Electrochemical characterization and stress corrosion cracking behavior of α-brass in molybdate-containing electrolytes

One of the major challenges in material design is the achievement of reasonable operational efficiency through understanding the factors affecting the material’s performance particularly strength and service lifetime characteristics. In this work, the electrochemical behavior of 72Cu–28Zn α-brass alloy in Na₂MoO₄-containing electrolytes was investigated using potentiodynamic polarization and electrochemical frequency modulation techniques complemented with scanning electron microscopy. Also, stress corrosion cracking behavior of the alloy under both open-circuit potential and anodic applied potentials, using the slow strain rate technique, was evaluated. The results drawn from the different techniques are comparable.     

Best candidate materials for fast speed response and high transmission performance efficiency of acousto optic modulators

An acousto-optic modulator (AOM), also called a Bragg cell, uses the acousto-optic effect to diffract and shift the frequency of light using sound waves (usually at radio frequency). They are used in lasers for quality switching, telecommunications for signal modulation, and in spectroscopy for frequency control. This paper has presented the best candidate selected acousto optic materials based AOM for upgrading speed response and transmission performance characteristics. These materials are common materials for acousto-optic devices such as silica glass (SiO₂), tellurium dioxide TeO₂), gallium phosphide, and gallium arsenide. As well as we have deeply investigated the important transmission characteristics of acousto optic modulators such as transmission performance efficiency, transmission bit rate, diffraction angle and efficiency, transient speed response, signal transmission quality, bit error rate and modulation bandwidth under wide range of the affecting parameters for different selected acousto optic materials to be the major of interest.     

Performance evaluation of a WDM/OCDM based hybrid optical switch utilizing efficient resource allocation

A hybrid optical switch （HOS） with physical layer of wavelength division multiplexing and optical code division multiplexing （WDM/OCDM） scheme is proposed. An additional feature to the HOS than optical cross connect （OXC） is that the controller can process requests for both circuit establishment and burst scheduling. In our study, the measurement criteria of HOS are the blocking probability, probability of error, and probability of outage. To simplify the analysis, no distinction is made between a circuit in progress and a burst in progress. Moreover, a minimum fit （MinF） resource allocation strategy is applied in order to increase the bandwidth efficiency and control the multiplexing interference of the OCDM. A 2D Markov model for the HOS is presented using the MinF strategy. Numerical results reveal that the code parameters and the resource allocation strategy greatly affect the performance. Certain periority can be achieved by assigning shorter codes to high periority users and longer codes to low periority users. Also, the probability of error and outage are reduced bv aonling the MinF strategy.     

Effect of size and indium-composition on linear and nonlinear optical absorption of InGaN/GaN lens-shaped quantum dot

Based on the Schr ¨odinger equation for envelope function in the effective mass approximation, linear and nonlinear optical absorption coefficients in a multi-subband lens quantum dot are investigated. The effects of quantum dot size on the interband and intraband transitions energy are also analyzed. The finite element method is used to calculate the eigenvalues and eigenfunctions. Strain and In-mole-fraction effects are also studied, and the results reveal that with the decrease of the In-mole fraction, the amplitudes of linear and nonlinear absorption coefficients increase. The present computed results show that the absorption coefficients of transitions between the first excited states are stronger than those of the ground states. In addition, it has been found that the quantum dot size affects the amplitudes and peak positions of linear and nonlinear absorption coefficients while the incident optical intensity strongly affects the nonlinear absorption coefficients.     

Harmonic and intermodulation distortions and noise associated with two-tone modulation of high-speed semiconductor lasers

We present results of modeling and simulation of the harmonic and intermodulation distortions as well as the intensity noise of high-speed semiconductor lasers under two-tone modulation. Multiple quantum-well lasers are considered, which are characterized by large differential gain and a modulation bandwidth of about 25GHz. The study is based on the rate equation model of semiconductor lasers excited by injection current with two sinusoidal tones separated by a radio frequency. The modulated laser signal is modeled in both the time and frequency domains. The time domain characteristics include the fluctuating waveform, while the frequency domain characteristics include the frequency spectrum of the relative intensity noise (RIN), carrier-to-noise ratio, modulation response, harmonic distortion, and the second- and third-order intermodulation distortions (IMD2 and IMD3). The analysis is performed for three frequencies of 5, 15, and 24 GHz, which are, respectively, lower, comparable, and higher than the laser relaxation frequency. The range of the modulation depth covers the regimes of small and large-signal modulation. We show that both RIN and IMD3 of two-modulated laser are minimum when the modulation frequency is 5GHz, and maximum when the modulation frequency is 24 GHz. The second-order harmonic distortion, IMD2, and IMD3 values are larger in the vicinity of relaxation oscillations and increase with the modulation index, especially under large-signal modulation.     

Assessment of bone calcium and phosphorus content using micro X‐ray fluorescence spectrometry (μ‐EDXRF): effects of long‐term cadmium poisoning

This study assesses whether the concentrations of biologically important elements in bones are altered by long‐term consumption of cadmium (Cd)‐contaminated water. Heavy metal poisoning has significant impact on humans, and pollutants such as Cd are often found at high concentrations in waterways. Twelve Sprague Dawley rats consumed water with 50 p.p.m. Cd (Cd group), and another 12 consumed normal water (control group). Six subjects from each group were sacrificed after 2 weeks and the others after 4 weeks. Spectra were acquired from the femur by using the EDAX Eagle III micro‐XRF setup, and quantitative calculations were performed by using the fundamental parameter method to determine the concentrations of elements. A bone calcium/phosphorus concentration ratio (Ca/P) of 2.07 ± 0.001 is observed in the spectra from control subjects after 2 weeks and 2.07 ± 0.001 after 4 weeks. In Cd subjects, Ca/P after 2 weeks is 2.04 ± 0.001 and after 4 weeks is 1.97 ± 0.003. Statistically significant differences are obtained when comparing controls with Cd subjects at both time points and when comparing Cd subjects at both time points. Cadmium poisoning significantly affects bone Ca and P concentrations, increasing the likelihood of osteoporosis and other bone diseases. Copyright © 2016 John Wiley & Sons, Ltd.     

Extension of the Jones matrix formalism to higher-order transverse modes

The well-known Jones matrix formalism, which can be directly applied to the propagation of the polarization of fundamental (TEM(00)) laser resonator modes, has to be modified for higher-order transverse modes. It is shown that this can be done in straightforward manner by using N x N matrices instead of the 2 x 2 Jones matrices, where N denotes the number of orthogonal polarization states of the transverse mode under consideration. The most common case of TEM(01) Hermite-Gaussian modes, where N is four, is discussed in detail.     

Numerical analysis of electronic conductivity in graphene with resonant adsorbates: comparison of monolayer and Bernal bilayer

We describe the electronic conductivity, as a function of the Fermi energy, in the Bernal bilayer graphene (BLG) in presence of a random distribution of vacancies that simulate resonant adsorbates. We compare it to monolayer (MLG) with the same defect concentrations. These transport properties are related to the values of fundamental length scales such as the elastic mean free path L _e , the localization length ξ and the inelastic mean free path L _i . Usually the later, which reflect the effect of inelastic scattering by phonons, strongly depends on temperature T. In BLG an additional characteristic distance l ₁ exists which is the typical traveling distance between two interlayer hopping events. We find that when the concentration of defects is smaller than 1%–2%, one has l ₁ ≤ L _e ? ξ and the BLG has transport properties that differ from those of the MLG independently of L _i (T). Whereas for larger concentration of defects L _e <l ₁ ? ξ, and depending on L _i (T), the transport in the BLG can be equivalent (or not) to that of two decoupled MLG. We compare two tight-binding model Hamiltonians with and without hopping beyond the nearest neighbors.     

Antimicrobial and antitumor activities of 1,2,4‐triazoles/polypyrrole chitosan core shell nanoparticles

Combination of natural biodegradable polymer with a synthetic polymer offers excellent properties for the support in drug delivery system. For this purpose, biodegradable conductive nanoparticle polypyrrole based on chitosan (PPC) has been prepared via oxidative polymerization of pyrrole in presence of chitosan using FeCl₃ as oxidant in acidic medium and used as a carrier for 1,2,4‐triazoles. The resultant nanoparticles were characterized by X‐ray diffraction, Fourier transform infrared analysis, transmission electron microscopy, scanning electron microscopy, and thermal gravimetric analysis. The results indicate that spherical nanoparticle of average diameter 52 ± 8 nm was successfully prepared. The spherical particles were composed of dark sphere surrounded by grey shell. A circumferential dark ring is observed in the shell after loading 1,2,4‐triazoles into PPC nanoparticles. The loaded triazoles were released almost linearly against time in a sustained fashion into different pH media. The mechanism of triazoles release was determined using different kinetics equations. The antibacterial activities against the gram‐negative and gram‐positive bacteria were examined. Furthermore, the antitumor activity of PPC nanoparticles loaded 1,2,4‐triazoles was also examined against Ehrlich ascites carcinoma cells and breast cancer cell line (MCF7). Polypyrrole chitosan loaded nanoparticles exhibited higher antitumor activity than 1,2,4‐triazoles.