手性咪唑酯类离子液体的合成及其物理性能

以咪唑,溴代烷烃及(-)-薄荷醇为原料合成了12个手性咪唑酯类离子液体,其结构经NMR和IR表征.物理性能研究结果表明,该类离子液体具有较好的热稳定性,且比旋光度存在一定的改变规律.     

(-)-龙脑手性离子液体的合成

以(-)-龙脑为手性源,与溴乙酰溴通过酯化反应合成溴代乙酸龙脑酯(2);2与4,4'-联吡啶发生取代反应引入两个手性中心制得新型手性离子液体——N,N'-双(龙脑氧甲酰亚甲基)联吡啶.二溴(3.2Br-);3.2Br-与四氟硼酸钾或六氟磷酸钾盐进行阴离子交换制得相应的手性离子液体3.2BF4-或3.PF6-.3.2Br...     

长光纤中拉曼光子时间模式的影响因素研究

在有损耗、色散和自相位调制的影响下,通过分段分析法计算了自发拉曼散射光子的二阶相关函数,研究了长光纤中脉冲光泵浦下自发拉曼散射的时间模式特性。研究结果表明：在无色散和自相位调制的情况下,自发拉曼散射光子的二阶相关函数不受泵浦光损耗的影响,仅由泵浦光脉宽和拉曼光子相干时间之间的比值决定,与自发参量下转换光子的二阶相关函数具有相同的表达式;在有色散和自相位调制的情况下,由色散和自相位调制共同引起的泵浦光脉宽变化,以及泵浦光和拉曼光子间色散致走离,使拉曼光子的时间模式发生改变。自发拉曼散射光子的二阶相关函数取决于光纤损耗系数、色散参数和初始泵浦光脉宽等因素,不再与自发参量下的转换光子相同。     

Synchronization in multilayer networks through different coupling mechanisms

In recent years, most studies of complex networks have focused on a single network and ignored the interaction of multiple networks, much less the coupling mechanisms between multiplex networks. In this paper we investigate synchronization phenomena in multilayer networks with nonidentical topological structures based on three specific coupling mechanisms:assortative, disassortative, and anti-assortative couplings. We find rich and complex synchronous dynamic phenomena in coupled networks. We also study the behavior of effective frequencies for layers I and II to understand the underlying microscopic dynamics occurring under the three different coupling mechanisms. In particular, the coupling mechanisms proposed here have strong robustness and effectiveness and can produce abundant synchronization phenomena in coupled networks.     

Tunable multi-wavelength microwave photonic filter based on the superposition of transfer functions

A microwave photonic filter （MPF） with reconfigurability and tunability resulting from the superposition of the transfer functions is proposed. Based on the Vernier effect between the optical frequency combs and the periodic optical filters, each comb line can be mapped into a sub-filter in the electronic field. The sub-filters are superposed to obtain the total transfer function of the MPF. By manipulating a few comb lines, we can reconfigure the passband shape, tune the bandwidth, and adjust the center frequency independently. Experiments verify that the bandwidth can be tuned from 224.8 to 674.3 MHz, and that the center frequency ranges from 1 to 4 CHz.     

Design and performance study of the LEPD silicon tracker onboard the CSES satellite

The low energy particle detector (LEPD) is one of the main payloads onboard the China seismic electromagnetic satellite (CSES). The detector is designed to ascertain space electrons (0.1-10 MeV) and protons (2-50 MeV). It has the capability of identifying the electrons and protons, to measure the energy spectrum and the incident angle of the particles. The LEPD is made up of a silicon tracker system, a CsI (Tl) mini-calorimeter, an anti-coincidence system made by plastic scintillator, as well as electronics and a data acquisition system (DAQ). The tracker is also a kind of E-E telescope; it consists of two layers of double-sided silicon strip detectors (DSSD). The signals emerging from the silicon tracker can be read out by two pieces of application specific integrated circuit (ASIC), which also can generate an event trigger for the LEPD. The functions of the DSSD system in the LEPD for charged particles were tested by 241Am @5.486 MeV α particles. The results show that the DSSD system works well, and has high performance to detect charged particles and measure the position of incident particles.     

A geometric factor calculation method based on the isotropic flux assumption

One of the instruments onboard the China Seismic Electromagnetic Satellite （CSES） is the Low Energy Particle Detector （LEPD）. The primary objective of LEPD is to provide measurements of the fluxes, energy spectra and pitch angles of 100 keV to 10 MeV electrons and protons from 2 to 50 MeV in the Earth＇s magnetosphere. The geometric factor is one of the principle parameters of a detector, which converts the physical quantity-count rate to the particle quantity-flux. In this paper, we calculated the geometric factor of LEPD via computer modeling of an isotropic radiation environment. It was first demonstrated that the radiation intensity related should obey a cosine-law, then a general sampling method of generating this distribution via GPS of GEANT4 was explained. Furthermore, combined with flux normalization, a comparison of the geometric factor calculation of a set of 2-layer detectors with different shapes （cylinder, truncated cone and rectangle） was performed. Results show a generally good agreement between simulation and analytical calculations for the cylinder and truncated cone detectors, and the result of the rectangular one, for which there is no accurate analytical formula, is consistent with the previous simulated results by others. As a practical instance of the 2-layer rectangle detector, the geometric factor of LEPD is 10.336±0.036 m cm2·sr for 10 MeV proton and 8.211±0.032 m cm2·sr for 8 MeV electron.     

瞬发中子密度衰减法计算中子代时间

采用蒙特卡罗程序MCNP计算了西安脉冲堆中子代时间。使用MCNP程序模拟了反应堆瞬发中子通量密度衰减,基于忽略缓发中子项的点堆动力学方程计算出中子代时间。在微次临界下,研究了次临界度、源的分布、计数区域等对西安脉冲堆中子代时间计算结果的影响。计算分析表明:采用瞬发中子密度衰减法计算中子代时间时,微次临界度、源分布、计数区域等对计算结果影响都很小;误差产生的主要原因是忽略缓发中子项的点堆动力学方程并不能较好地反应瞬发中子通量密度的衰减规律。     

等截面引射器启动性能数值研究

采用雷诺平均方程和SST k-ω湍流模型,空间离散采用二阶精度的Roe FDS方法,限制器采用Min-Mod方法,时间迭代采用隐式方法,研究了等截面引射器长度、引射器与喷管的间隙对其启动性能的影响。结果表明:等截面引射器存在启动、临界、不启动三种状态;在引射器长度一定的情况下,引射器与喷管之间的间隙越小,引射器的启动压比越小;在引射器与喷管之间间隙一定的情况下,对于本文所计算的工况,当引射器长度小于3m时,引射器所需的启动压比会很大,当引射器长度小于2m,则引射器很难启动;当引射器长度超过7m时,会对引射器的加工、安装、冷却带来诸多不利影响。