Rovibrational quenching of BH in ultracold 3He collisions

The interaction potential of a He-BH complex is investigated by the coupled-cluster single-double plus pertur-bative triples (CCSD (T)) method and an augmented correlation consistent polarized valence (aug-cc-pV)5Z basis set extended with a set of (3s3p2d1f1g) midbond functions. Using the five two-dimensional model potentials, the first three-dimensional interaction potential energy surface is constructed by interpolating along (r–r e ) by using a fourth-order polynomial. The cross sections for the rovibrational relaxation of BH in cold and ultracold collisions with 3 He atom are calculated based on the three-dimensional potential. The results show that the Δv =-1 transition is more efficient than the Δv =-2 transition, and that the process of relaxation takes place mainly between rotational energy levels with the same vibration state and the Δj =-1 transition is the most efficient. The zero temperature quenching rate coefficient is finite as predicted by Wigner’s law. The resonance is found to take place around 0.1–1 cm-1 translational energy, which gives rise to a step in the rate coefficients for temperatures around 0.1–1 K. The final rotational distributions in the state v = 0 resulting from the quenching of state (v = 1, j = 0) at three energies corresponding to the three different regimes are also given.     

拉曼散射光谱在氧碘化学激光器参数测试上的应用

介绍了拉曼散射在氧碘化学激光器参数测试上的应用,给出了在流量为0 5mol/s的射流式氧发生器上的实验结果。采用一套测试装置可以同时进行O2(a1Δ)产率和氯气利用率测试,提高了测试效率;由于无需进行另外的标定实验,提高了测试精度,为此该方法可以极大地改善目前O2(a1Δ)产率和氯气利用率测试精度较低的现状。     

中心对称光折变材料中的小光强空间孤子

给出了小光强条件下中心对称光折变材料中光波演化方程的亮、暗及灰空间孤子解析解，并推导出了孤子宽度的显式表达式． 关键词： 光折变效应 光折变材料 空间孤子     

氧碘激光器化学式碘发生装置的实验研究

针对采用化学式碘发生器的氧碘激光器稳定出光时间较短的情况,通过热力学和化学动力学方面的实验和分析进行了化学式碘发生装置供碘稳定性的研究。分析了物料转化率和反应速率随反应初始温度及反应时间的变化,得到了固相产物的灰层扩散是该反应控制步骤的结论,明确了实验中CuI要大大过量,用氯气量控制碘量的原则,同时确定了适宜的起始反应温度。优化后,在近15s时间内碘流量变化小于15%,显示出了较好的供碘稳定性,此时CuI的转化率为23%。     

中空微球及其制备方法

中空微球具有低密度、高比表面积且可以容纳客体分子等特点,在众多领域受到广泛关注.本文对聚合物中空微球、无机中空微球、聚合物/无机复合中空微球的制备方法进行了综述,并介绍了一种在使用过程中形成中空结构的可膨胀微球.     

结直肠组织中脂类的拉曼光谱研究

利用共聚焦显微拉曼光谱系统,检测了结直肠癌组织及邻近正常组织的拉曼光谱234例,从分子水平探讨结直肠癌变的原因。实验结果表明：在900～2 100 cm-1频移范围内,与正常组织比较,归属于结直肠癌组织中脂类伸缩振动的1 067和1 133 cm-1 拉曼峰强度相对较弱,扭转振动的1 299 cm-1与CH面内变形振动的1 264 cm-1拉曼峰的强度比值减少,应用SPSS16.0统计学软件进行平均值计算与比较,正常组织中的1 299和1 264 cm-1的强度比值平均值为3.17,癌变组织的为1.33; 二者的分界值为1.96,以此判别结直肠癌组织和正常组织符合率为94%。研究表明,结直肠癌组织中脂类的链内纵向有序性下降,不饱和度增加。可推测结直肠癌组织中脂类的能量储存增加是引起这些变化的原因,而这些变化将导致细胞膜的流动性增强,从而改变细胞膜的物质运输、能量传递和信号传导,终将引起DNA 结构的变化。因此,脂类的能量分布变化可能是导致细胞癌变的原因之一。     

Tunneling current of the Coulomb-coupled quantum dots embedded in n-n junction

Taking account of the electron--electron (hole) and electron--hole interactions, the tunneling processes of the main quantum dot (QD) Coulomb-coupled with a second quantum dot embedded in n--n junction have been investigated. The eighteen resonance mechanisms involved in the tunneling processes of the system have been identified. It is found that the tunneling current depends sensitively on the electron occupation number in the second quantum dot. When the electron occupation number in the second dot is tiny, both the tunneling current peaks and the occupation number plateaus in the main QD are determined by the intra-resonance mechanism. The increase of the electron occupation number in the second dot makes the inter-resonance mechanism participate in the transport processes. The competition between the inter and intra resonance mechanisms persists until the electron occupation number in the second dot reaches around unity, leading to the consequence that the inter-resonance mechanisms completely dominate the tunneling processes.     

利用超球势曲线分析正电子与氦原子体系中的共振态

超球势曲线用来分析正电子氦原子体系中的共振态。利用插值方法得到交叉的势曲线,然后求解超球薛定谔方程。计算结果表明处于-0.07922 a.u.的共振是与Ps(n=2)态相联的,而处于-0.06888 a.u.的共振是与He（1s3s）态相关。     

大片单层低缺陷MXene的制备及其膜材料的电磁屏蔽性能

采用原位生成氢氟酸法刻蚀Ti₃AlC₂制备了单片层二维过渡金属碳化物(MXene), 用扫描电子显微镜(SEM)、 透射电子显微镜(TEM)及原子力显微镜(AFM)等表征了MXene的微观形貌. 结果表明, 所制备的MXene材料具有大片、 单层及低缺陷等特点. 通过抽滤MXene分散液制备的MXene膜材料具有导电性高(3280 S/cm)及韧性优异等特点. MXene膜的屏蔽性能测试结果表明, 8 μm厚的MXene膜屏蔽效能为60.6 dB, SSE/t值则高达19531.1 dB·cm ²·g ^-1. 推测MXene膜的屏蔽机理是一种以吸收为主的电磁干扰屏蔽机制.     

光在吸收介质中的传播速度对光腔衰荡测量精度的影响

利用光腔衰荡法测量吸收系数时,光在吸收介质中的传播速度和空腔是不同的,这种区别导致测量精度在一定程度上受到影响.为了考察吸收系数的测量精度受光速变化的影响程度,进行了相关的分析和推导,并根据实验及部分文献提供的数据进行了数值计算,得到了忽略光速变化将导致测量结果偏小的结论,偏差值与腔镜反射率有关.当腔镜反射率达到99.99%时,就有必要考虑该因素的影响,除非实际测量中存在其它因素使测量精度远不能达到最高值.