Cu(Ⅱ)对壳聚糖的配位控制降解

对壳聚糖进行液态均相络合反应制得壳聚糖铜配合物,IR、UV、元素分析及热重分析等检测证实了壳聚糖铜配合物中配位键的存在,且显示壳聚糖在形成配位结构后存在有利于降解的优势构象。以H₂O₂对壳聚糖-Cu(Ⅱ)络合物及壳聚糖进行氧化降解,考察降解过程中粘度的变化及降解产物分子量分布,在相同的降解条件下,壳聚糖铜配合物的降解速度明显高于壳聚糖,降解产物分子量分布较壳聚糖直接降解窄,结果进一步证明壳聚糖铜配合物中存在有利于降解的优势结构,同时证明以金属离子Cu(Ⅱ)对壳聚     

吲哚衍生物的合成及其海洋防污性能

以吲哚和酰氯(苯甲酰氯及苯磺酰氯)为原料，合成了7个N-酰基取代吲哚类化合物(a~g)，其结构经¹H NMR和元素分析确证。研究了化合物对球等鞭金藻、亚心形扁藻和舟形藻以及藤壶幼虫的生长抑制活性。结果表明：当吲哚结构连接电负性较高的基团时，化合物对藻类和藤壶幼虫的生长抑制性较好，其中以连接苯磺酰基化合物的抑制效果最佳。目标化合物对藤壶幼虫12 h和24 h的半致死浓度(LC₅₀)明显低于底物吲哚，其中以苯磺酰基取代的化合物最低。采用目标化合物制备的海洋防污涂料，浅海挂板90 d后，对海洋污损生物的附着表现出明显的抑制作用。     

小孔成像的焦移理论

根据Li和wolf的焦移理论,本文提出一种较严格分析小孔成像最佳位置和分辨率的方法.小孔的作用可等效为一个具有“可变光焦度”的薄透镜.     

Polarization Gradient Cooling by Zeeman-Effect-Assisted Saturated Absorption

A novel and simple method to realize polarization gradient cooling （PGC） is reported. The stabilizing, shifting and rapid tuning of the frequency of the external cavity diode laser is realized by using the Zeeman-effect-assisted Doppler-free saturated absorption technique. Based on this convenient technique, 87Rb cold atoms are captured from room-temperature background vapor in the magneto-optical trap （MOT）. Meanwhile, the steady-state number, the density and the lifetime of atoms in the MOT are measured. Subsequently, a frequency-fast-varying circuit is designed to realize PGC, which is demonstrated effectively and reliably in experiments. The temperature of the cold atom cloud is measured by two different methods, which coincide with each other.     

Fractional Fourier transform for partially coherent beam in spatial-frequency domain

By using Fourier transform and the tensor analysis method, the fractional Fourier transform (FRT) in the spatial-frequency domain for partially coherent beams is derived. Based on the FRT in the spatial-frequency domain, an analytical transform formula is derived for a partially coherent twisted anisotropic Gaussian－Schell model (GSM) beam passing through the FRT system. The connections between the FRT formula and the generalized diffraction integral formulae for partially coherent beams through an aligned optical system and a misaligned optical system in the spatial-frequency domain are discussed, separately. By using the derived formula, the intensity distribution of partially coherent twisted anisotropic GSM beams in the FRT plane are studied in detail. The formula derived provide a convenient tool for analysing and calculating the FRTs of the partially coherent beams in spatial-frequency domain.     

椭圆平顶高斯光束及其传输特性

 用张量光学方法定义了三维不可分离变量的椭圆平顶高斯光束(EFGB),导出了这种光束经过非轴对称光学系统的传输公式及相应的张量ABCD定律, 并对EFGB经过自由空间的传输作了数值计算。结果表明, EFGB的传输特性依赖于阶次, 而且耦合EFGB的光强分布在传输过程中会发生旋转。     

罗丹明6G合锌（Ⅱ）配合物的合成及晶体结构

合成了罗丹明 6G合锌 (Ⅱ )配合物 ,晶体结构分析结果表明配合物组成为 [C2 9H31N2 O2 ) 2 ZnCl4·H2 O] .晶体属三斜晶系 ,空间群P -1 (# 2 ) ,晶胞参数为a =1 .1 687(2 )nm ,b =1 .2 50 1 (5)nm ,c =2 .0 694 (5)nm ;α =99.1 3 (2 )°,β=1 0 0 .1 7(4 )°,γ =96.4 6(4 )°;Z =2 ,ρcal=1 .3 0 g/cm3.研究了配合物的摩尔电导、IR和荧光光谱、差热 -热重分析 .     

空间频率域的张量ABCD定律

运用张量分析方法把轴对称系统中的空间频率域的柯林斯公式推广到一般的非轴对称光学系统,并推导了在空间频率域中适用于非轴对称光学系统的张量ABCD定律。空间频率域中的柯林斯公式和张量ABCD定律直接给出了像散光束的空间傅里叶频谱的传输规律。它们在处理与空间频谱有关的问题,如空间滤波,成像系统的传递函数,复杂像散高斯光束在自由空间的传输等问题时更为简便。     

基于个性化三维心脏-躯干模型的心磁正问题

建立了基于有限元法(FEM)的三维心磁正问题计算框架,以研究人体心脏电生理活动产生的磁场问题.首先对被试的心脏和躯干磁共振影像数据源进行三维个性化建模,获得心脏-躯干几何模型.其次结合心脏三维模型与修正的FitzHugh-Nagumo(FHN)方程研究由跨膜电位(TMP)产生的电兴奋在心脏内部的传导.随后利用躯干三维模型与准静态麦克斯韦方程,研究心脏电兴奋产生的生物电磁场在体内的传播过程,进而获得体表外的心脏磁场分布.心磁计算框架仿真结果显示,使用FEM的模型可以较好地模拟体表外磁场分布.一维FHN方程和直导线的简化模型数值结果分别与解析解呈现出较好的一致性,验证了该计算框架的可行性.综上,该框架成功地仿真了TMP在心脏内部的传播过程及其在体表外投影的磁场分布,这将有助于未来心磁逆问题求解的研究.     

FLaser frequency stabilization and shifting by using modulation transfer spectroscopy

The stabilizing and shifting of laser frequency are very important for the interaction between the laser and atoms. The modulation transfer spectroscopy for the 87Rb atom with D2 line transition F = 2 →F＇ = 3 is used for stabilizing and shifting the frequency of the external cavity grating feedback diode laser. The resonant phase modulator with electro-optical effect is used to generate frequency sideband to lock the laser frequency. In the locking scheme, circularly polarized pump- and probe-beams are used. By optimizing the temperature of the vapor, the pump- and probe-beam intensity, the laser linewidth of 280 kHz is obtained. Furthermore, the magnetic field generated by a solenoid is added into the system. Therefore the system can achieve the frequency locking at any point in a range of hundreds of megahertz frequency shifting with very low power loss.