铁基非晶态因瓦合金的声子谱研究

用非弹性中子散射实验方法研究了非晶态Ｆｅ_９０－ｘＣｏ_ｘＺｒ_１０（ｘ＝１０，４０）和Ｆｅ_８０－ｙＣｒ_ｙＰ_１３Ｃ_７（ｙ＝４，８）合金的广义声子谱，在低能区域（?ω≤２０ｍｅＶ）观察到了与因瓦效应相关的声子谱软化现象。初步讨论了这种动力学方面的反常行为。结果表明，声子谱软化可能与在因瓦合金中存在增强的电子－声子相互作用有关。 关键词：     

家蚕脑激素的分离提纯

本文采用八步分离提取法,成功地从2,800,000个家蚕(Bombyx mori)雄蛾头部提取和初步纯化了脑激素——即促前胸腺激素(PTTH),称为“粗制PTTH”.脑激素粗提物约7微克经蓖麻蚕无脑蛹的测试表明具有生物活性.又由100,000个家蚕蛾头分离提取的粗制PTTH,再经过四步凝胶柱层析进一步纯化,结果获得3.4毫克更纯的脑激素(“高纯度PTTH”).用7毫微克高纯度PTTH,即可使去脑蓖麻蚕施发育为成虫.     

微通道流动沸腾气泡受限特性实验研究

本文利用可视化手段实验研究矩形截面微通道(1 mm×0.5 mm)内发生流动沸腾时气泡的生长及受限现象。实验使用去离子水为工质,气泡受限过程由高速CCD相机观察并记录。研究发现,气泡高度方向通道壁面的存在对气泡在该方向的生长产生强烈的限制作用,气泡生长后期顶端气液界面在并未与限制壁面接触时其曲率便明显减小,壁面对气泡生长的限制作用通过其对气泡界面施加一个壁面限制力而体现.通过对比不同运行工况条件下的气泡受限现象,分析讨论了气泡受限过程中其界面形状变化规律及影响因素。     

聚乙二醇双水相萃取光度法测定镍

用水溶性高聚物、表面活性剂及有机物与无机盐形成的双水相体系萃取分离色素、蛋白质及测定金属离子已有报道[1-5].     

Lennard-Jones流体气液相图的粒子交换分子动力学模拟研究

利用粒子交换分子动力学模拟方法(Particle exchange molecular dynamics,PEMD)研究了Lennard-Jones流体的气液相图．模拟中,用两个耦合箱分别代表液相和气相．通过直接比较两箱的粒子化学势来控制交换粒子,从而达到两相平衡．采用Widom方法计算化学势．两模拟箱平衡时具有相同的温度、压强和粒子化学势．模拟的气液相图结果与利用其它方法得到的Lennard-Jones流体气液相图符合得很好．     

BiVO_4/MOF复合材料的合成及其光催化性能

通过简单溶剂热法制备了一种新型复合光催化剂BiVO_4/M IL-53(Fe);运用XRD、SEM/EDS、FT-IR、N_2吸附-脱附和UV-vis DRS等手段对其进行表征,并对其光催化降解RhB活性进行了研究,提出了相应的光催化降解RhB的可能机理。结果表明,相较于单一BiVO_4材料,复合催化剂的比表面积增大,且其光催化效率相较于纯BiVO_4和MIL-53(Fe)也有了较大的提高;其中,BF-2复合材料的光催化活性最高,分别约为纯MIL-53 (Fe)和BiVO_4的5. 2倍和8. 1倍。同时,BiVO_4/MIL-53(Fe)复合光催化剂经过四次循环实验后,仍能保持较稳定的光催化活性和结构。     

Effect of Substrate Bias on Microstructures of Zirconia Thin Films Deposited by Cathodic Vacuum Arc

Zirconium oxide （Zr02） thin films are deposited at room temperature by cathodic arc at substrate biases of 0 V, -60 V and -120 V, respectively. The crystal structure, composition, morphology, and deposition rate of the as-deposited thin films are systematically investigated by x-ray diffraction, x-ray photoelectron spectroscopy （XPS） as well as scanning electron microscopy. The results show that the crystal structure, morphology and deposition rate of the films all are dependant on substrate bias. With the increase of bias voltage from 0 V to -120 V, the zirconium oxide thin film grown on silicon wafer first exhibits monoclinic lattice and tetragonal lattice, further evolves monoclinic phase with the preferred orientation along the （-111） and （-222） directions at -60 V and finally along nearly one observed preferred （002） direction under -120 V. In addition, the variations of morphology with bias voltage are correlated to changes of the film structure. The results of XPS demonstrate that Zr elements are almost oxidized completely in the films achieved under -120 V bias.     

大自然的织锦

从空中俯瞰大地，沙丘和山脊呈现出大尺度的花样结构；观察身边的世界，树叶和花朵大多展现出对称的图案；如果有幸在显微镜下观察世界，微观尺寸的生物和无生命物质会表现出更多令人称奇的形态来。大自然就是这样一幅神奇的织锦，处处透出惊人的美，隐含着深刻的数学和物理。图中所示为韩国济州岛礁石所展现的密堆积图案，     

A cold plasma plume with a highly conductive liquid electrode

A cold dielectric barrier discharge （DBD） plasma plume with one highly conductive liquid electrode has been developed to treat thermally sensitive materials, and its preliminary discharging characteristics have been studied. The averaged electron temperature and density is estimated to be 0.6eV and 1011/cm3, respectively. The length of plasma plume can reach 5cm with helium gas （He）, and the conductivity of the outer electrode affects the plume length obviously. This plasma plume could be touched by bare hand without causing any burning or painful sensation, which may provide potential application for safe aseptic skin care. Moreover, the oxidative particles （e.g., OH, O＊, 03） in the downstream oxygen （02） gas of the plume have been applied to treat the landfill leachate. The results show that the activated 02 gas can degrade the landfill leachate effectively, and the chemical oxygen demand （COD）, conductivity, biochemical oxygen demand （BOD）, and suspended solid （SS） can be decreased by 52%, 57%, 76% and 92%, respectively.     

YBa2Cu3O7-y超导体的50Hz交流损耗研究

利用瓦特计技术,研究了YBa_2Cu_3O_(7-y)烧结样品和粉末熔化法(PMP)织构样品在77K和50Hz交变磁场下的交流(ac)损耗(?)实验结果表明,ac损耗(?)同外磁场振幅H_m之间遵从幂函数规律:(?)∝H_m~n对于YBa_2Cu_3O_(7-y)的烧结样品:(1)当H_m<40Oe时,这样低的磁场已穿透弱连接的晶粒边界网络,导至晶粒间的损耗,(?)∝H_m~(1.6)(2)当40Oe≤H_m<170Oe时,中等磁场破坏了晶粒间的耦合,并且磁通穿进了晶粒内,引起不完全穿透的晶粒内损耗,(? 关键词：