Preparation and Crystal Structure of PrNb_5O_(14)

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Crystal and Molecular Structure of Quinide

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An Interesting Approach to Bis—calix [5] arene Analogue from Caxlix[6] arene

By 1,4-bridgine of p-tert-butylcalix [6] arene with 2,6-bis(bromomethyl)-4-methyl-anisole,a new type of bis-calix [5] arene analogue was obtained in high yield.     

Selective Transport of Alkali—Metal Cations through Liquid Membranes by Non—Cyclic Carriers

The emission spectra of a series of naphthalene end-labeled oligo-oxyethylene(N-Pn-N) and their facilitated transport of cations across liquid membranes have been investigated.Alkali-metal cations enhance or inhibit the intramolecular excimer formation of N-Pn-N remarkably,suggesting that the polyether chain of N-Pn-N in solution complexes with the cations,and the orientation of the terminal chromophores depends on the cation size and the length of the polyether chain. These compounds are able to act as carriers to facilitate transport of alkali-metal cations through organic liquid membranes.The transport efficiencies are comparable with those of cyclic carriers such as crown ethers,and show remarkable selectivity.     

Synthesis and Properties of Polyetherketones Containing Sulfide and Phthalazinone

High molecular weight copoly(ether ketone)s (PEK) based on 4-(4-hydroxyphenyl)-1-phthalazinone (DHPZ)/4,4′-thiobisphenol (TBP)/4,4′-diflourodiphenylketone (DFK) were prepared by nucleophilic substitution polycondensation. The copolymers were characterized by FT- and ^1H-NMR. Thermal properties and solubility of copolymers were studied.     

通用模拟退火用于稳健多元分析校正

模拟退火是一种全局优化算法，具有跨越局部最优点的机制，最小一乘是一种较常用的最小二乘更为稳健的优化准则，更适用于可能偏离正态分布的实际数据集，本文探讨了用最小一乘为准则并利用模拟退火方法同时测定多组分体系的可能性。应用于2－3组分药物体系分析，获得了满意的结果，本文还探讨了改变步长提高模拟退火算法优化精度的方法。     

3D－QSAR Study on Diindolylmethane and Its Analogues with Comparative Molecular Field Analysis(CoMFA)

Comparative molecular field analysis (CoMFA),a three dimensional quantitative structure-activity relationship (3D-QSAR) method was applied to a series of diindolylmethane(DIM) analogs to study the relationship between their structure and their induction of CYP 1A1-associated ethoxyresorufin-O-deethylase(EROD) activity.A DISCO model of pharmacophore was derved to guide the superposition of the compounds.The coefficient of cross-validation (q^2) and non cross-validation(r^2) for the model established by the study are 0.827 and 0.988 respectively,the value of variance ratio (F) is 103.53 and standard error estimate (SEE)is 0.044.These values indicate that the CoMFA model derived is significant and might have a good prediction for the catalytic activity of DIM compounds.As a consequence,the predicted activity values of new designed compounds were all higher than that of the reported value.     

A New Activation Method for Electroless Metal Plating：Palladium Laden via Bonding with Self—Assembly Monolayers

A new activation method has been developed for electroless copper plating on silicon wafer based on palladium chemisorption on SAMs of APTS without SnCl2 sensitization and roughening condition.A closely packed electroless copper film with strong adhesion is successfully formed by AFM observation.XPS study indicates that palladium chemisorption occurred via palladium chloride bonding to the pendant amino group of the SAMs.     

一种多起点并发式快速运动估计搜索方法

为了提高块匹配运动估计快速算法的搜索速度、精度和鲁棒性,提出了一种多起点并发式快速运动估计搜索方法。根据匹配块搜索的特性,提出了均匀选取多个起始点的方法,同时根据搜索区域的大小制定了自适应的限制条件和进度表,使得算法的收敛速度有了很大的提高。该算法在迭代过程中不但能够接受使目标向好的方向前进的解,而且能够在一定限度内接受使目标恶化的解,这使得算法能够有效地跳出局部极小的陷阱。使用基于TMS320C6415芯片的DSP图像处理系统对抖动视频图像序列进行实验。实验结果表明,当视频图像为PAL制,分辨率为720×576个像素,并且相邻图像间的抖动范围为±40个像素时,使用新提出的方法,匹配参数的计算量不大于使用全域匹配方法计算量的1/8,并且搜索精度远高于其他传统的快速搜索方法。