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591.
Shui Hua TANG Bao Chun LIU Qi LIANG Li Zhen GAO Liang Fu ZHANG Zuo Long YU* Chengdu Institute of Organic Chemistry Chinese Academy of Sciences Chengdu 《中国化学快报》2001,(1)
It is well known that NO is one of the most predominant pollutants. It is the main source of acid rain and has strong carcinogenicity. Therefore, removal of NO is one of the key environmental subjects in the world nowadays. With the discovery of carbon nanotubes and their large-scale synthesis1-2, attention is now being focused on their potential application in various fields of materials research. In the field of heterogeneous catalysis, numerous carbon materials have been used to disperse … 相似文献
592.
Man Zhou ZHU Qi Hua WU Qing Xiang GUO* Department of Chemistry University of Science Technology of China Hefei 《中国化学快报》2001,(9)
Delivery of exogenous DNA into cells of various origins plays an important role not only in basic research, but also in clinical application in gene therapy. Great efforts have been made towards the development of viral and nonviral vectors for these purposes1~6. However, at the present stage, none of the vectors can claim to be the panacea. Although most viral vectors can transfer gene efficiently and some of them can be used for gene transfer into tissue cells in vivo, they suffer from immu… 相似文献
593.
Zhan Zhu LIU Ye Feng TANG Shi Zhi CHEN* Institute of Materia Medica Chinese Academy of Material Sciences & Peking Union Medical College Beijing 《中国化学快报》2001,(11)
1,2,3,4-tetrahydroisoquinoline-3-carboxylic acids (TIC) are of considerable interest due to their biological activity and as an important structural element in several important alkaloids and other medically useful products1. Moreover, TIC is a phenylalanine analogue in which the dihedral angle is limited to a very small range because of its bicyclic nature2. In connection with the design of topographically constrained peptides, TIC has been utilized in several instance as a replacement o… 相似文献
594.
The title compound, (H2en)3H3O{Mo8V4O36(VO4) (VO)2} ?4H2O, was hydrothermally synthesized and structurally characterized by means of IR, ESR spectrum and single crystal X-ray diffraction. It crystallized in a monoclinic system with space group P21/c, a=1. 980 4(4) nm, 6=2. 063 4(4) nm, c=l. 192 0(2) nm, =94. 76(3)?and deep black colour. The compound contains V-centered bi-capped a-Keggin fragments {Mo8V7O42} that are linked together by edge-shared units V O5 via V桹梀 bonds, forming a chain. 相似文献
595.
Shuang Xi MEI Yun Xin DENG Quan Bin HAN Zhong Wen LIN Han Dong SUN* Laboratory of Phytochemistry Kunming Institute of Botany Academia Sinica Kunming Department of Pharmacy Guiyang Medical College Guiyang 《中国化学快报》2001,(2)
The genus Isodon has been shown to be a rich source of diterpenes, especially the highly oxidized ent-kaurene diterpenoids with various biological activities1-3. The chemical constituents of Isodon forrestii was reported by Yun Long Xu et al.4. We have investigated the titled plant collected in another place, from the 70% acetone extract of the aerial parts of I. forrestii, seven compounds including a new diterpene glycoside 1 were isolated by a combination of silica gel, preparative TLC an… 相似文献
596.
NaLI Qi Tai ZHENG Zhi Da MIN* Department of Natural Products Chemistry China Pharmaceutical University Nanjing Institute of Materia Medica Chinese Academy of Medical Sciences & Peking Union Medical College Xian Nong Tan street Beiji 《中国化学快报》2001,(10)
Pueraria peduncularis (Grah. ex Benth.) Benth. is a plant of Leguminosae which grows in the southwest of China. Different from other plants of Pueraria, it could not be used as a medicine due to its toxicity1. In order to use the Pueraria plants safer, we studied the constituents of P. peduncularis. Previous phytochemical studies of an n-BuOH extract afforded three triterpenoid saponins2-3. The continuing investigation on CHCl3 extract led to the isolation of a new indole alkaloid. … 相似文献
597.
In previous paper and work, we reported the synthesis and cytotoxicity studies of a novel series of short chain peptide conjugates of the cytotoxic agent 2, 6-dimethoxyhydro -quinone-3-mercaptoacetic acid1 (DMQ-MA). The DMQ-MA is a derivative of 2,6-dimethoxybenzoquinone, which is a natural product of fermented wheat germ and found to have a wide spectrum of cytotoxicity against various tumor cell lines under the synergistic activation of L-ascorbic acid (AH2)2,3. Compared with DMQ, DMQ… 相似文献
598.
WANG Wei WANG Yu-hong Li Wei * *Biological Macromolecular Laboratory College of Life Science Jilin University Changchun P. R. China 《高等学校化学研究》2002,18(4):491-494
IntroductionBioinformatics is coming with Human GenomeProject(HGP) . With the explosions of sequence,structural and other information available ,bioinformatics is playing an increasingly large rolein the study of fundamental biomedical problems.At present and in the near future,it is the mainchallenge for bioinformatists to make gene dicoveryand annotation of human genome sequences whenthe vast amount of data is produced by the highthroughput genome sequencing in a large scale andautomated m… 相似文献
599.
LI Bo * Yoshifumi KOIDE Kunio ESUMI . Toyota Central R & D Labs. Inc. Yokomichi Nagakute Aichi Japan . Departemnt of Applied Chemistry Institute of Colloid Interface Science Science University of Tokyo 《高等学校化学研究》2002,18(2):206-210
IntroductionInclusioncompoundshavebeennotedinrecentyearsandresorcinol typecalix [4 ]arenehasbeenstudiedfortheirinclusionabilitiesbyScheiderandBugleretal[1— 3] .Thepolyolmoietiesincalix[4 ]re sorcinareneformrigidhydrogen bondingnetworks[4 ] ,andcalix [4 ]resorcinare… 相似文献
600.
CHEN Wei YUAN Hong-ming JIANG Yu-sheng HUO Hua CHEN Jie-sheng *State Key Laboratory of Inorganic Synthesis Preparative Chemistry Jilin University Changchun P. R. China 《高等学校化学研究》2002,18(4):375-379
IntroductionSince Wilson and co- workers successfullysynthesized three- dimensional microporousaluminophosphates (Al PO4 - n ) [1] in the 1 980 s,much attention has been focused on the explorationof1 - D chain,2 - D layer and3 - D open- frameworkmetal phosphates from aqueous or non- aqueoussystems.The number of metals incorporated intothe frameworks of these materials is continuouslyincreasing and the metals include Be[2 ] ,Ga[3] ,In[4 ] ,Sn[5] ,Sb[6 ] ,and the transition metals Zn[7] ,Ni… 相似文献