三叔丁基膦亚胺苯氧钛配合物及其乙烯聚合性能

四种不同基团取代的苯酚锂盐分别与三叔丁基膦亚胺三氯化钛进行反应,制得相应三叔丁基膦亚胺苯氧钛配合物(t-Bu_3)PNTi(OAr)Cl_2[OAr=O-C_6H_5(4a),O-2,6-Me_2C_6H_3(4b),O-2,6-i-Pr_2C_6H_3(4c)和O-2,6-t-Bu_2C_6H_3(4d)],产物均借助~1H NMR,~(13)C NMR,~(31)P NMR及元素分析进行了结构表征,并利用X射线单晶衍射确定了配合物三叔丁基膦亚胺三氯化钛(3),4b和4d的分子结构.在助催化剂甲基铝氧烷(MAO)作用下,4a~4d对乙烯聚合均表现出高催化活性,并随配合物空间位阻增加而升高.4c热稳定性好,通过控制聚合反应条件,由此可以得到不同分子量及分子量分布的聚乙烯产物.     

模糊随机桁架结构的动力特性双因子分析法

针对模糊随机桁架结构的动力特性分析,提出了一种新的模糊随机有限元方法．当结构的物理参数和几何尺寸同时具有模糊随机性时,利用模糊因子法和随机因子法建立了结构刚度矩阵和质量矩阵;从结构振动的Rayleigh商表达式出发,利用区间运算推导出结构动力特性模糊随机变量的计算表达式;之后利用随机变量的矩法和代数综合法,推导出结构特征值的数字特征的计算式．通过算例分析了模糊随机桁架结构参数的模糊随机性对其动力特性的影响．该方法的优点是能准确反映结构某一参数的模糊随机性对结构特征值及其数字特征的影响．     

Long-range surface plasmon polaritons with subwavelength mode expansion in an asymmetrical system

Long-range surface plasmon polariton (LRSPP) modes in an asymmetrical system, in which the thin metal film is sandwiched between a semi-infinite substrate and a high permittivity polymer film with a finite thickness, are theoretically calculated and analyzed. Due to the high permittivity of the polymer film, at proper polymer film thicknesses, the index-matching condition of the dielectrics at both sides of the metal can be satisfied for supporting LRSPP modes, and the electromagnetic field above the metal can be localized well. It is found that these LRSPP modes have both long propagation lengths and subwavelength mode expansion above the metal at the optimal polymer film thicknesses. Furthermore, the requirements on the refractive index and the thickness of the polymer film to support LRSPP modes at the optimal thicknesses are found to be not critical.     

Bending Loss Calculation of a Dielectric-Loaded Surface Plasmon Polariton Waveguide Structure

Based on full 3D finite element method simulations, the transmission of a dielectric-loaded surface plasmon polariton waveguide （DLSPPW） based 1/4 circle is calculated for a 90° bend model and a 270° bend model, respectively. It is found that the 270° bend model gives almost pure bending loss while the 90° bend model contains additional coupling loss. The models are applied to deduce the loss and unloaded quality factor of DLSPPW based waveguide ring resonators （WRRs） and the results of the 270° bend model agree well with direct simulating results of the WRRs. Thus the 270° bend model gives a fast and simple way to calculate bending loss and it is helpful for WRR design because no wavelength scan is needed.     

有界对称区域上Dirichlet空间中的紧Toeplitz算子

介绍了有界对称区域Ω上Dirichlet空间中的Toeplitz算子的紧性:如果S是有限个Toeplitz算子乘积的有限和,S是紧算子当且仅当S的Berezin变换S(z)趋于0.     

基于液晶纯相位光调制器的4f系统去噪方法

分析了4f系统的噪声来源,提出使用液晶空间光调制器实时去除系统噪声.通过使用Zemike多项式拟合透镜等光学器件引入的像差,根据液晶纯相位光调制器利用位相共轭波进行静态波面校正的工作原理,提出了一种新的相位校正算法,模拟仿真美国BNS公司反射式256×256纯相位液晶空间光调制器,通过重构并逼近畸变波面,产生相位共轭波...     

二维相位计算单元的全光实现

相位的计算在二维傅里叶变换等光学计算中有着很重要的作用,在G-S算法等相位恢复算法中更是有着较多的应用.提出了一种全新的相位叠加方案,除了器件本身的光电转换特性外,不需要外加非光学的辅助单元,用全光的方式实现了相位的线性叠加.通过对该计算单元原理和基本构架进行理论分析和计算机仿真,证明了方案的可行性.设计的计算单元既可...     

Morphological and structural damage investigation of nanostructured molybdenum fuzzy surface after pulsed plasma bombardment

Steady high-flux helium (He) plasma with energy ranging from 50 eV to 90 eV is used to fabricate a fiber-form nanostructure called fuzz on a polycrystalline molybdenum (Mo) surface. Enhanced hydrogen (H) pulsed plasma in a wide power density range of 12 MW/m²-35 MW/m² is subsequently used to bombard the fuzzy Mo, thereby simulating the damage of edge localized mode (ELM) to fuzz. The comparisons of surface morphologies, crystalline structures, and optical reflectivity between the original Mo and the Mo treated with various He⁺ energy and transient power densities are performed. With the increase of He ion energy, the Mo nano-fuzz evolved density is enlarged due to the decrease of filament diameter and optical reflectivity. The fuzz-enhanced He release should be the consequence of crystalline growth and the lattice shrinkage inside the Mo-irradiated layers (~200 nm). The fuzz induced by lower energy experiences more severe melting damage and dust release under the condition of the identical transient H plasma-bombardment. The H and He are less likely to be trapped due to aggravated melting evidenced by the enhanced crystalline size and distinct lattice shrinkage. As the transient power density rises, the thermal effect is enhanced, thereby causing the fuzz melting loss to aggravate and finally to completely disappear when the power density exceeds 21 MW/m². Irreversible grain expansion results in huge tensile stress, leading to the observable brittle cracking. The effects of transient thermal load and He ion energy play a crucial role in etching Mo fuzz during ELM transient events.     

适应复杂外形的三维粘性混合网格生成算法

提出一类适应复杂外形的粘性混合网格生成算法。表面网格由前沿推进三角形曲面网格程序获得,边界层布置各向异性的三棱柱体网格,远物面区域采用Delaunay方法生成四面体网格。针对模型的复杂几何特征,综合采用了各种网格处理技术,以保证边界层网格的质量,并避免算法失效问题。网格实例及计算结果表明了本文算法的实用性及和效性。     

Impact of substrate injected hot electrons on hot carrier degradation in a 180-nm NMOSFET

Although hot carriers induced degradation of NMOSFETs has been studied for decades, the role of hot electron in this process is still debated. In this paper, the additional substrate hot electrons have been intentionally injected into the oxide layer to analyze tile role of hot electron in hot carrier degradation. The enhanced degradation and the decreased time exponent appear with the injected hot electrons increasing, the degradation increases from 21.80% to 62.00% and the time exponent decreases from 0.59 to 0.27 with Vb decreasing from 0 V to -4 V, at the same time, the recovery also becomes remarkable and which strongly depends on the post stress gate bias Vg. Based on the experimental results, more unrecovered interface traps are created by the additional injected hot electron from the breaking Si-H bond, but the oxide trapped negative charges do not increase after a rapid recovery.