Syntheses and spectroscopic investigation of some cyclophosphazanes: Analysis of pseudo‐triplet splitting

Some new phosphoramidates, 1–3 , and the corresponding cyclophosphazanes, 4–6 , with formula Cl₂P(p‐NHC₆H₄CH₃) 1 , Cl₂P(O)(p‐NHC₆H₄NO₂) 2 , (CH₃)₂NP(O)Cl(p‐NHC₆H₄CH₃) 3 , [ClP(p‐NC₆H₄CH₃)]₂ 4 , [ClP(O)(p‐NC₆H₄NO₂)]₂ 5 , and [(CH₃)₂NP(O)(p‐NC₆H₄CH₃)]₂ 6 were synthesized and characterized by ¹H, ¹³C, ³¹P NMR, IR, mass spectroscopy, and elemental analysis. A pseudo‐triplet signal was observed in the ¹H NMR spectrum of molecule 6 for the N(CH₃)₂ protons. The A₆A′ ₆X₂ spin system was suggested for the pseudo‐triplet pattern of ³J_PNCH coupling in this molecule. Ab initio calculations were performed at the HF and B3LYP levels of theory with 6‐311G^** standard basis set on the geometry of compound 6 . Also, the NMR chemical shift calculations were done to compare the computed results with the experimental ones. The calculated results are in good agreement with experimental data. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:337–343, 2006; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20229     

Energy and mass transport of Casson nanofluid flow over a slanted permeable inclined surface

In this problem, examination of Casson nanofluid flow over nonlinear slanted extending sheet with chemical reaction and heat generation/absorption influences are under thought. Nanofluid exhibits in this examination is established on Buongiorno model. The governing nonlinear PDE’s are reduced to nonlinear ODE’s by employing suitable transformations. The Keller-box numerical technique is considered for simulation of this research. The influence of chemical reaction and nonlinear parameter on concentration and velocity distribution is analyzed. The recovered results exhibit that the impact of inclination and Casson factor reduced liquid velocity. While energy and mass transport rates are increased against inclination factor. Numerical and graphical outcomes are additionally exhibited in tables and graphs.

     

Hydrodynamic analysis of a heat exchanger with crosscut twisted tapes and filled with thermal oil-based SWCNT nanofluid: applying ANN for prediction of objective parameters

Journal of Thermal Analysis and Calorimetry - Present study investigates hydrodynamic analysis of heat exchanger with crosscut twisted tapes and filled with thermal oil-based SWCNT nanofluid (NF)....     

Investigation of antioxidant and electron beam radiation effects on the thermal oxidation stability of low-density polyethylene

Effect of various antioxidants on the thermal oxidation stability of LDPE and X-LDPE has been investigated. To achieve this purpose, miscellaneous commercial grade antioxidants such as Irganox 1010, Irganox1076, Irgafos168, Irganox B225, and Chimassorb 944 were selected. Then, formulations based on different content of antioxidant were prepared. The samples were crosslinked by exposure to electron beam irradiation. To assess the thermal oxidation stability of samples, oxidation induction time (OIT) test was accomplished on both the irradiated and unirradiated specimens. Ageing tests were carried out in order to evaluate the thermal oxidation stability of irradiated X-LDPE. The results indicate that Irganox 1010 is the most effective antioxidant amongst the selected ones, concerning thermal oxidation stability of LDPE, before and after aging test.     

Synthesis of 2‐aryl‐1‐arylmethyl‐1H‐1,3‐benzimidazoles catalysed by ferric ammonium sulfate (NH4Fe(SO4)2) under solvent‐free conditions

NH₄Fe(SO₄)₂ was found to be a mild and effective catalyst for the selective synthesis of 2‐aryl‐1‐arylmethyl‐1H‐1,3‐benzimidazoles under solvent‐free conditions. Copyright © 2015 John Wiley & Sons, Ltd.     

Comparison of optical detection system ,PVDF detection system, and PVDF needle hydrophone for optoacoustic tomography

Optoacoustic tomography (PAT) is a two-dimensional medical imaging method that has the advantage of optical contrast and resolution of ultrasonic waves. The detection systems with a high sensitivity can be used for detecting small tumors, located deeply in human tissues, such as the breast. In this study, the sensitivity of existing ultrasonic detection systems has been compared experimentally with that by using thermoelastic waves as a broadband ultrasonic source. For the comparison, an optical stress transducer(OST), a polyvinylidene difluoride (PVDF) sheet and a calibrated PVDF needle hydrophone were used.To ensure all of the detection systems interrogated by the same ultrasonic field, a small optical instrument that fixed the generating laser head was constructed. The sensitivity was evaluated by measuring signalto-noise ratios (SNRs) and noise equivalent pressures (NEPs). The PVDF system, with a 4-kPa NEP has a 22 dB better performance than the OST. The OST showed nearly the same sensitivity as the hydrophone for detecting ultrasound waves at a 1-cm distance in water. PVDF detection system provides a useful tool for imaging of soft tissues because of its high sensitivity and broad detection range.     

An efficient and provably secure three-party password-based authenticated key exchange protocol based on Chebyshev chaotic maps

Three-party password-based authenticated key exchange (3PAKE) protocols allow two clients to establish a secure session key through a server over an insecure channel. Recently, the 3PAKE protocols have been developed based on Chebyshev chaotic maps, in which the clients utilize smart cards to login into the server and employ server’s public key to ensure the identity of the server or symmetric cryptosystems to encrypt the messages. However, this paper describes an efficient chaos-based 3PAKE protocol without smart cards, which requires neither server’s public key nor symmetric cryptosystems. The security of the proposed 3PAKE protocol is proved in the random oracle model using the chaos-based decisional Diffie–Hellman assumption. In comparison with the existing chaos-based 3PAKE protocols, our protocol individually provides better performance in terms of communication, computation, and security aspects, and is supported by the formal proof in the random oracle model.     

Investigation of the size effects in Timoshenko beams based on the couple stress theory

In this paper, a size-dependent Timoshenko beam is developed on the basis of the couple stress theory. The couple stress theory is a non-classic continuum theory capable of capturing the small-scale size effects on the mechanical behavior of structures, while the classical continuum theory is unable to predict the mechanical behavior accurately when the characteristic size of structures is close to the material length scale parameter. The governing differential equations of motion are derived for the couple-stress Timoshenko beam using the principles of linear and angular momentum. Then, the general form of boundary conditions and generally valid closed-form analytical solutions are obtained for the axial deformation, bending deflection, and the rotation angle of cross sections in the static cases. As an example, the closed-form analytical results are obtained for the response of a cantilever beam subjected to a static loading with a concentrated force at its free end. The results indicate that modeling on the basis of the couple stress theory causes more stiffness than modeling by the classical beam theory. In addition, the results indicate that the differences between the results of the proposed model and those based on the classical Euler–Bernoulli and classical Timoshenko beam theories are significant when the beam thickness is comparable to its material length scale parameter.     

Minimization of Total Absolute Flow Time Deviation in Single and Multiple Machine Scheduling

In this note, single machine scheduling and minimizing absolute flow time deviation (TAFD) are considered. The relationship between this problem and the mean absolute deviation of job completion times about a common due date (MAD) is discussed. Based on the MAD problem optimal solutions of the TAFD problem are given. Furthermore, the generalization of the problem to the multiple machine case is discussed and an efficient algorithm for generating many optimal solutions of the problem, in the multi-machine case, is given.