Thermal,electrical and optical properties of proton-irradiated Makrofol DE 7-2 nuclear track detector

Samples from sheets of the polymeric material Makrofol DE 7-2 have been exposed to 1 MeV protons of fluences in the range 2.5×10¹³–5×10¹⁵ p/cm². The resultant effect of proton irradiation on the thermal properties of Makrofol has been investigated using thermogravimetric analysis and differential thermal analysis (DTA). The onset temperature of decomposition T _o and the activation energy of thermal decomposition E _a were calculated, and the results indicated that the Makrofol detector decomposes in one weight loss stage. Also, the proton irradiation in the fluence range 7.5×10¹³–5×10¹⁵ p/cm² led to a more compact structure of Makrofol polymer, which resulted in an improvement in its thermal stability with an increase in the activation energy of thermal decomposition. The variation of transition temperatures with proton fluence has been determined using DTA. The Makrofol thermograms were characterized by the appearance of an endothermic peak due to the melting of the crystalline phase. The melting temperature of the polymer, T _m, was investigated to probe the crystalline domains of the polymer. At a fluence range of 7.5×10¹³–5×10¹⁵ p/cm², the defect generated destroys the crystalline structure, thus reducing the melting temperature. In addition, the V–I characteristics of the polymer samples were investigated. The electrical conductivity was decreased with the increasing proton fluence up to 5×10¹⁵ p/cm². Further, the refractive index, transmission of the samples and any color changes were studied. The color intensity Δ E was greatly increased with the increasing proton fluence and was accompanied by a significant increase in the red and yellow color components.     

Effect of experimental conditions on surface hardness measurements of calcified tissues via LIBS

This paper reports on the effects of LIBS experimental conditions on the measurement of the surface hardness of calcified tissues. The technique mainly depends on a previously demonstrated correlation between the intensity ratio of ionic to atomic spectral lines and the hardness of the target material. Three types of calcified tissues have been examined, namely enamel of human teeth, shells, and eggshells. Laser-induced breakdown spectra were obtained under two different experimental conditions. In the first nano and picoseconds, laser pulses were used in a single-pulse arrangement, while in the second, single- and double-pulse regimes with nanosecond laser excitation were utilized. The results show that the ionic to atomic spectral line intensity ratios are higher in the case of picosecond laser pulse for both Ca and Mg spectral lines. This effect has been justified in view of the repulsive force of the laser-induced shock waves which depends clearly on the target surface hardness and on the laser irradiance. The electron densities ratio (pico/nano) is shown to be strongly depending on the laser irradiance too. In the case of calcium, single-pulse ratios are higher than the double-pulse ratios, while there is no appreciable difference between both in the case of magnesium. The results obtained herein suggest that double-pulse nanosecond arrangement and the choice of a minor element such as Mg furnishes the best experimental conditions for estimating the surface hardness via LIBS spectra. To validate this method, it has been applied on two previously measured groups of teeth enamel, the first is of ancient Egyptians, and the second from Nubians and Ugandans. The results support the usefulness of this method for similar real-life applications.     

Forecasting the impact of environmental stresses on the frequent waves of COVID19

Nonlinear Dynamics - A novel approach to link the environmental stresses with the COVID-19 cases is adopted during this research. The time-dependent data are extracted from the online repositories...     

Modeling of colloid and colloid-facilitated contaminant transport in a two-dimensional fracture with spatially variable aperture

Mathematical models are developed for two-dimensional transient transport of colloids, and cotransport of contaminant/colloids in a fracture-rock matrix system with spatially variable fracture aperture. The aperture in the fracture plane is considered as a lognormally distributed random variable with spatial fluctuations described by an exponential autocovariance function. Colloids are envisioned to irreversibly deposit onto fracture surfaces without penetrating the rock matrix; whereas, the contaminant is assumed to decay, sorb onto fracture surfaces and onto colloidal particles, as well as to diffuse into the rock matrix. The governing stochastic transport equations are solved numerically for each realization of the aperture fluctuations by a fully implicit finite difference scheme. Emphasis is given on the effects of variable aperture on colloid and colloid-facilitated contaminant transport. Simulated breakthrough curves of ensemble averages of several realizations show enhanced colloid transport and more pronounced fingering when colloids are subject to size exclusion from regions of small aperture size. Moreover, it is shown that an increase in the fracture aperture fluctuations leads to faster transport and increases dispersion. For the case of contaminant/colloids cotransport it is shown, for the conditions considered in this work, that colloids enhance contaminant mobility and increase contaminant dispersion.Nomenclature b fracture aperture, L - c contaminant concentration in the fracture, M/L³ - c _m contaminant concentration in the rock matrix, M/L³ - c _o source contaminant concentration, M/L³ - c ^* contaminant concentration adsorbed onto fracture surfaces, M/L² - c _m ^* contaminant concentration adsorbed inside the rock matrix, M/M - d _p colloidal particle diameter, L - D hydrodynamic dispersion coefficient dyadic, L²/t - D Brownian diffusion coefficient for colloids and molecular diffusion coefficient for contaminants, L²/t - D _m effective diffusion coefficient in the rock matrix, L²/t - h total head potential in the fracture, L - K _f partition coefficient for contaminant sorption onto fracture surfaces, L - K _m contaminant partition coefficient in the rock matrix, L³/M - K _n partition coefficient for contaminant sorption onto suspended colloids, L - K _n* partition coefficient for contaminant sorption onto deposited colloids, L³/M - _x fracture length in thex-direction, L - _y fracture length in they-direction, L - n colloid concentration in the liquid phase, M/L³ - n _o source colloid concentration, M/L³ - n ^* colloid concentration adsorbed onto fracture surfaces, M/L² - n _max ^* maximum deposited colloid concentration on fracture surfaces, M/L² - N ^* number of deposited colloidal particles per unit surface area of the fracture, 1/L² - N _max ^* maximum number of deposited colloidal particles per unit surface area of the fracture, 1/L² - q ^* diffusive mass flux into the rock matrix, M/L²t - R retardation factor in the fracture - R _m retardation factor in the rock matrix - s contaminant concentration adsorbed on colloids in the liquid phase, M/M - s _o source solid-phase contaminant concentration onto suspended colloids, M/M - s ^* contaminant concentration adsorbed on deposited colloids, M/M - t time, t - U interstitial velocity vector, L/t - x coordinate along the fracture length, L - y coordinate along the fracture width, L - z coordinate perpendicular to the fracture plane, L - area blocked by a deposited colloidal particle, L² - _L longitudinal dispersivity, L - _T transversal dispersivity, L - fluid specific weight, M/L²t² - fraction of the fracture surface physically covered by colloids - gz dummy integration variable - porosity of the rock matrix - colloid deposition coefficient, L - first-order decay coefficient, 1/t - fluid dynamic viscosity, M/Lt - defined in (18) - _b bulk density of the rock matrix, M/L³ - _p colloidal particle density, M/L³ - standard deviation of the lognormally distributed fluctuations of the fracture aperture