静态顶空/气相色谱-质谱法同时测定化妆品中22种有毒挥发性有机溶剂残留

以2015版《化妆品安全技术规范》中规定的常见禁用及限用有毒挥发性有机溶剂为研究对象,建立了静态顶空/气相色谱-质谱法(SHS/GC-MS)同时测定化妆品中22种有毒挥发性有机溶剂(VOC)(二氯甲烷、顺式-1,2-二氯乙烯、反式-1,2-二氯乙烯、2-氯-1,3-丁二烯、三氯甲烷、1,2-二氯乙烷、苯、四氯化碳、三氯乙烯、甲苯、四氯乙烯、氯苯、乙苯、三溴甲烷、间二甲苯、对二甲苯、苯乙烯、邻二甲苯、异丙苯、1,4-二氯苯、1,2-二氯苯、六氯丁二烯)残留的检测方法。试样在80℃下30 min静态顶空,经DB-1柱分离后,采用选择离子监测模式(SIM)进行定性定量分析。优化了顶空、色谱和质谱参数,结果表明:22种VOC在0.5~50 ng/m L浓度范围内均呈良好的线性关系,相关系数均大于0.99,在1.0,2.0,5.0 ng/m L 3个浓度加标水平下的平均回收率为80.3%~102.7%,相对标准偏差(RSD,n=6)为6.4%~9.9%,检出限为0.2~5.0 ng/g。结果表明,该方法简便、灵敏、准确,具有良好的重现性和稳定性,适合于化妆品中22种VOC残留的筛查和确证检测。     

Molecular Dynamics Simulation of Water Confined in Carbon Nanotubes

Molecular dynamics simulations are performed for water confined in carbon nanotubes with various diameters （11.0-13.8 A ）. The simulations under an isobaric pressure （one atmosphere） by lowering temperatures from 300 K to 190K are carried out. Water molecules within variously sized tubes tend to transform from disorder to order with different configurations （four-water-molecule ring, six-water-molecule ring and seven-water-molecule ring） at phase transition temperatures, which may be lowered by the increasing tube radius. It is also found that the configurations of water in （10, 10） tube are not unique （seven-molecule ring and seven-molecule ring plus water chain）.     

用布喇格光纤光栅传感器测定口腔复合树脂材料光固化收缩与温度演化特性

复合树脂材料已成为重要的牙齿美容修复材料.本文利用两种布喇格光纤光栅传感器测定了口腔复合树脂材料在光固化过程中的收缩与温度演化特性.一种为普通的光纤布喇格光栅,另一种为经过了化学镀镍的光纤布喇格光栅,同时埋入复合树脂样品中,用光照射使其固化,测得光纤布喇格光栅在固化过程中温度和应力随时间的演化曲线.实验结果表明,在光固化过程中,因为聚合反应,树脂产生了强烈的收缩应力和温度变化.掌握复合树脂的光固化收缩特性和温度变化特性对不断改良材料性能以及优化口腔材料的治疗效果具有实际意义.     

浮栅ROM器件的辐射效应实验研究

浮栅ROM器件的质子和中子辐射效应实验结果表明，其31.9MeV质子和14MeV中子的辐射效应不是单粒子效应，而是一种总剂量效应。浮栅ROM器件的^60Coγ辐照实验验证了这一点，器件出现错误有个注量或剂量阈值。动态监测和静态加电的器件都出现数据错误，且不能用编程器重新写入数据。然而不加电的器件在更高注量的质子或中子或更高剂量的γ辐照下未出现错误，器件刚开始出错时，错误数及错误地址都是不确定的。     

A new compensation method for temperature-dependent gain tilt in L-band EDFA by adjusting only inserted VOA

A novel compensation method for temperature-dependent gain tilt of L-band erbium-doped fiber amplifier (L-EDFA) is proposed, in which the attenuation between stages is the only parameter to be adjusted. A simple linear relationship between the attenuation and the erbium fiber coil temperature was derived theoretically. When the erbium fiber coil temperature cycles from 26 to 70℃, the gain tilt variation less than 0.3 dB is achieved experimentally by adjusting only the pre-inserted variable optical attenuator (VOA).     

二维平板光子晶体的等效负折射率测量EI北大核心CSCD

光子晶体特殊的色散特性能导致负折射现象发生。用波束位移法对二维光子晶体平板的负折射现象进行理论计算和实验测量,得到了入射光经平板光子晶体折射后的二维光场分布。测量结果表明,横电(TE)光在光子晶体中发生负折射,出射光沿出射面产生了反方向的横向位移,由此计算出来的负折射率约为-0.44,而横磁(TM)光没有发生负折射。实验结果与仿真结果吻合较好。     

羊踯躅花瓣总RNA提取方法的比较与改进

不同组织的RNA提取难点各异,适宜方法也不尽相同.分析、比较了热酸性酚抽提法、热硼酸法、异硫氰酸胍法和改良的异硫氰酸胍法从羊踯躅花瓣中提取总RNA的效果,经过多次反复实验发现采用改良的异硫氰酸胍法所得的总RNA质量好,纯度高,完整性很好,适用于cDNA文库的构建、Northern印迹与mRNA差异显示等后续研究工作.     

Above-threshold detachment of negative ions by circularly polarized few-cycle laser fields

In accordance with nonperturbative quantum scattering theory,we investigate photoelectron angular distributions(PADs) from above-threshold detachment(ATD) of negative ions irradiated by circularly polarized few-cycle laser fields.Electrons ejected on the polarization plane demonstrate distinct anisotropies in angular distributions which distinctly vary with the carrier-envelope(CE) phase.The anisotropy is caused by interference between transition channels;it also depends strongly on laser frequency,pulse duration,and kinetic energy of photoelectrons.Optimal emission of photoelectrons,which varies with CE phase,makes it possible to control photoelectron motion.     

具有循环极大子群p-群上的中心对称的正则凯莱地图（英文）

证明了两类具有循环极大子群的p-群上不存在中心对称的正则凯莱地图.     

有限群的子群完备码（英文）

本文从子群双陪集的角度给出了有限群的一般子群可作为子群完备码的充要条件.在此基础上给出了拟二面体群中的所有子群完备码.