Kinetic study of in situ normal and AGET atom transfer radical copolymerization of n–butyl acrylate and styrene: Effect of nanoclay loading and catalyst concentration

The effect of clay nanolayers and catalyst concentration on the kinetics of atom transfer radical copolymerization of styrene and butyl acrylate initiated by activators generated by electron transfer (AGET initiation system) or an alkyl halide (normal initiation system) was studied. Monomer conversion was studied by attenuated total reflection–Fourier transform infrared spectroscopy, and also proton nuclear magnetic resonance (¹H NMR) spectroscopy was utilized to evaluate the heterogeneity in the composition of poly(styrene‐co‐butyl acrylate) chains. A decrease in the copolymerization rate of styrene and butyl acrylate in the presence of clay platelets was observed since clay layers confine the accessibility of monomer and growing radical chains. Considering the linear first‐order kinetics of the polymerization, successful AGET and normal atom transfer radical polymerization (ATRP) in the presence of clay nanolayers were carried out. Consequently, poly(styrene‐co‐butyl acrylate) chains with narrow molecular weight distribution and low polydispersity indices (1.13–1.15) were obtained. The linearity of ln([M]₀/[M]) versus time and molecular weight distribution against conversion plots indicates that the proportion of propagating radicals is almost constant during the polymerization, which is the result of insignificant contribution of termination and transfer reactions. Controlled synthesis of poly(styrene‐co‐butyl acrylate)/clay is implemented with the diminishing catalyst concentration of copper(I) bromide/N,N,N′,N′′,N′′‐pentamethyl diethylene triamine without affecting the copolymerization rate of normal ATRP. © 2012 Wiley Periodicals, Inc. Int J Chem Kinet 44: 789–799, 2012     

Vibrational analysis of electrostatically actuated microstructures considering nonlinear effects

The vibrational behavior of electrostatically actuated microstructures subjected to nonlinear squeeze film damping and in-plane forces is investigated. First-Order Shear Deformation Theory is used to model dynamical system by means of finite element method, while finite difference method is applied to solve the nonlinear Reynolds equation of squeeze film damping simultaneously. Vibrational analysis of microplates is performed by solving eigenvalue problem, after validating the model by pull-in phenomenon and transient behavior. In addition, considering nonlinear squeeze film damping and step-input actuations, response frequencies of microplates are calculated. Effect of ambient pressure and in-plane forces on dynamic pull-in phenomenon is also studied. Results for simplified models are verified and are in good agreement with the published literature. This investigation can reveal nonlinear vibrational behavior of microstructures.     

Identification of Weakly Nonlinear Systems Using Describing Function Inversion

In this paper describing functions inversion is used and the restoring force of a nonlinear element in a MDOF system is characterized. The describing functions can be obtained using linearized frequency response functions (FRFs). The response of the system to harmonic excitation forces at distinct frequencies close to the resonant frequency results in linearized FRFs. The nonlinear system can be approximated at each excitation frequency by an equivalent linear system. This approximation leads to calculation of the first-order describing functions. By having the experimental describing functions calculated and the system’s responses corresponding to the nonlinear element (measured or interpolated), nonlinear parameter identification can be performed. Two numerical and experimental case studies are provided to show the applicability of this method.     

On the stability of multiple parameter time-varying dynamic systems

A technique is presented for determaining the stability of lumped-pararaeter, time-varying, dynamic systems with aperiodic coefficients. An “energy like” function is used to develop stability conditions which are direct in terms of the coefficient matrices. The significance of what is presented here is twofold. First, it gives stability conditions applicable to systems which are not necessarily periodic. Second, is allows for a systematic categorization of the effects of the parameter changes on system response and stability, in order to provide a better understanding of the behavior of this class of dynamic systems as they arise in various areas of engineering.     

Micro/macro-slip damping in beams with frictional contact interface

Friction in contact interfaces of assembled structures is the prime source of nonlinearity and energy dissipation. Determination of the dissipated energy in an assembled structure requires accurate modeling of joint interfaces in stick, micro-slip and macro-slip states. The present paper proposes an analytical model to evaluate frictional energy loss in surface-to-surface contacts. The goal is to develop a continuous contact model capable of predicting the dynamics of friction interface and dissipation energy due to partial slips. To achieve this goal, the governing equations of a frictional contact interface are derived for two distinct contact states of stick and partial slip. A solution procedure to determine stick–slip transition under single-harmonic excitations is derived. The analytical model is verified using experimental vibration test responses performed on a free-frictionally supported beam under lateral loading. The theoretical and experimental responses are compared and the results show good agreements between the two sets of responses.     

An experimental and numerical study of packing,compression, and caking behaviour of detergent powders

This paper presents an experimental and numerical study of the packing, compression, and caking behaviour of spray dried detergent(SDD) powders with a two-fold aim: an experimental process of observation and evaluation of the packing, compression and caking behaviour of SDD powders, and a numerical approach based on discrete element modelling(DEM). The mechanical properties, including the stress–strain response and the corresponding porosity change as a function of consolidation stress in a confined cylinder, the stress–strain response during unconfined shearing and the cake strength as a function of consolidation stress, were evaluated and compared for different SDD powders using an extended uniaxial tester(Edinburgh Powder Tester – EPT). The experiments using EPT showed excellent reproducibility in the measurement of packing, compression and caking behaviour and were therefore very useful for describing the handling characteristics of these powdered products including screening new products and different formulations. It was found that the sample with higher moisture had lower bulk porosity but higher compressibility and cake strength. The porosity, compressibility and cake strength were found to vary across different size fractions of the same sample. The larger sieve-cut samples had higher initial bulk porosity, compressibility and cake strength. It is revealed that moisture plays a significant role in packing, compression, and shearing behaviour of the powder. Three-dimensional DEM modelling using a recently developed elasto-plastic adhesive-frictional contact model showed that the contact model is able to capture the detergent behaviour reasonably well and can be used to model complex processes involving these powders.     

Nonlinear model updating of frictional structures through frequency–energy analysis

Nonlinear Dynamics - Recently, some researchers have suggested using frequency–energy representations of nonlinear normal modes (NNMs) for nonlinear model updating of conservative systems....     

Influence of hybrid nanofluids and heat generation on coupled heat and mass transfer flow of a viscous fluid with novel fractional derivative

Journal of Thermal Analysis and Calorimetry - In this paper, it has been discussed a nonlocal fractional model of viscous nanofluid holding a hybrid nanostructure. Hybridized copper (Cu) and...     

Interference of arsenic trioxide on magnesium dependent polymerization of microtubule proteins

Prevention of microtubule polymerization is considered as one of the promising approaches towards inhibition of cell proliferation, especially in treatment of malignancies. Arsenic trioxide, As₂O₃, is being successfully used in the treatment of human lymphoma, while the mechanism of its therapeutic function is still under investigation. Experiments were designed to determine if indeed As₂O₃ interferes with polymerization of nanotube microtubule. Microtubules were extracted from sheep brain and their interaction with arsenic trioxide was examined by spectrometery. Electrical conductometry of 2 mM MgSO₄ solution containing various concentrations of As₂O₃ was studied in order to determine their possible interaction. Transmission electron microscopy was used to show microtubule structure in the presence of arsenic trioxide. Fluorometric characteristics of tubulin dimer were examined in presence of varying concentrations of arsenic trioxide. It is concluded that arsenic trioxide interacts with Mg²⁺ ion around GTPase site of β-tubulin, resulting enhancement of depolymerization of the microtubule polymer.