Vinylic MIDA Boronates: New Building Blocks for the Synthesis of Aza‐Heterocycles

A two‐step synthesis of structurally diverse pyrrole‐containing bicyclic systems is reported. ortho‐Nitro‐haloarenes coupled with vinylic N‐methyliminodiacetic acid (MIDA) boronates generate ortho‐vinyl‐nitroarenes, which undergo a “metal‐free” nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide substrate tolerance and it is applicable in the preparation of more complex “drug‐like” molecules. Interestingly, an ortho‐nitro‐allylarene derivative furnished a cyclic β‐aminophosphonate motif.     

Synthesis and luminescence properties of hybrid systems based on liquid crystal terbium(ІІІ) and europium(ІІІ) complexes

Russian Journal of General Chemistry - Hybrid liquid crystal systems with different ratios of the components have been prepared on the basis of 5,5′-di(heptadecyl)-2,2′-bipyridine...