十八烷@聚甲基丙烯酸甲酯微胶囊相变材料的制备及表征

采用乳液聚合法合成了Oct@PMMA微胶囊相变材料,以聚乙烯吡咯烷酮作为分散剂,季戊四醇四丙烯酸酯作为交联剂改善微胶囊储热性能与热稳定性;采用FT-IR、XRD、DSC和TG等技术对微胶囊的化学和物理性质进行了表征。结果表明,聚乙烯吡咯烷酮通过提高乳液液滴的稳定性和分散程度,提升了微胶囊的热力学性能及收率,相变焓值达到105.6 J/g,收率达到98.01%,季戊四醇四丙烯酸酯改善了微胶囊的热稳定性,热降解温度达到175℃。     

基于人工神经网络的肉类光谱识别

利用自组的光纤探头式光谱仪对载体肉类表面进行光谱测量,采用反向传播人工神经网络(BP-ANN)对肉类可见光谱进行识别,分析了隐层神经元、期望误差、判别输出范围等网络参数的调整对识别功能的影响.基于大量实测数据样本,优化网络结构参数选择,建立了良好的人工神经网络,对肉类光谱识别率达到97.5%.     

谷氨酸钠溶液514nm激光拉曼光谱受环境光影响的研究

探讨了环境光的存在对谷氨酸钠溶液的514 nm绿色激光激发的拉曼光谱的影响.研究表明不同的环境光、自然光和室内荧光灯光均会对514 nm激光拉曼光谱产生干扰,存在着特征干扰峰.自然阳光干扰较小;而荧光灯光表现为1127、2107 cm-1和2170 cm-1等3个明显尖锐的脉冲峰,不能忽略.建议在进行谷氨酸钠溶液514 nm绿色激光拉曼光谱检测时,须在暗室或暗罩中进行,以完全隔离环境光的影响.     

Adjacency effect estimation by ground spectra measurement and satellite optical sensor synchronous observation data

This paper addresses the estimation of adjacency effect of CBERS-2 image. The adjacency effect influences the digital number (DN) value of a pixel by adding surrounding scattering signals and path scattering signals. Based on the theory of radiation transfer model, a procedure is designed to measure the reflectance from the surface target materials and the materials in a box, which is 1.5 m above the surface to avoid upwelling reflectance. The results show that the adjacency effect varies from visible, near infrared and becomes steady within short infrared wavelength region; the adjacency effect weakens with the increase of distance between testing sites. The adjacency effect of CBERS-2 image is corrected and the quality of the resulting image is improved.     

同位镀铋膜电极测定爆米花中的痕量铅

采用同位镀铋膜法修饰铂电极,用差分脉冲溶出伏安法对爆米花中痕置铅进行了测定,并优化了实验条件.在优化的实验条件下,分别对2.0×10<'8>-6.0×10<'-7>mol/L和6.0×10<'-7>-1.0×10<'-4>mol/L的pb<'2+>进行了测定,Pb<'2+>溶出峰电流与Pb<'2+>浓度呈良好的线性关系...     

多层栅介质层有机薄膜晶体管的存储与光响应特性

在真空室内一次性制备了具有多层栅介质层结构的有机薄膜晶体管(OTFTs).结果表明,制备的OTFTs具有电控开关、存储和光敏多重功能特性.分析认为,存储特性归功于器件的结构,采用了分离的CaF2纳米粒子岛作为电荷俘获中心.在光照环境下,观察到了两种不同类型的光响应特性.快速的光响应来自于有源层吸收了能量大于带隙的光子所...     

α-苯甲胺基-β-(3-吲哚基)-丙酸甲酯的合成

以L-色氨酸为原料经过4步得到α-苯甲胺基-β-(3-吲哚基)-丙酸甲酯,它是一种具有潜在的抗肿瘤活性的吲哚二酮哌嗪化合物的中间体,首先通过“酰氯法”合成L-色氨酸甲酯盐酸盐,再脱去盐酸,与苯甲醛发生缩合反应形成希夫碱,最后选择性还原,得目的产物,得率54.9%.     

δ-(Zn,Cr)S(111)表面上的Dzyaloshinsky-Moriya作用:第一性原理计算

根据密度泛函理论的第一性原理计算了具有非中心反演对称的异质结δ-(Zn,Cr)S(111)体系的原子结构和电子结构.Cr原子之间通过第一层S原子传递磁性相互作用.结合广义布洛赫条件,又进一步计算了反方向的自旋螺旋能量与波矢的色散关系E(q)与E(-q).E(q)与E(-q)能量之差反映了δ-(Zn,Cr)S(111)的S层与Cr层之间空间反演对称性破缺引起的DMI的大小.通过海森伯相互作用(HBI)模型与Dzyaloshinsky-Moriya作用(DMI)模型拟合第一性原理计算值,得到了Cr原子间各近邻的HBI参数J_1-J_4与DMI参数d-_1,d_2.在δ-(Zn,Cr)S(111)中,Cr原子间的耦合为M型反铁磁.DMI参数d_1为-0.53 meV,为顺时针手性DMI,在δ-(Zn,Cr)S(111)界面上有可能会产生斯格明子.本文计算表明,磁性和非磁性半导体界面有可能存在DMI,为理论研究和磁存储技术的进步开拓一个新的方向.     

重离子冷却储存环CSRm双电子复合实验研究类锂36,40Ar15+离子同位素移动

配备电子冷却装置的重离子储存环为开展高电荷态离子的双电子复合（dielectronic recombination,DR）精密谱学研究提供了绝佳的实验平台。本工作在兰州重离子加速器冷却储存环主环（HIRFL-CSRm）上开展了类锂36,40Ar15+离子的双电子复合实验,实验观测了电子-离子质心系能量范围为0~35 eV的双电子复合速率系数谱。通过外推法获得了36,40Ar15+离子2s_1/2→2p_1/2和2s_1/2→2p_3/2的跃迁能量。同时利用GRASP2K程序理论计算了36,40Ar15+离子2s_1/2→2p_1/2和2s_1/2→2p_3/2跃迁的质量移动因子和场移动因子,进而得到双电子复合谱的同位素移动值。36,40Ar15+离子2s_1/2→2p_1/2和2s_1/2→2p_3/2同位素移动分别为0.861 meV和0.868 meV。它们均小于目前CSRm上双电子复合实验的实验分辨为~10 meV,进而解释了实验测量的DR谱上未能观察到同位素移动的原因。然而,高电荷态离子的同位素移动场效应与原子序数Z5成正比,因此,在重离子加速器冷却储存环实验环（HIRFL-CSRe）以及未来大型加速器--强流重离子加速器装置（HIAF）上有望通过DR精密谱学方法研究高电荷态重离子甚至放射性离子的同位素移动,进而获得相关原子核的核电荷半径等信息。The cooler storage ring is equipped with an electron-cooler. It is an excellent experimental platform for dielectronic recombination (DR) experiment of highly-charged ions. In this paper, the dielectronic recombination experiments of lithium-like Ar15+ ions with mass number 36 and 40 are conducted at the HIRFL-CSRm(main ring of the Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou). The experimental electron-ion collision energy scale is from 0 eV to 35 eV. Extrapolation method is exploited to obtain the excitation energies of transitions 2s_1/2→2p_1/2 and 2s_1/2→2p_3/2 of the 36,40Ar15+ ions from experimental data. Meanwhile, GRASP2K program is utilized to calculate the mass shift factors and field shift factors of 36,40Ar15+ ions for 2s_1/2→2p_1/2 and 2s_1/2→2p_3/2 transitions to obtain isotope shifts in DR spectra. In theoretical calculation, isotope shifts of 36,40Ar15+ ions corresponding to 2s_1/2→2p_1/2 and 2s_1/2→2p_3/2 are 0.861 meV and 0.868 meV, respectively. They are both less than the experimental precision (~10 meV) of these dielectronic recombination experiments at the CSRm, which explains that isotope shifts cannot be distinguished from the experimental dielectronic recombination spectra. However, the field shift of highly-charged ions is proportional to Z5. In the future, the dielectronic recombination experiments of highly-charged heavy ions even radioactive ions will be conducted at the HIRFL-CSRe (experimental ring of the Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou) and the future large accelerator facility--HIAF(High intensity Heavy-ion Accelerator Facility) to measure isotope shifts to obtain the nuclear charge radius information.