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991.
J. Salgado E. Martinho I. F. Gonçalves 《Journal of Radioanalytical and Nuclear Chemistry》2004,260(2):317-320
The resonance neutron self-shielding factor, G
res, is required in neutron metrology and activation data analysis. In a previous paper, the authors have shown that a dimensionless
variable can be introduced which converts the dependence of G
res on the physical and nuclear properties of the material samples into an universal curve, valid for the isolated resonances
of any nuclide. This work presents a methodology based on the universal curve, which enables to calculate G
res for a group of isolated resonances by weighting its individual contributions. A good agreement was reached with results calculated
by the MCNP code and with experimental values for Mo foils and wires.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
992.
A. V. Burenin 《Optics and Spectroscopy》2004,97(5):701-706
The energy levels of the cyclopentane molecule are classified taking into account pseudorotation and inversion motion caused by the nonplanarity of the equilibrium configuration of the five-membered cycle of the carbon nuclei of the molecule. For this purpose, the relatively recently developed symmetry-group chain methods, which are the most powerful methods at present, are used. 相似文献
993.
C. Bourrely I. Caprini L. Micu 《The European Physical Journal C - Particles and Fields》2003,27(3):439-446
We derive dispersion relations for decay, using the Lehmann-Symanzik-Zimmermann formalism, which allows the analytic continuation of the amplitudes with respect
to the momenta of the external particles. No off-shell extrapolation of the field operators is assumed. We obtain generalized
Omnès representations, which incorporate the and S-wave phase shifts in the elastic region of the direct and crossed channels, according to the Watson theorem. The contribution
of the inelastic final-state and initial-state interactions is parameterized by the technique of conformal mappings. We compare
our results with previous dispersive treatments and indicate how the formalism can be combined with lattice calculations to
yield physical predictions.
Received: 14 October 2002 / Published online: 14 February 2003 相似文献
994.
We study the ill-posedness question for the one-dimensional Zakharov system and a generalization of it in one and higher dimensions. Our point of reference is the criticality criteria introduced by Ginibre, Tsutsumi and Velo (1997) to establish local well-posedness.
995.
996.
997.
N. A. A. Rossi R. G. Jones S. J. Holder 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):30-40
ABA block copolymers of methyl methacrylate and methylphenylsilane were synthesized with a methodology based on atom transfer radical polymerization (ATRP). The reaction of samples of α,ω‐dihalopoly(methylphenylsilane) with 2‐hydroxyethyl‐2‐methyl‐2‐bromoproprionate gave suitable macroinitiators for the ATRP of methyl methacrylate. The latter procedure was carried out at 95 °C in a xylene solution with CuBr and 2,2‐bipyridine as the initiating system. The rate of the polymerization was first‐order with respect to monomer conversion. The block copolymers were characterized with 1H NMR and 13C NMR spectroscopy and size exclusion chromatography, and differential scanning calorimetry was used to obtain preliminary evidence of phase separation in the copolymer products. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 30–40, 2003 相似文献
998.
There are consistently estimable parameters of interest whose semiparametric Fisher information vanishes at some points of the model in question. Here we investigate how bad this is for estimation. 相似文献
999.
Independent systems, each containing an atomic ensemble entangled through the interaction with its own photon, can be, in turn, entangled in the course of measurements. Schemes for preparing states of the W and Greenberger-Horne-Zeilinger (GHZ) classes with the use of projective measurements of light that include three-photon parametric interactions are proposed and analyzed. 相似文献
1000.
I. Capek J. Chudej S. Janí
kov 《Journal of polymer science. Part A, Polymer chemistry》2003,41(6):804-820
The sterically stabilized emulsion polymerization of styrene initiated by a water‐soluble initiator at different temperatures has been investigated. The rate of polymerization (Rp) versus conversion curve shows the two non‐stationary‐rate intervals typical for the polymerization proceeding under non‐stationary‐state conditions. The shape of the Rp versus conversion curve results from two opposite effects—the increased number of particles and the decreased monomer concentration at reaction loci as the polymerization advances. At elevated temperatures the monomer emulsion equilibrates to a two‐phase or three‐phase system. The upper phase is transparent (monomer), and the lower one is blue colored, typical for microemulsion. After stirring such a multiphase system and initiation of polymerization, the initial coarse polymer emulsion was formed. The average size of monomer/polymer particles strongly decreased up to about 40% conversion and then leveled off. The initial large particles are assumed to be highly monomer‐swollen particles formed by the heteroagglomeration of unstable polymer particles and monomer droplets. The size of the “highly monomer” swollen particles continuously decreases with conversion, and they merge with the growing particles at about 40–50% conversion. The monomer droplets and/or large highly monomer‐swollen polymer particles also serve as a reservoir of monomer and emulsifier. The continuous release of nonionic (hydrophobic) emulsifier from the monomer phase increases the colloidal stability of primary particles and the number of polymer particles, that is, the particle nucleation is shifted to the higher conversion region. Variations of the square and cube of the mean droplet radius with aging time indicate that neither the coalescence nor the Ostwald ripening is the main driving force for the droplet instability. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 804–820, 2003 相似文献