Disappearance of Superconductivity and a Concomitant Lifshitz Transition in Heavily Overdoped Bi_2Sr_2CuO_6 Superconductor Revealed by Angle-Resolved Photoemission Spectroscopy

By partially doping Pb to effectively suppress the superstructure in single-layered cuprate Bi_2Sr_2CuO_(6+δ)(Pb-Bi2201) and annealing them in vacuum or in high pressure oxygen atmosphere, a series of high quality Pb-Bi2201 single crystals are obtained with T_c covering from 17 K to non-superconducting in the overdoped region. High resolution angle resolved photoemission spectroscopy measurements are carried out on these samples to investigate the evolution of the Fermi surface topology with doping in the normal state. Clear and complete Fermi surfaces are observed and quantitatively analyzed in all of these overdoped Pb-Bi2201 samples. A Lifshitz transition from holelike Fermi surface to electron-like Fermi surface with increasing doping is observed at a doping level of ~0.35. This transition coincides with the change that the sample undergoes superconducting-to-non-superconducting states.Our results reveal the emergence of an electron-like Fermi surface and the existence of a Lifshitz transition in heavily overdoped Bi2201 samples. This provides important information in understanding the connection between the disappearance of superconductivity and the Lifshitz transition in the overdoped region.     

聚甲苯胺蓝-(多壁碳纳米管/PDDA)n杂化膜修饰电极的制备及其对NADH的催化氧化

导电聚合物修饰电极由于聚合物结构致密,限制了底物在聚合物膜中的渗透,且随着膜厚的增加其导电能力逐渐减弱.碳纳米管在导电聚合物中的掺杂明显改善了导电聚合物的导电性~([1]).但是碳纳米管的水溶性差及纳米尺寸带来的聚集效应,使得通过主体聚合制备杂化膜的过程中容易出现相分离进而影响到杂化膜的性质~([2]).     

氧化锰表面改性活性炭电极材料的电化学特性

用Mn(NO3)2溶液浸渍-高温热解法对普通活性炭进行表面改性处理以改善其电化学性能. 采用氮气吸附、SEM、XRD等方法研究改性活性炭的比表面积、孔结构、形貌和氧化锰的晶体结构; 用循环伏安、恒流充放电、交流阻抗等电化学方法研究了改性活性炭电极构成的电化学电容器的性能. 结果表明, Mn(NO3)2热解产生的多价态氧化锰有法拉第赝电容效应, 尤其是立方晶形结构的α-Mn2O3, 与活性炭的双电层电容构成了复合电容, 因而改性炭材料的比电容有明显的提高, 其质量比电容达到254 F·g-1, 比未改性炭的165 F·g-1提高了54%. 改性炭电极电化学电容器具有优异的充放电可逆性和稳定性, 而且等效串联电阻较小, 只有0.40 Ω; 经2000次循环的长期测试, 容量保持率几乎达到100%.     

Detailed electronic structure of three-dimensional Fermi surface and its sensitivity to charge density wave transition in ZrTe_3 revealed by high resolution laser-based angle-resolved photoemission spectroscopy

The detailed information of the electronic structure is the key to understanding the nature of charge density wave(CDW) order and its relationship with superconducting order in the microscopic level. In this paper, we present a high resolution laser-based angle-resolved photoemission spectroscopy(ARPES) study on the three-dimensional(3 D) hole-like Fermi surface around the Brillouin zone center in a prototypical quasi-one-dimensional CDW and superconducting system ZrTe_3. Double Fermi surface sheets are clearly resolved for the 3 D hole-like Fermi surface around the zone center. The3 D Fermi surface shows a pronounced shrinking with increasing temperature. In particular, the quasiparticle scattering rate along the 3 D Fermi surface experiences an anomaly near the charge density wave transition temperature of ZrTe_3(～ 63 K). The signature of electron–phonon coupling is observed with a dispersion kink at ～ 20 me V; the strength of the electron–phonon coupling around the 3 D Fermi surface is rather weak. These results indicate that the 3 D Fermi surface is also closely connected to the charge-density-wave transition and suggest a more global impact on the entire electronic structure induced by the CDW phase transition in ZrTe_3.     

6H-SiC衬底上AlGaN基垂直结构紫外LED的制备

利用金属有机物化学气相沉积方法,在n型6H-SiC衬底上制备了15对Si掺杂Al_(0.19)Ga_(0.81)N/Al_(0.37)Ga_(0.63)N DBR,并采用低温AlN缓冲层有效抑制了DBR结构中裂纹的产生,得到了表面均方根粗糙度仅为0.4 nm且导电性能良好的n型DBR,其在369 nm处峰值反射率为68%,阻带宽度为10 nm。在获得导电DBR的基础上,进一步在n型6H-SiC衬底上构建了有、无DBR的垂直结构紫外LED。对比两者电致发光光谱,发现DBR结构的引入有效增强了LED紫外发光强度。     

某机载红外转塔低温像面抖动的分析与研究

针对某机载红外转塔在低温环境下会产生像面抖动的现象,分析了引起像面抖动的主要因素,通过建立模型、热力学分析和静力分析,得出在低温环境下俯仰支架变形量最大为0.34 mm,承受加速度过载下变形最大为0.46 mm。通过对俯仰支架进行调整、固化形态,使俯仰组件低温转动平滑,应力变形量在0.05 mm以内。同时对旋变布线方式及电机电刷安装位置提出了改进措施并给出了控制数据,解决了某机载红外转塔低温像面抖动问题。     

循环跃迁的Δ 型三能级系统中的无反转激光

研究了在引入非相干抽运的情况下,循环跃迁的Δ型共振三能级系统中产生的无反转激光.利用主方程的方法, 导出了缀饰态中强相干场极限下布居数项和相干项的稳态近似解析解以及产生无反转激光所需要满足的条件;并利用数值模拟的方法讨论了布居数分布、 系统增益对探测场和相干场拉比频率的依赖性以及随时间的演化规律. 结果表明:无论各个参量取何值,共振Δ型三能级系统总是处于无粒子数反转的状态; 只要探测场或相干场之中有一个为强场,便可产生无反转激光; 当其中任意一个场远强于另一个场时,系统的无反转增益将不再依赖于任何一个场的拉比频率.     

Duhamel项的精细积分方法在非线性微分方程数值求解中的应用

基于Duhamel项的精细积分方法,构造了几种求解非线性微分方程的数值算法。首先将非线性微分方程在形式上划分为线性部分和非线性部分,对非线性部分进行多项式近似,利用Duhamel积分矩阵,导出了非线性方程求解的一般格式。然后结合传统的数值积分技术,例如Adams线性多步法等,构造了基于精细积分方法的相应算法。本文算法利用了精细积分方法对线性部分求解高度精确的优点,大大提高了传统算法的数值精度和稳定性,尤其是对于刚性问题。本文构造的算法不需要对线性系统矩阵求逆,可以方便的考察不同的线性系统矩阵对算法性能的影响。数值算例验证了本文算法的有效性,并表明非线性系统的线性化矩阵作为线性部分是比较合理的选择。     

A New Algorithm of Time Stepping in Dynamic Viscoelastic Problems

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时域自适应精细算法求解对流热传导问题

应用时域自适应精细算法求解对流传热问题.通过展开技术,可更准确地描述变量随时间的变化,同时将时空耦合的初边值问题转化为一系列的空间边值问题,并采用有限元方法递推求解.自适应技术可弥补时间步长不同时可能造成的计算精度损失.并进行了数值检验.