全文获取类型
收费全文 | 2130篇 |
免费 | 125篇 |
国内免费 | 13篇 |
专业分类
化学 | 1596篇 |
晶体学 | 10篇 |
力学 | 65篇 |
数学 | 323篇 |
物理学 | 274篇 |
出版年
2024年 | 6篇 |
2023年 | 15篇 |
2022年 | 36篇 |
2021年 | 42篇 |
2020年 | 31篇 |
2019年 | 41篇 |
2018年 | 32篇 |
2017年 | 41篇 |
2016年 | 89篇 |
2015年 | 56篇 |
2014年 | 110篇 |
2013年 | 133篇 |
2012年 | 164篇 |
2011年 | 185篇 |
2010年 | 110篇 |
2009年 | 111篇 |
2008年 | 146篇 |
2007年 | 137篇 |
2006年 | 123篇 |
2005年 | 115篇 |
2004年 | 118篇 |
2003年 | 82篇 |
2002年 | 72篇 |
2001年 | 35篇 |
2000年 | 32篇 |
1999年 | 22篇 |
1998年 | 22篇 |
1997年 | 19篇 |
1996年 | 17篇 |
1995年 | 11篇 |
1994年 | 14篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 8篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 17篇 |
1984年 | 6篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 6篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1971年 | 2篇 |
1958年 | 2篇 |
排序方式: 共有2268条查询结果,搜索用时 0 毫秒
991.
992.
An online method for the analysis of volatile organic compounds in electronic cigarette aerosol based on proton transfer reaction mass spectrometry 下载免费PDF全文
993.
994.
Molecular Level Characterization of the Structure and Interactions in Peptide‐Functionalized Metal–Organic Frameworks 下载免费PDF全文
Dr. Tanya K. Todorova Dr. Xavier Rozanska Dr. Christel Gervais Dr. Alexandre Legrand Dr. Linh N. Ho Pierrick Berruyer Dr. Anne Lesage Prof. Lyndon Emsley Dr. David Farrusseng Dr. Jérôme Canivet Dr. Caroline Mellot‐Draznieks 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(46):16531-16538
We use density functional theory, newly parameterized molecular dynamics simulations, and last generation 15N dynamic nuclear polarization surface enhanced solid‐state NMR spectroscopy (DNP SENS) to understand graft–host interactions and effects imposed by the metal–organic framework (MOF) host on peptide conformations in a peptide‐functionalized MOF. Focusing on two grafts typified by MIL‐68‐proline ( ‐Pro ) and MIL‐68‐glycine‐proline ( ‐Gly‐Pro ), we identified the most likely peptide conformations adopted in the functionalized hybrid frameworks. We found that hydrogen bond interactions between the graft and the surface hydroxyl groups of the MOF are essential in determining the peptides conformation(s). DNP SENS methodology shows unprecedented signal enhancements when applied to these peptide‐functionalized MOFs. The calculated chemical shifts of selected MIL‐68‐NH‐ Pro and MIL‐68‐NH‐ Gly‐Pro conformations are in a good agreement with the experimentally obtained 15N NMR signals. The study shows that the conformations of peptides when grafted in a MOF host are unlikely to be freely distributed, and conformational selection is directed by strong host–guest interactions. 相似文献
995.
Frederic Gyselinck Ulrich Maschke Andre Traisnel Xavier Coqueret 《Liquid crystals》2013,40(3):421-428
Polymer dispersed liquid crystal (PDLC) films were prepared by polymerization-induced phase separation processes using ultraviolet (UV) and electron beam (EB) radiation. A mixture of the nematic LC material E7, an aromatic polyester acrylate, and additional monomeric acrylates was exposed to the EB radiation. A photoinitiator was included in the initial mixture in the case of UV exposure. The electro-optical behaviour of the PDLC films obtained has been investigated as a function of the chosen radiation. The transmission versus voltage curves strongly depend on the curing conditions, and are highly reproducible. Threshold and saturation voltages continuously increase with increasing dose values for UV-cured films, whereas plateau values were reached for EB-cured samples. A small memory effect has been observed for UV-cured systems. 相似文献
996.
Xavier Moreau Jean-Philippe Goddard Serge Thorimbert 《Journal of organometallic chemistry》2009,694(4):561-565
The platinum- and gold-catalyzed cycloisomerization of enyne systems has been carried out in various ionic liquids (ILs). In some cases, better selectivities and shorter reaction times have been observed compared to conventional conditions. 相似文献
997.
Mathematical constructions and comparisons of accurate absorbing boundary conditions for the one-dimensional Schrödinger equation with a general variable repulsive potential are developed. Stable semi-discretization schemes are built for the associated initial boundary value problems. Finally, some numerical simulations give a comparison of the various absorbing boundary conditions and show that they yield accurate computations. 相似文献
998.
999.
Dr. Francisco Núñez‐Zarur Dr. Xavier Solans‐Monfort Prof. Roser Pleixats Dr. Luis Rodríguez‐Santiago Prof. Mariona Sodupe 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(43):14553-14565
DFT (B3LYP‐D) calculations have been used to better understand the origin of the recovered Hoveyda–Grubbs derivative catalysts after ring‐closing diene or enyne metathesis reactions. For that, we have considered the activation process of five different Hoveyda–Grubbs precursors in the reaction with models of usual diene and enyne reactants as well as the potential precursor regeneration through the release/return mechanism. The results show that, regardless of the nature of the initial precursor, the activation process needs to overcome relatively high energy barriers, which is in agreement with a relatively slow process. The precursor regeneration process is in all cases exergonic and it presents low energy barriers, particularly when compared to those of the activation process. This indicates that the precursor regeneration should always be feasible, unlike the moderate recoveries sometimes observed experimentally, which suggests that other competitive processes that hinder recovery should take place. Indeed, calculations presented in this work show that the reactions between the more abundant olefinic products and the active carbenes usually require lower energy barriers than those that regenerate the initial precatalyst, which could prevent precursor regeneration. On the other hand, varying the precursor concentration with time obtained from the computed energy barriers shows that, under the reaction conditions, the precursor activation is incomplete, thereby suggesting that the origin of the recovered catalyst probably arises from incomplete precursor activation. 相似文献
1000.