退火温度对Zn0.93Fe0.07O薄膜微结构和铁磁性能的影响

用射频磁控溅射方法在硅片上制备了Zn0.93Fe0.07O薄膜,并在空气中用不同温度进行热处理,利用X射线衍射仪和扫描电子显微镜对其微结构、表面和断面形貌进行测试.结果表明,薄膜沿c轴方向择优生长,呈六角纤锌矿结构,空气中450℃退火的样品XRD谱中出现最强的(002)衍射峰,晶粒尺寸变大,薄膜结晶和取向明显变好.用振动样品强磁计对样品铁磁特性进行测试,发现当退火温度的升高时,饱和磁化强度有所增加,并经分析认为这可能是薄膜中晶粒间的晶界缺陷引起的.     

石墨结构层包嵌铜纳米薄片及其前驱体的Raman光谱

石墨结构层包嵌铜纳米薄片是一种纳米尺度的复合材料,结构为铜纳米片被机械包嵌在石墨碳网之间.在其Raman光谱中,E2g2模的振动频率出现了红移,表明铜纳米薄片外部原子将部分电荷转移给了碳网,这与X射线光电子能谱分析结果一致.由1阶和3阶石墨层间化合物前驱体还原的样品,其Raman光谱具有弯曲碳网的特征,这可能来自薄片边缘的卷曲.前驱体的Raman光谱与其他受主型石墨层间化合物的Raman光谱一致.     

概率论教学中值得注意的几个问题

<正> 概率论是中专学校唯一的一门研究随机现象统计规律的数学课程。由于随机现象的不确定性,使得学生在学习概率论的过程中,往往感到对某些概念、公式理解不透,从而解题时就不那么得心应手。本文是自己在概率论教学中的一点体会。     

A study of hadronic shower development in the ECAL of the alpha magnetic spectrometer Ⅱ

In this paper, we studied the development of hadronic shower in an electromagnetic calorimeter of Alpha Magnetic Spectrometer Ⅱ. Two parametrized empirical formulae were proposed to describe the hadronic shower shape in calorimeter. Using 100 GeV proton beam incident on the center of the ECAL, detailed plots of lateral and longitudinal hadronic shower behavior were given and we found the formulae can describe the development of the hadronic shower with the test beam data. The possible application of the parametrized formulae including e^±-π^± discrimination and tau jet reconstruction was discussed.     

双(N-氧化吡啶2-甲醛)缩1,2-丙二胺镍配合物的合成和晶体结构

合成所得双(N-氧化吡啶-2-甲醛)缩1,2-丙二胺的镍(Ⅱ)配合物[Ni(piopn)(H_2O)_2](ClO_4)_2的晶体属空间群C_?~4-C_c,晶胞参数α=7.397(3)A,b=13.187(7)A,c=25.502(14)A,β=102.18(4)°. 用分子轨道理论的近似方法分析了该配合物的电子结构和分子轨道,探讨了分子的结构特征与红外光谱的关系。     

CONTRIBUTION FROM MOLDCULAR FIELD TO THE TEMPERATURE DEPENDENCE OF TUNNELING MAGNETORESISTANCE

Based on the nearly free-electron approximation, we have investigaed the temperature (T) dependence of spin-polarized tunneling in the magnetic tunnel junction with an asymmetrical barrier, with emphasis on the variation of molecular field with T in the same way as that of surface magnetization. It is found that the Slonczewski model can describe well the T depen-dence of spin-polarized tunneling, while the Julliere model only describes the T dependence of JMR qualitatively, but does accurately that of the difference of tunneling conductance between the parallel and antiparallal alignments for the magnetizations of FMs; Differing from the pre-vious finding, we find the electron spin polarization is not strictly proportional to the surface magnetization, for the former decreases with the increasing T more rapidly than the latter does.     

一种研究生物大分子与其小分子配基相互作用的毛细管电泳新方法

建立了一种定量研究大分子与小分子间相互作用的毛细管电泳新方法,即在线微透 析三电极系统亲和毛细管电泳法。本法可测定小分子的自由浓度而不受蛋白质大分子的干 扰。详细介绍了实验装置的制作,探讨了进样机制。作为实例,研究了生理条件下ｐＨ７．４, ５０ｍｍｏｌ／Ｌ磷酸介质中,牛血清白蛋白与磺胺甲基异噁唑、Ｌ－色氨酸、Ｄ－色氨酸的亲和常数的 测定,其值分别为５．８×１０~ ４Ｌ／ｍｏｌ, ２．３ ×１０~４Ｌ／ｍｏｌ, １．７７×１０~３Ｌ／ｍｏｌ。本法较简便,能在生理环 境下测定,样品用量亦少。