(III) center. © 1994 John Wiley & Sons, Inc. 相似文献
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Peter E.J. Vos Claes Eskilsson Alessandro Bolis Sehun Chun Robert M. Kirby 《International Journal of Computational Fluid Dynamics》2013,27(3):107-125
Time-stepping algorithms and their implementations are a critical component within the solution of time-dependent partial differential equations (PDEs). In this article, we present a generic framework – both in terms of algorithms and implementations – that allows an almost seamless switch between various explicit, implicit and implicit–explicit (IMEX) time-stepping methods. We put particular emphasis on how to incorporate time-dependent boundary conditions, an issue that goes beyond classical ODE theory but which plays an important role in the time-stepping of the PDEs arising in computational fluid dynamics. Our algorithm is based upon J.C. Butcher's unifying concept of general linear methods that we have extended to accommodate the family of IMEX schemes that are often used in engineering practice. In the article, we discuss design considerations and present an object-oriented implementation. Finally, we illustrate the use of the framework by applications to a model problem as well as to more complex fluid problems. 相似文献
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Gabriella Ieronimo Alessandro Mondelli Francesco Tibiletti Angelo Maspero Giovanni Palmisano Simona Galli Stefano Tollari Norberto Masciocchi Kenneth M. Nicholas Silvia Tagliapietra Giancarlo Cravotto Andrea Penoni 《Tetrahedron》2013
The thermal reaction between nitrosoarenes and alkynes under alkylating conditions produces N-alkoxyindoles as the major products in moderate to good yields and excellent regioselectivity. Various electrophiles are used affording different N–O-protected hydroxyindoles in a multi-component fashion. Privileged acetylenic substrates used in reactions with substituted nitrosoarenes are arylalkynes or propiolates. Potentially bioactive compounds and other classes of highly functionalizable indole products were prepared. Reactions between o-carbomethoxy-nitrosoarenes and arylacetylenes provided tricyclic compounds containing an acylaziridine indoline skeleton. 相似文献
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Fernanda Cortez Lopes Deise Michele Tichota Jamile Queiroz Pereira Jéferson Segalin Alessandro de Oliveira Rios Adriano Brandelli 《Applied biochemistry and biotechnology》2013,171(3):616-625
The search for new sources of natural pigments has increased, mainly because of the toxic effects caused by synthetic dyes used in food, pharmaceutical, textile, and cosmetic industries. Fungi provide a readily available alternative source of natural pigments. In this context, the fungi Penicillium chrysogenum IFL1 and IFL2, Fusarium graminearum IFL3, Monascus purpureus NRRL 1992, and Penicillium vasconiae IFL4 were selected as pigments producers. The fungal identification was performed using ITS and part of the β-tubulin gene sequencing. Almost all fungi were able to grow and produce water-soluble pigments on agro-industrial residues, with the exception of P. vasconiae that produced pigments only on potato dextrose broth. The production of yellow pigments was predominant and the two strains of P. chrysogenum were the largest producers. In addition, the production of pigments and mycotoxins were evaluated in potato dextrose agar using TOF-MS and TOF-MS/MS. Metabolites as roquefortine C, chrysogine were found in both extracts of P. chrysogenum, as well fusarenone X, diacetoxyscirpenol, and neosolaniol in F. graminearum extract. In the M. purpureus extract, the pigments monascorubrin, rubropunctatin, and the mycotoxin citrinin were found. The crude filtrates have potential to be used in the textile industry; nevertheless, additional pigment purification is required for food and pharmaceutical applications. 相似文献
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