充液矩形贮箱弹性箱底板应力与变形分析

基于相容拉格朗日-欧拉法,通过对流场与弹性固体间流固耦合作用的分析,得到了矩形贮箱弹性底板流固耦合系统的自由振动微分方程。将伯努利方程与外加激励条件、速度势函数耦合到自由振动方程中,采用迦辽金积分法,给出了矩形贮箱在流体作用下的应力与变形的解析解。讨论了弹性底板的抗弯刚度、结构尺寸、底板材料参数及流体深度等因素对底板应力与变形的影响。研究结果表明:在液体晃动非线性激励作用下,贮箱底板的应力和变形随着液体深度、板长的增大而增大,随着板厚的减小而增大,且成非线性变化关系;底板的变形及应力与底板的材料常数相关,其中板厚的变化对其变形和应力影响要比板长及液体深度的影响显著得多。本文结果可为工程实际中矩形贮箱的设计提供参考。     

Prediction of nanoparticle transport and deposition in bends

Nanoparticle transport and deposition in bends with circular cross-section are solved for different Reynolds numbers and Schmidt numbers. The perturbation method is used in solving the equations. The results show that the particle transport patterns are similar and independent of the particle size and other parameters when suspended nanoparticles flow in a straight tube. At the outside edge, particle deposition is the most intensive, while deposition at the inside edge is the weakest. In the upper and lower parts of the tube, depositions are approximately the same for different Schmidt numbers. Curvatures of tube, Reynolds number, and Schmidt number have second-order, forth-order, and first-order effects on the relative deposition efficiency, respectively.     

通道中串列旋转圆柱的格子Boltzmann-虚拟区域方法的模拟

通过结合格子Boltzmann方法(LBM)和虚拟区域(Fictitiou sDomain)思想,建立格子Boltzmann-虚拟区域(LB-DF/FD)方法.采用两套网格系统,欧拉网格用于流体,拉格朗日网格用于固体.原有的LBM在计算运动固体的受力方面存在数据振荡,LB-DF/FD方法改进了此缺陷.为验证该方法,模拟圆柱绕流、圆形颗粒在无限长通道中平动及在无限大流场中转动三种情况,结果与其他数值解及理论解符合得很好.利用该方法模拟低雷诺数下通道中串列旋转圆柱周围的流场,分析圆柱间距(g)及雷诺数(Re)对流场结构的影响.给出Re=0.001,0.1和10下,0.2≤g≤8.0的流线结构、圆柱升力、阻力以及力矩等数值结果.结果表明,g对流场的结构及圆柱的受力有显著影响,Re对圆柱阻力及Stokes单元数目的影响较大.     

Research on nucleation and coagulation of nanoparticles in parallel twin jets

The large eddy simulation method has been used to simulate the diffusion of H2SO4 vapor in the parallel twin jets.The distributions of number concentration and size of nanoparticles produced by nucleation and coagulation in sulfuric acid/water system are given.The functions of the sulfur content,relative humidity and jet Reynolds number are evaluated according to the distributions of number concentration and size of nanoparticles.The results show that the nucleation in sulfuric acid/water system produces large number of nanoparticles ,and gas-to-nanoparticle conversion mostly takes place in the middle and interface of the twin jets.The coagulation process of particles reduces the number concentration,while increases the mean particle size.For the case with higher sulfur content,more number and smaller size nanoparticles are produced by nucleation and coagulation.There is also a larger number of nanoparticles for the cases with higher relative humidity and jet Reynolds number.     

带有半埋藏空间裂纹的Cr12构件电磁热止裂分析

对带有半埋藏环形裂纹的Cr12标准拉伸试件进行了电磁热止裂研究.通过ZL-2型放电装置实现了半埋藏空间裂纹的止裂实验,采用微机控制电子万能试验机完成了止裂前后试件拉伸性能测试,同时计算了电磁热止裂前后应力强度因子的变化;建立了超强脉冲电流放电瞬间,环形裂纹尖端附近电流绕流、温度场和热应力场的数值分析模型,通过热-电耦合和热-机械耦合两个过程得到了脉冲放电瞬间拉伸试件中的电流矢量场、温度场和热应力场.研究表明:脉冲电流放电瞬间,围绕裂纹尖端金属熔化,钝化了裂尖,并围绕裂尖形成了热压应力场,得到了超细化的金属组织,止裂后抗拉强度得到了提高,达到了止裂的目的.     

Study on the mixing of fluid in curved microchannelswith heterogeneous surface potentials

In this paper the mixing of a sample in the curved microchannel with heterogeneous surface potentials is analysed numerically by using the control-volume-based finite difference method. The rigorous models for describing the wall potential and external potential are solved to get the distribution of wall potential and external potential, then momentum equation is solved to get the fully developed flow field. Finally the mass transport equation is solved to get the concentration field. The results show that the curved microchannel has an optimized capability of sample mixing and transport when the heterogeneous surface is located at the left conjunction between the curved part and straight part. The variation of heterogeneous surface potential $\psi_{\rm n}$has more influence on the capability of sample mixing than on that of sample transport. The ratio of the curved microchannel's radius to width has a comparable effect on the capability of sample mixing and transport. The conclusions above are helpful to the optimization of the design of microfluidic devices for the improvement of the efficiency of sample mixing.     

紫外光催化氧化在环境水质分析中的应用

紫外光催化氧化是近年来环境水质分析中采用的一种样品预处理新技术,目前在国内环境监测领域还应用得不多。本文结合笔者近期的工作,介绍了紫外光催化氧化的原理、特点、设备及其在环境水质分析中的应用,并简介了微波辅助紫外光催化氧化和超声波-紫外光氧化两种最新技术。     

微分电位溶出法连续测定饮料中的铜铅镉锌

建立了微分电位溶出法连续测定饮料中痕量铜、铅、镉、锌的新方法。在HAc- Na Ac( p H4 .5)～ 3.5× 1 0 -2 mol·L-1KCl～ 2 .6× 1 0 -5 mol· L-1Hg2 +介质中测定锌 ,然后调节底液为 0 .0 1 mol·L-1HCl,连续测定铜、铅、镉。铜、铅、镉、锌 ,检出限分别为 4 ,0 .1 ,2 ,4 μg· L-1,线性测定范围 Zn2 +:0～ 30 0 μg·L-1,Cu2 +、Pb2 +、Cd2 +:0～ 2 2 0μg· L-1,回收率为 83.4 %～ 1 0 3.3% ,RSD<3.4 % ( n=7)。该法较好解决了金属互化物的影响 ,样品不需消化便可直接测定。     

超声条件下合成4—戊基（4‘—丙基）双环己基联苯

在超声辐射下,用相转移催化剂十六烷基三甲基溴化铵作助催化剂,室温下通过氯化钯催化４－（４’－丙基）环己基苯基硼酸与４－（４’－戊基）环己基溴苯偶联反应２０ｍｉｎ,合成了４－戊基（４’－丙基）双环己基联苯,反应转化率９７％,反式产物选择性６２％。     

次谐波对混合层中拟序涡合并过程影响的数值研究

本文用拟谱方法对混合层二涡、三涡的合并规律进行了数值研究,分析了基波和交谐波之间相位差对涡合并过程的影响,并对此进行了解释。计算结果表明：二涡合并有配地和撕裂两种形式,且涡的完全通过撕裂合并的现象仅在相位差为π/2时出现;三涡合并有三种形式。通过计算可见,通过施加多级次谐波并改变它们之间的相位差可以主动控制拟序涡的发展和演变。