Three-dimensional Fourier Fringe Analysis

Over the years two-dimensional Fourier Fringe Analysis (2D-FFA) has demonstrated both its capability and its relative robustness in analysing fringe patterns within a short time-frame from static objects. Nowadays, there is an increasing demand to measure dynamic objects. Today 2D-FFA is seen as a fast and flexible method of processing fringe patterns for dynamic objects. But it is still inherently a 2D approach, i.e. it deals with three-dimensional data (video sequences) on an individual 2D frame-by-frame basis. In this paper, a novel three-dimensional Fourier Fringe Analysis (3D-FFA) algorithm is proposed to demodulate fringe pattern sequences taken from dynamic objects. This technique processes the stack of fringe patterns as a single 3D volume, not as a set of individual 2D frames that are each processed in isolation. The proposed algorithm has been evaluated on both computer simulated and real dynamic objects. Results show that the proposed technique is able to demodulate fringe pattern volumes successfully.     

Kinetics of the acyl migration in some adducts of acyl-1, 4-benzoquinones: Part I

The rates of migration of acetyl, propionyl, isobutyryl, and benzoyl substituent in Diels-Alder adducts of acyl-1, 4-benzoquinones, (enediones), (I), to form the corresponding 2-acyl hydroquinones, (II), in 50% (v/v) ethanolic pyridine have been studied in detail. Rate dependence on pyridine concentration has been established and maximum rate was found at pyridine a volume percent of 25 in an ethanolic reaction mixture. The study indicated first-order dependence on reactants and fractional dependence on pyridine concentration. The effect of substituents of the acyl group on the rate showed that electronic factors play an important role on the stability of the transition state. A plausible mechanism, which is consistent with the results has been postulated and suitable rate law in consonance with the postulated mechanism have been derived.     

Spectrophotometric determination of zirconium in steels with xylenol orange

Zirconium (0.005–0.25%) is determined after acid dissolution of the steel, and fusion of insoluble matter with sodium carbonate and sodium hydrogensulphate. Niobium and other interfering ions are removed by mercury cathode electrolysis. Residual small amounts of iron(III) are masked with ascorbic acid.     

Two new rearranged taxoids from Taxus wallichiana ZUCC

Two new rearranged taxane diterpenoids, 5alpha,7beta,10beta,13alpha-tetrahydroxy-2alpha,9alpha,15-triacetoxy-11(15-->1)-abeo-taxa-4(20), 11-diene (1) and 5alpha,9alpha,10beta,13alpha-tetraacetoxy-15-hydroxy-11(15-->1)-abeo-taxa-4(20), 11-diene (2) have been isolated from the barks of Taxus wallichiana. The structures of these compounds have been confirmed by modern spectroscopic techniques.     

Synthesis and Structural Investigation of a Series of Noncentrosymmetric Cyclohexaphosphates: M(C6H5NH3)4P6O18?8H2O (M: Cd, Cu, Co)

Three new noncentrosymmetric cyclohexaphosphates with the general formula M(C₆H₅NH₃)₄ P₆O₁₈⋅8H₂O (M: Cd, Cu, Co) are synthesized. They crystallize in the monoclinic system, space group P2₁, Z = 2 and are isostructural. We have determined their structure from the Cd salt. This Cd salt exhibits the following unit-cell parameters: a = 9.852(1), b = 24.784(4), c = 9.2078(8) Å, β = 107.92(9)^∘, V = 2139.2(9) ų. The structure has been solved using direct method and refined to a reliability R factor of 0.042. The structure can be described as infinite anionic layers with composition of [Cd(P₆O₁₈)(H₂O)₈]⁴⁻ and parallel to the (1 0 1) plane. The charge compensation and the three-dimensional cohesion are performed by the protonated amine located between these inorganic layers.     

Assessment of Bhatiari Lake water quality: Pollution indices,hydrochemical signatures and hydro-statistical analysis

This study aimed at evaluating the water quality of Bhatiari Lake (BL) for the first time based on water quality parameters, pollution indices, hydrochemical signatures and hydro-statistical analysis. Lake water samples were collected from the lake during April–May 2019 and wide ranges of parameters were considered for the investigation. Except for COD and Fe, all the parameters were within the permissible limit. COD crossed Bangladesh standards and testing institution (BSTI) and United States environmental protection agency (USEPA) standards. In contrast, Fe crossed World health organization (WHO), Bureau of Indian Standards (BIS) and USEPA standards. Hydrochemical analysis indicated the water as soft-fresh where near neutral low-metal was noticed from the Ficklin-Caboi diagram. Ca²⁺-Mg²⁺-HCO₃^- type water was confirmed from Piper and Chadha diagram, whereas Durov and Schoeller's diagram were indicated the influence of Mg²⁺-HCO₃^-. The trend of cations and anions were Ca²⁺> Mg²⁺> Na⁺>K⁺ and HCO₃^? > Cl^? > NO₃^? > SO₄^2? > PO₄^3? as stated by pie chart. Most precipitation dominant water was confirmed from the Gibbs diagram. Principal component analysis (PCA), Cluster analysis (CA) and Correlation matrix (CM) indicated the co-existence of geogenic and anthropogenic sources for pollution. Good water quality was observed via an integrated approach namely degree of contamination (C_d), Single-Factor Pollution Index (SPI), Comprehensive pollution index (CPI), Heavy metal evaluation index (HEI), Heavy metal pollution index (HPI), Nemerow's pollution index (NPI) and Ecological risk index (ERI). In addition, water quality index (WQI) remarked the water is excellent. Taken collectively, the present study indicates the BL water can be considered pollution-free.     

Quantum chemical investigation on D-π-A-based phenothiazine organic chromophores with spacer and electron acceptor effects for DSSCs

Structural Chemistry - In this work, the newly designed phenothiazine-based organic dye (PT-BTBA, PT-EBTBA, and PT-EBTEBA) derivatives were screened and investigated for dye-sensitized solar cell...     

Vibrational study of phase transition in N-benzyl methyl ammonium dihydrogenmonophosphate monohydrate

Raman spectra (100-3200 cm(-1)) of polycrystalline samples of C(6)H(5)CH(2)NH(2)CH(3)H(2)PO(4).H(2)O were studied at temperature ranging from 77 to 350 K. By comparison with homologue compounds and calculated wavenumbers, an assignment of the observed bands is proposed. The thermal evolution of Raman spectra reveals an order-disorder phase transition at about 120 K involving the hydrogen bonds coupled with the distortion of the organic cations. The line at 244 cm(-1)assigned to tau(CH(3)) shows a remarkable evolution across the transition. Therefore, a careful analysis of the thermal evolution of this mode was performed using Porto model. The activation energy, obtained from the plot of Deltanu(1/2) versus temperature, is E(a)=1.27 kcal mol(-1). This value is of the same order of magnitude as the one found for homologue hydrogen bonded compounds.     

Vibrational and optical properties of a one‐dimensional organic–inorganic crystal [C6H14N]PbI3

Self‐assembled organic–inorganic [C₆H₁₄N]PbI₃ crystals were synthesized. The crystal structure consists of one‐dimensional semiconductor chains formed by infinite PbI₆ face‐sharing octahedra aligned along the a‐axis. The organic cations are linked to the inorganic chains by N H· · ·I hydrogen bonds and act as insulator barriers. The vibrational properties of [C₆H₁₄N]PbI₃ were studied using polarized Raman scattering and infrared (IR) absorption. The observed Raman and IR spectral features were identified by comparison with the vibrational properties of homologous compounds and with the vibrational wavenumbers calculated using the ab initio PM3 method. Moreover, the photoluminescence and diffuse reflectance of [C₆H₁₄N]PbI₃ single crystals, along with the UV‐Vis absorption of spin‐ coated films, were measured. A strong green‐blue luminescence due to radiative recombinations of 1D excitons is observed. The Stokes shift is estimated at 70 meV. Copyright © 2008 John Wiley & Sons, Ltd.