盐LB单分子层膜的非线性光学性质

合成了一种能够形成单分子层膜,又具有很大分子二阶非线性极化率的有机分子材料——菧盐。对菧盐单分子层膜进行了光学二次谐波信号的测量,得到其分子二阶非线性极化率=1.2×10~(-27)esu。但它很难构成稳定的多层膜结构。本文首次报道菧盐/花生酸混合Langmuir-Blodgett(简计L-B)膜的制备及其非线性光学性能研究,混合膜就一般分子材料不能既具有较大的二阶非线性极化率,又能形成稳定的多层膜结构这一难题的可行性进行了探索。实验证明,混合膜是制备高倍频系数的稳定多层膜的可行措施之一。     

物体边界层域内位移及应力的边界元法新公式

1.前言当分析塑性加工工具表层剥落破坏原因和求解断裂力学强度因子或其他工程问题时,仅计算物体表面应力是不够的,还需要计算边界层域内的位移及应力场。用边界元法计算上述工程问题时,当域内点和边界积分点距离足够小时,基本解中     

In-plane optical spectral weight redistribution in the optimally doped Ba_(0.6)K_(0.4)Fe_2As_2 superconductor

We performed detailed temperature-dependent optical measurements on optimally doped Ba0.6K0.4Fe2As2 single crystal, We examine the changes of the in-plane optical conductivity spectral weight in the normal state and the evolution of the superconducting condensate in the superconducting state. In the normal state, the low-frequency spectral weight shows a metallic response with an arctan （T） dependence, indicating a T-linear scattering rate behavior for the carriers. A high energy spectral weight transfer associated with the Hund＇s coupling occurs from the low frequencies below 4000 cm^-1 5000 cm^-1 to higher frequencies up to at least 104 cm^-1. Its temperature dependence analysis suggests that the Hund＇s coupling strength is continuously enhanced as the temperature is reduced. In the superconducting state, the FGT sum rule is conserved according to the spectral weight estimation within the conduction bands, only about 40% of the conduction bands participates in the superconducting condensate indicating that Ba0.6K0.4Fe2As2 is in dirty limit.     

Evolution of the 251 cm^-1 infrared phonon mode with temperature in Ba_0.6K_0.4Fe₂As₂

The far-infrared optical reflectivity of an optimally doped Ba1-xKxFe2As2(x =0.4) single crystal is measured from room temperature down to 4 K. We study the temperature dependence of the in-plane infrared-active phonon at 251 cm-1 . This phonon exhibits a symmetric line shape in the optical conductivity, suggesting that the coupling between the phonon and the electronic background is weak. Upon cooling down, the frequency of this phonon continuously increases, following the conventional temperature dependence expected in the absence of a structural or magnetic transition. The intensity of this phonon is temperature independent within the measurement accuracy. These observations indicate that the structural and magnetic phase transition might be completely suppressed by chemical doping in the optimally doped Ba0.6K0.4Fe2As2 compound.     

Abnormal magnetoresistance behavior in Nb thin films with rectangular arrays of antidots

Magnetoresistance in superconducting Nb films perforated with rectangular arrays of antidots （holes） is investigated at various temperatures and currents. Normally, the magnetoresistance increases with the increasing magnetic field. In this paper, we report a reverse behavior in a certain range of high fields after vortex reconfiguration transition, where the resistances at non-matching fields are smaller than those in the low field regime. This phenomenon is due to a strong caging effect, in which the interstitial vortices are trapped among the pinned multiquanta vortices. This effect is temperature and current dependent.     

考虑摩擦三维弹塑性接触边界元法

边界元法与其它数值方法相比，由于具有应力和面力计算精度高的特点，非常适合于接触问题的分析，本文建立了考虑摩擦三维弹塑性接触问题的边界元法，采用此方法对板带轧制这一典型的弹塑性接触问题进行了分析，证明本文人出的方法是有效的。     

用边界元法分析轧制压力和摩擦力

本文给出了一种新的求解轧制力和摩擦力分布的方法，利用测量手段对轧制过程中的轧件进行测量，然后再利用边界元法对轧辊进行分析，从而求解出轧制中轧制力和摩擦力。这种方法避开了求解轧制力对轧件进行弹塑性分析，也解决了用测力销测量带来的困难，使轧制问题的分析求解得到了简化并提高了求解精度。     

预条件GMRES(m)法迭代求解大规模边界元弹性问题

提出了一种基于单元节点的块雅可比预条件方法,扩大了边界元法的计算规模,使之可用于大规模工程问题的求解.数值实验说明了这种预条件技术的有效性,表明预条件GMRES(m)算法具有较好的收敛特性,适合于求解大规模问题边界元弹性问题所形成的稠密非对称线性方程组.     

Optical conductivity as a probe of a hidden Fermi-liquid behavior in BaFe_(1.904) Ni_(0.096) As_2

We measured the infrared reflectivity of BaFe1.904Ni0.096As2 single crystal from room temperature down to 20 K.Two Drude terms and a Lorentz term well describe the real part of the optical conductivity σ1(ω). We fit the reciprocal of static optical conductivity 1/σ1(0) by the power law ρ(T)=ρ0+ATnwith n=1.6. The "broad" Drude component exhibits an incoherent background with a T-independent scattering rate 1/τb, while the other "narrow" one reveals a T-quadratic scattering rate 1/τn, indicating a hidden Fermi-liquid behavior in BaFe1.904Ni0.096As2 compound.     

含氢键相互作用的IPN体系(Ⅴ)——体系组成变化对相结构和性能的影响

研究了含引入氢键的PBA和PS(OH)组成的IPN体系,PS(OH)为含羟基的改性聚苯乙烯.与相应的非交联聚合物的共混体系不同,IPN均显示两相结构,一相几乎为纯PBA,另一相则是混合相;仅当PS(OH)中羟基含量高达30mol％且其为IPN的主要成分时,才有相当量的PS(OH)溶入PBA为主的相.IPN的模量-组成行为可用Budiansky方程描述,表明两相的连续性,这一结论与透射电子显微镜的观察一致.