高灵敏共振瑞利散射法对痕量药物奥曲肽的测定

采用共振瑞利散射法测定多肽药物奥曲肽.在pH 4.1的B-R缓冲溶液中,奥曲肽和石蕊相互作用后,共振瑞利散射显著增强,在285 ～367 nm范围内呈现高的散射强度,且以310 nm处的ΔIRRS最强.奥曲肽的质量浓度在0.007 3 ～0.45 mg/L范围内与ΔIRRS成正比,检出限(3σ)为2.2 μg/L.该法用于奥曲肽合成样品和注射液中奥曲肽含量的测定,结果满意,实现了以廉价试剂、简便方法快速测定痕量贵重药品的目的.     

基于半导体材料微纳波导全光逻辑门的研究进展

全光逻辑门是全光计算以及全光信号处理系统中关键的光子器件.随着互补金属氧化物半导体(CMOS)工艺的发展,基于半导体材料微纳波导全光逻辑门已经成为集成光学领域中的重要方向;尤其是硅基光子集成器件在近些年成为了国际研究热点.文章主要对基于绝缘体上的硅(SOI)和Ⅲ-Ⅴ族化合物材料不同波导结构（马赫-曾德尔干涉仪(Mach-Zehnder interferometer)微环谐振腔和条形波导结构）的全光逻辑门的研究进展进行了介绍,并且在器件的工作速率和功耗方面,分别对上述基于SOI和Ⅲ-Ⅴ族化合物材料三种不同波导结构的全光逻辑门进行了分析和比较.     

Electron spin resonance investigation of the substitution of Fe3^＋ for Ti4^＋ ions in rutile TiO2 single crystal

A Fe doped rutile TiO 2 single crystal is grown in an O 2 atmosphere by the floating zone technique.Electron spin resonance (ESR) spectra clearly demonstrate that Fe 3+ ions are substituted for the Ti 4+ ions in the rutile TiO 2 matrix.Magnetization measurements reveal that the Fe:TiO 2 crystal shows paramagnetic behaviour in a temperature range from 5 K to 350 K.The Fe 3+ ions possess weak magnetic anisotropy with an easy axis along the c axis.The annealed Fe:TiO 2 crystal shows spin-glass-like behaviours due to the aggregation of the ferromagnetic clusters.     

Spontaneous magnetization and resistivity jumps in bilayered manganite （La0.8Eu0.2）4/3Sr5/3Mn2O7 single crystals

Owing to the inhomogeneous state resulting from the doping of a small number of Eu ions into Laa/3Sr5/3Mn2O7, from the resulting single crystal （La0.8Eu0.2）a/3Sr5/3Mn2O7 we have observed the magnetization jump, the resistivity jump, as well as the relaxation phenomena. For （Lao.sEuo.2）a/3Sr5/3Mn2O7, it has a very delicate ground state due to the interplays among spin, charge, orbital, lattice degrees of freedom. Consequently, the magnetization state is sensitive to temperature, magnetic field, as well as time. Meanwhile, the evolution of the magnetization with time shows a spontaneous jump when both the temperature and the magnetic field are constant. Similar step-like behaviours are also observed in resistivity. All these results suggest that Eu doping can greatly modulate the physical properties of Laa/3Sr5/3Mn2O7 and cause such interesting behaviours.     

La0.67Sr0.33Mn1-xCrO3（0.00≤x≤0.30）的特殊输运行为

研究了La0.67Sr0.33Mn1-xCrO3(0.00≤x≤0.30)体系的M-T曲线、p-T曲线和MR-T曲线。实验结果表明：Cr对Mn位的替代对居里温度Tc影响不明显，但是随着Cr含量的增加，电阻率和磁电阻出现双峰行为，CMR效应的温区被极大地拓宽了。体系的特殊输运行为和异常CMR效应可能是Mn^3 -O-Mn^4 和Mn^3 -O-Cr^3 两种通道共存和竞争的结果。     

微信服务平台的设计及在办公中的应用

由于电脑办公对地点、设备等要求带来的不便,所以对微信办公进行了研究,提出了基于微信公众平台的高校办公流程。采用Linux php mysql作为开发平台,利用微信公众平台开放接口实现整个过程。以校园信息化服务系统为例,阐述了该系统的办公流程、设计方法、核心技术,达到普通用户可通过微信客户端向学校各部门提出建议,管理员通过微信绑定身份后可实现信息分类、回复等办公操作的目的。借助微信公众平台实现智能终端办公,有助于实时交互、提高办公效率、简化办公操作,与此同时,也对此类微信办公开发具有借鉴意义。     

基于能量原理的连续体结构安定分析

基于安定分析的静力定理,建立了一种以结构吸收的塑性能为安定判断准则,应用一种特殊的加载方式求解连续体结构安定问题的数值方法.应用这种能量方法对两个经典安定分析算例进行了计算,与相关结果进行对比表明能量法的有效性和可靠性.该方法摆脱了传统分析方法中的数学规划运算,有较高的求解效率,可方便地应用于实际工程中.     

Magnetocaloric properties and Griffiths phase of ferrimagnetic cobaltite CaBaCo4O7

We present a study on the magnetocaloric properties of a CaBaCo$_{4}$O$_{7}$ polycrystalline cobaltite along with research on the nature of magnetic phase transition. The magnetization as a function of temperature identifies the ferrimagnetic to paramagnetic transition at a Curie temperature of 60 K. Moreover, a Griffiths-like phase is confirmed in a temperature range above $T_{\rm C}$. The compound undergoes a crossover from the first to second-order ferrimagnetic transformation, as evidenced by the Arrott plots, scaling of the universal entropy curve, and field-dependent magnetic entropy change. The maximum of entropy change is 3 J/kg$\cdot$K for $\Delta H = 7$ T at ${T}_{\rm C}$, and a broadening of the entropy peak with increasing magnetic field indicates a field-induced transition above $T_{\rm C}$. The analysis of the magnetic entropy change using the Landau theory reveals the second-order phase transition and indicates that the magnetocaloric properties of CaBaCo$_{4}$O$_{7}$ are dominated by the magnetoelastic coupling and electron interaction. The corresponding values of refrigerant capacity and relative cooling power are estimated to be 33 J/kg and 42 J/kg, respectively.     

Long-distance super-exchange and quantum magnetic relaxation in a hybrid metal–organic framework

The hybrid metal–organic framework [(CH3)2NH2]Fe(HCOO)3with a perovskite-like structure exhibits a variety of unusual magnetic behaviors at low temperatures. While the long-distance super-exchange through the Fe-O–CH-O–Fe exchange path leads to a canted antiferromagnetic ordering at TN～ 19 K, a second transition of magnetic blocking develops at TB～ 9 K. The stair-shaped magnetization hysteresis loops below TBresemble the behaviors of resonant quantum tunneling of magnetization in single-molecular quantum magnets. Moreover, the magnetic relaxation also exhibits several features of resonant quantum relaxation, such as the exponential law with a single characteristic relaxation time, and the nonmonotonic dependence of relaxation rate on the applied magnetic field with a much faster relaxation around the resonant fields. The origin of quantum tunneling behaviors in the [(CH3)2NH2]Fe(HCOO)3metal–organic framework is discussed in terms of magnetic phase separation due to the modification of hydrogen bonding on the long-distance super-exchange interaction.     

Realization of a flux-driven memtranstor at room temperature

The memtranstor has been proposed to be the fourth fundamental circuit memelement in addition to the memristor,memcapacitor, and meminductor. Here, we demonstrate the memtranstor behavior at room temperature in a device made of the magnetoelectric hexaferrite(Ba_(0.5)Sr_(1.5)Co_2Fe_(11) AlO_(22)) where the electric polarization is tunable by external magnetic field. This device shows a nonlinear q–р relationship with a butterfly-shaped hysteresis loop, in agreement with the anticipated memtranstor behavior. The memtranstor, like other memelements, has a great potential in developing more advanced circuit functionalities.