沉淀剂对水热合成Sr2CeO4形貌及发光性质的影响

分别以(NH4)2CO3、Na2CO3为沉淀剂,采用水热法合成了Sr2CeO4蓝白光荧光粉.利用热重-差热、红外光谱及X射线衍射分析了不同沉淀剂所得前驱体的热分解过程及目标产物的形成过程;利用扫描电镜、荧光分光光度计分别对荧光粉的微观形貌、发光特性进行了分析表征.结果表明:以(NH4)2CO3、Na2CO3为沉淀剂所得前驱体晶相组成相同,均由Ce2(CO3)2O·H2O、CeCO3OH及SrCO3三相组成,经1000℃下焙烧2h均得到正交晶相的SF2CeO4.以(NH4)2CO3为沉淀剂所得样品呈类球形,分散性较好;以Na2CO3为沉淀剂所得样品呈不规则形状,团聚现象严重.所得Sr2CeO4的激发光谱均是位于200 ～400 nm之间的一个宽带双峰结构,发射光谱均是位于400～600nm之间的一个宽带,最大发射峰位于466nm左右,归属于Ce4+的f→t1g跃迁,呈蓝白光发射.在最大激发波长下,以(NH4)2CO3为沉淀剂所得样品的发光强度相对较大.     

铷原子气体自旋噪声谱的测量与改进

利用自主设计并制作的基于现场可编程门阵列的实时傅里叶变换采集卡(FFTsDAC),采用线偏振光检测碱金属铷原子气样品中的自旋随机涨落(即自旋噪声谱).详细讨论了背景噪声以及自旋噪声随探测光光强的变化关系,证实了自旋噪声来自于系统中自旋的随机涨落.对比了两种FFTsDAC(8 bit采样的FFTsDACl和12 bit采样的FFTsDAC2)的测量性能,分析了影响实验信噪比的因素.FFTsDAC2具有更高的测量效率和采样深度以及更长的单次采样时间,因而具有更高的信噪比和更好的频率分辨率,与数值模拟的结果一致.     

基于PSIM机载大视场宽谱段偏振光谱成像系统光学设计

为满足偏振光谱成像探测中对于大视场、宽谱段技术要求,设计了一种基于偏振强度调制技术(PSIM)的宽谱段大视场偏振光谱成像仪。针对前置望远镜组,文中对现有国内玻璃材料消色差分析,优选了可见至短波红外的复消色差玻璃,通过控制镜组中PSIM模块光线角度,实现大视场内在PSIM模块上的入射角度需求。结合分析结果,采用光学设计软件优化设计。设计结果表明,前置望远系统能够实现波段为400～1 700 nm,视场角为72°,焦距为20 mm, F数为4的高质量成像,全谱段内探测器截止频率处传递函数优于0.4, PSIM模块上最大入射角度为±4.99°,有效保证了各视场内偏振调制的一致性。后置光谱分光系统采用基于Offner结构的凸面光栅,优化结果显示各波段点列图均小于一个像元,在探测器奈奎斯特频率处中心波长的MTF达到0.6,各项指标均满足设计要求。本文对于基于PSIM宽谱段偏振光谱成像仪器的工程化具有很重要的现实意义,对宽谱段光学系统消色差设计也具有一定指导意义。     

Microwave-promoted pure host phase for red emission CaS：Eu2＋ phosphor from single CaSO4 precursor and the photoluminescence property

We report a novel approach to obtaining a classical blue-green excitable CaS：Eu2＋ phosphor with desired red emission by microwave （MW） firing procedure in the absence of adding elemental sulphur. The disturbing effect of MW electro- magnetic field on decomposition of CaSO4 into CaS activated by europium is distinctly observed to give pure host phase without adding any elemental sulphur and carbon. The host phase evolution is observed to be highly dependent on the variation of applied MW power from X-ray diffraction （XRD） patterns and the corresponding photoluminescence （PL）, and a maximum PL intensity at 1100 W of MW power is acquired for the obtained purer host phase. The non-thermal and non-equilibrium effects by MW are revealed to correlate with the interaction between polar structure of the host and applied electromagnetic field. The results demonstrate an optional procedure to prepare this red-emitting phosphor in an effective, environment-friendly and scalable approach for phosphor production in the application of bio-illumination for plant cultivation and artificial photosynthesis.     

Spin Squeezing and Fixed-Point Bifurcation

We study spin squeezing and classical bifurcation in a nonlinear bipartite system. We show that the spin squeezing can be associated with a fixed-point bifurcation in the classical dynamics, namely, it acts as an indicator of the classical bifurcation. For the ground state of a system with coupled giant spins, we find that the spin squeezing achieves its minimum value near the bifurcation point. We also study the dynamics of the spin squeezing, for an initial state corresponding to one of the fixed point, we find that in the stable regime, the spin squeezing exhibits periodic oscillation and always persists except at some fixed times, while in the unstable regime, the periodic oscillation phenomenon disappears and the spin squeezing survives for a short time. Finally, we show that the mean spin squeezing, which is defined to be averaged over time, attains its minimum value near the bifurcation point.     

Reduced Fidelity Susceptibility in One-Dimensional Transverse Field Ising Model

We study critical behaviors of the reduced fidelity susceptibility for two neighboring sites in the onedimensional transverse field Ising model. It is found that the divergent behaviors of the susceptibility take the form of square of logarithm, in contrast with the global ground-state fidelity susceptibility which is power divergence. In order to perform a scaling analysis, we take the square root of the susceptibility and determine the scaling exponent analytically and the result is further confirmed by numerical calculations.     

同轴双方柱气动力载荷的相互干扰

本文研究了在大气边界层气流中同轴双方柱气动力载荷的相互干扰,讨论了这种干扰与风向角和间距比之间的关系.结果表明处于相邻方柱的干扰下,上游方柱的最大气动力载荷大于单体的载荷;而下游方柱则受到前柱明显的阻挡作用,不仅如此,当风向角为0°,小间距下的后柱,不但没有阻力,还会受到反向的摧力.还发现在串列情况下存在和双圆柱类似的临界间距,阻力和升力在临界间距附近有明显的突变.同时将本实验的结果和一些文献中的结果进行了比较.     

非线性超声束的冲击波形成研究

通过用频域方法数值求解KZK方程;以活塞声场为例,研究了非线性超声束的冲击波形成规律。结果表明:除了非线性强度、吸收外,衍射是另一个影响非线性超声束冲击波形成的重要因素。文章发现在不同的衍射条件下的活塞声场的冲击波形成距离有很大差异。最后,还比较了不同参数下冲击波形成时的声压波形和冲击波形成的空间分布。     

微波溶样AAS法测定新疆杏脯中的微量元素

微波溶样技术是近年来产生的一种嵌新的极有前途的溶样技术。本文采用微波消解溶样，利用原子吸收法对新疆食用杏脯中甘些微量元素含量进行测定，进行了消化条件及消化结果的准确度、精密度等试验，结果表明高压微波消化法具有消解完全、结果准确的优点。     

HPLC-ELSD与GC-MS法测定牛乳甘油三酯sn-2位脂肪酸组成

研究建立了快速、准确测定牛乳脂肪甘油三酯sn-2位脂肪酸组成的方法．利用胰脂酶专一水解甘油三酯sn-1和sn-3位置上的脂肪酸得到sn-2单甘油酯和游离脂肪酸,再通过蒸发光散射高效液相色谱分离出sn-2位单甘油酯,然后对其进行衍生,用气相色谱质谱联用仪对sn-2脂肪酸组成进行分析．结果显示用蒸发光散射高效液相色谱法分离sn-2位单甘油酯时方法的回收率达到83．3％～85．1％,该法省去了传统测定中费时费力的薄层色谱分离步骤．用气相色谱质谱联用法对产物进行分析,精密度高,结果可靠．分析结果表明,牛乳脂肪sn-2位脂肪酸由2．57％月桂酸、7．68％豆蔻酸、34．74％棕榈酸、11．56％亚油酸、22．53％油酸和15．21％硬酯酸组成．