层状四水硫酸锆催化合成乙二醇单乙醚醋酸酯反应机理的理论研究

采用以量子化学ASED－MO（含原子对排斥的EHMO法）为基础的结构自动优化EHTOPT法,研究了层状四水硫酸锆催化合成乙二醇乙醚醋酸酯的反应机理;构筑了反应组分乙二醇单乙醚羟基上的氢原子通过氢 键与层状四水硫酸锆结晶水上的氧原子结合。同时,还研究了醋酸在四水硫酸锆表面形成正碳离子的结合状态,提出了相应的酯化反应机理,在此基础上推导出的动力学方程与实验结果相符。     

Safety margin criterion of nonlinear unbalance elastic axle system

IntroductionAtpresentanewanddevelopingsubject—chaoticdynamicsstartsabroadprospectforanalysisofnonlinearsystem[1～ 5 ].Largerotatingmachineryisatypicalnonlinearnon_autonomoussystem .Thesaferunofrotorsystemisofgreatsignificancetosociallifeandeconomicdevelopment.Thestabilityisthekeytosafeoperation .Thesafestabilityanalysisandcontrolforlargesystemisnotonlyamajorbasicresearchbutalsoisveryimportanttosolvethesafeproblemsinlifeandproduction[6 ,7].Soar,althoughmanymathematicians,mechanistsandengineer…     

（LaO）3BO3基质中Tb^3的发光特性

在254nm紫外光（UV）激发下,研究了（LaO)3BO3基质中Tb^3 的激发光谱、发射光谱、发光寿命与Tb^3 浓度的关系,并探讨了Tb^3 的^5D3→^7D3→F4。跃迁发射的自身浓度猝灭机理,在阴极射线（CD）激发下,研究了（LaO)3BO3:Tb^3 的发光强度与Tb^3 浓度、加速电压及电流密度的关系,发现在UV事CR两种激发条件下,试样均能发出明亮的绿色荧光,有望成为一种有发展前途的绿粉。     

Six—Parameter Exponential—Type Potential and the Identity for the Exponential—Type Potentials

We propose a six-parameter exponential-type potential (SPEP),which has been shown to be a shapeinvariant potential with a translation of parameters.For this reducible potential,the exact energy levels are obtained by using the supersymmetric shape invariance technique.Choosing appropriate parameters,four classes of exponential-type potentials and their exact energy spectra are reduced from the SPEP and a general energy level formula,respectively.Each class shows the identity except for the different definitions of parameters.     

Long—Range Effects on the Pyroelectric Coefficient of Ferroelectric Superlattice

Long-range effects on the pyroelectric coefficient of a ferroelectric superlattice consisting of two different ferroelectric materials are investigated based on the transverse Ising model.The effects of the interfacial coupling and the thickness of one period on the pyroelectric coefficient of the ferroelectric superlattics are studied by taking into account the long-range interaction.It is found that with the increase of the strength of the long-range interaction,the pyroelectric coefficient decreases when the temperature is lower than the phase transition temperature;the mumber of the pyroelectric peaks decreases gradually and the phase transition temperature increases,It is also found that with the decrease of the interfacial coupling and the thickness of one period.the phase transition temperature and the number of the pyroelectric peaks decrease.     

Transparency and Strong Gain Without Population Inversion in Photonic Bandgap Crystals

Without using the weak-field approximation,we investigate the transient properties of a Λ-type atom with one transition near resonant with a photonic bandgap edge.Whatever the initial state of the atom is,the atom can become transparent to a probe field,and strong gain without population inversion is also possible if the atom has been pre-excited.The defect mode formed by atomic doping can have a strong effect on the absorption properties of the atom.     

A Pseudospectral Time—Domain Algorithm for Calculating the Band Structure of a Two—Dimensional Photonic Crystal

A pseudospectral time-domain (PSTD) method is developed for calculating the band structure of a two-dimensional photonic crystal.Maxwell‘s equations are rewritten in terms of period fields by using the Bloch theorem.Instead of spatial finite differences,the fast Fourier transform is used to calculate the spatial derivatives.To reach a similar accuracy,fewer sample points are required in the present PSTD method as compared to the conventional finite-difference time-domain methods.Our numerical simulation shows that the present PSTD method is an efficient and accurate method for calculating the band structure of a photonic crystal.     

索尼LCX029CRT液晶显示器纯位相调制特性的研究

为了研究索尼LCX029CRT液晶显示器纯位相调制特性,设计了索尼LCX029CRT液晶显示器的驱动电路,并搭建了测试光路对其纯位相调制特性进行了研究,同时对光路进行了理论分析。实验获得一组移动的干涉条纹,实验测试研究结果表明索尼LCX029CRT液晶显示器具有π／2的相位调制特性。