Scattering of solitons for the Schrödinger equation coupled to a particle

We establish soliton-like asymptotics for finite energy solutions to the Schrödinger equation coupled to a nonrelativistic classical particle. Any solution with initial state close to the solitary manifold converges to a sum of a travelling wave and an outgoing free wave. The convergence holds in global energy norm. The proof uses spectral theory and the symplectic projection onto the solitary manifold in the Hilbert phase space.     

On the variational representation of solutions to some quasilinear equations and systems of hyperbolic type on the basis of potential theory

We demonstrate a method that permits to obtain generalized solutions for some quasilinear equations and systems of hyperbolic type. The corresponding variational principle is constructed using the theory of equilibrium of a potential in an external field. Dedicated to the memory of B. M. Levitan Supported by RFBR grants Nos. 05-01-00522 and NSh-1551.2003.1, by Program No. 1 of the Branch of Mathematics, Russian Academy of Sciences, and by INTAS project No. 03-51-6637.     

Advantages of NIR radiation use for optical determination of skin horny layer thickness with embedded TiO2 nanoparticles during tape stripping procedure

The tape stripping technique is an experimental method frequently used for reconstruction of the in-depth distribution of various topically administered substances within the horny layer of human skin, e.g., compounds contained in sunscreens. Titanium dioxide (TiO₂) nanoparticles (25–200 nm in diameter) are one such compound. Optical techniques which apply blue light are found to be suitable for reconstruction. However, the presence of particles affects the light propagation within the skin and therefore causes incorrect determination of strip thickness, leading to an improper reconstructed distribution of nanoparticle concentration revealed from the experimental data. This study evaluates the errors emerging from the use of blue (400 nm) and NIR (800 nm) radiation and finds the use of longer wavelength light more advantageous. Particles of different diameters are considered, and it is revealed that the application of small particles (25–60 nm) results in the lowest rate of error.     

General strategy for a short and efficient synthesis of 3-hydroxy-4-methylprolines (HMP)

The non-proteinogenic amino acid 3-hydroxy-4-methylproline (HMP) is an active constituent of some potent antimicrobials including echinocandins, nostopeptins, pneumocandins, sporiofungin and mulundocandins. A synthesis has been achieved in 10 steps with 29% overall yield; the Evans’ aldol reaction using Crimmins’ modified method was pivotal to the success of the strategy.     

Direct C–H arylation of 3-methoxythiophene catalyzed by Pd. Application to a more efficient synthesis of π-alkoxy-oligothiophene derivatives

The direct regioselective C–H arylation of 3-methoxythiophene and 3,4-ethylenedioxythiophene (EDOT) was performed successfully under ‘Heck-type’ experimental conditions. This novel synthetic methodology has been used to prepare in a more simple way a series of oligothiophenes interesting for the electronic industry to build new synthetic organic materials.     

Standard enthalpy of formation of La2CoO4(cr)

The enthalpies of reactions of La₂CoO₄(cr) and CoCl₂(cr) with hydrochloric acid were measured with an isothermal-jacket calorimeter. The results obtained and the available literature data were used to calculate the standard enthalpy of formation of La₂CoO₄(cr) at 298.15 K, Δ_f H ^o = ?2179 ± 7 kJ/mol.