C18-MCM-41复合介孔材料的合成及其在固相微萃取中的应用

以十八烷基三氯硅烷为偶联剂,采用分步合成法合成了烷基官能化的介孔分子筛C18-MCM-41,用元素分析、傅立叶红外光谱(FT-IR)、X射线衍射(XRD)对合成的复合材料进行表征,结果表明,有机官能化后材料仍保持介孔材料的结构特性。以该材料为固相微萃取涂层材料对水中的多环芳烃(萘、蒽、菲)进行了分析,方法的线性范围分别为5.0~250、0.4~300、0.5~400μg/L,检出限分别为5.0、0.10、0.25μg/L,加标回收率在94.3%~104.4%之间,分析结果令人满意,说明C18-MCM-41介孔材料可作为涂层材料用于固相微萃取。     

激发-发射荧光法同时测定大米中多菌灵和西维因残留量

样品经预处理后使用激发-发射荧光光谱仪获取荧光信号。基于交替惩罚三线性分解（APTLD）和自加权交替三线性分解（SWATLD）算法的二阶校正方法,借助显著的“二阶优势”在重叠的光谱信号中准确分辨出多菌灵和西维因的光谱,获得定性定量结果。多菌灵和西维因的回收率分别为97.4%～105.2%和103.0%～106.2%,标准偏差均小于4%,预测均方根误差（RMSEP）在接受范围内。对选择性、灵敏度、检出限、定量限等品质因子进行了计算,并使用椭圆联合置信区（EJCR）进行统计分析,表明该方法可实现大米中多种农药残留同时定量检测。     

深亚微米SRAM质子单粒子翻转实验研究

宇航半导体器件运行在一个复杂的空间辐射环境中,质子是空间辐射环境中粒子的重要组成部分,因而质子在半导体器件中导致的辐射效应一直受到国内外的关注。利用兰州重离子加速器(Heavy Ion Research Facility In Lanzhou) 加速出的H2 分子打靶产生能量为10 MeV 的质子,研究了特征尺寸为0.5/0.35/0.15 μm体硅和绝缘体上硅(SOI) 工艺静态随机存储器(SRAM) 的质子单粒子翻转敏感性,这也是首次在该装置上开展的质子单粒子翻转实验研究。实验结果表明特征尺寸为亚微米的SOI 工艺SRAM器件对质子单粒子翻转不敏感,但随着器件特征尺寸的减小和工作电压的降低,SOI 工艺SRAM器件对质子单粒子翻转越来越敏感;特征尺寸为深亚微米的体硅工艺SRAM器件单粒子翻转截面随入射质子能量变化明显,存在发生翻转的质子能量阈值,CREME-MC模拟结果表明质子在深亚微米的体硅工艺SRAM器件中通过质子核反应导致单粒子翻转。Microelectronic devices are used in a harsh radiation environment for space missions. Among all the reliability issues concerned, proton induced single event upset (SEU) is becoming more and more noticeable for semiconductor components exposed on space. In this work, an experimental research of SEU induced by 10 MeV proton for static random access memory (SRAM) of 0.5, 0.35 and 0.15 m feature size is carried out on HeavyIon Research Facility in Lanzhou for the rst time. The experimental results show that proton induced SEUs in submicron and deep-submicron (SRAMs) are dominated by secondary ions generated by proton nuclear reaction events. The silicon-on-insulator SRAMs characters natural radiation-hardened SEU by proton. For the deep-submicron bulk-silicon technology SRAM, the proton SEU cross section is closely related to the proton energy and there is a threshold energy for the SEU occurrence by proton indirect ionization. CREME-MC simulation indicates that the SEU events in deep-submicron SRAM are induced by the proton nuclear reaction.     

激光辅助照明在电视观瞄具逆光成像上的应用

针对机载光电装备的电视观瞄具对逆光物体进行观瞄时,光亮度剧烈变化,会产生光晕,无法捕获有用细节这一问题,提出利用激光辅助照明成像方案提高物体在激光波段的照度。在观瞄逆光物体时,一方面通过降低相机的曝光时间降低相面照度,另一方面采用激光辅助照明,对逆光物体进行激光照射。通过实验,电视系统能够对激光的照射进行成像,逆光物体的图像边缘灰度差达到55,满足边缘检测的要求,能够分辨物体边缘信息。     

一维非线性周期结构中弹性波传播的辛数学方法

利用辛数学方法分析了质量-弹簧非线性周期结构链中弹性波的传播问题．首先利用能量方法得到频域动力方程,随后通过小量变换将非线性动力方程线性化,得到辛矩阵,进而通过求解辛矩阵的本征值问题来研究波的传播性能．质量-弹簧模型中的弹簧刚度非线性对结构链的传播特性影响很大,研究发现非线性明显改变了周期结构的传播性能,而且不同于线性结构,非线性结构的传播特性与入射波强度有关．数值算例表明随着非线性强度及入射波强度的增大,传播通带宽度逐渐减小,禁带宽度逐渐增大．当入射波强度增大到一定值时,弹性波无法在结构中进行传播．与一般递归方法的比较分析,验证了辛数学方法在非线性周期结构波传播问题中的有效性与优越性．     

Symplectic analysis for wave propagation in one-dimensional nonlinear periodic structures

The wave propagation problem in the nonlinear periodic mass-spring structure chain is analyzed using the symplectic mathematical method. The energy method is used to construct the dynamic equation, and the nonlinear dynamic equation is linearized using the small parameter perturbation method. Eigen-solutions of the symplectic matrix are used to analyze the wave propagation problem in nonlinear periodic lattices. Nonlinearity in the mass-spring chain, arising from the nonlinear spring stiffness effect, has profound effects on the overall transmission of the chain. The wave propagation characteristics are altered due to nonlinearity, and related to the incident wave intensity, which is a genuine nonlinear effect not present in the corresponding linear model. Numerical results show how the increase of nonlinearity or incident wave amplitude leads to closing of transmitting gaps. Comparison with the normal recursive approach shows effectiveness and superiority of the symplectic method for the wave propagation problem in nonlinear periodic structures.     

含碘二氧化硅纳米颗粒对BODIPY染料光动力效果的影响

利用含碘硅烷前体制备包裹BODIPY染料分子的纳米二氧化硅颗粒.颗粒中的碘原子通过重原子效应有效提高了BODIPY染料分子的系间窜越效率,进而提高了染料分子的单重态氧量子产率及光损伤DNA的能力.这一结果表明,含碘二氧化硅纳米颗粒可以成为众多荧光染料分子在光动力疗法领域应用的一个有效药物负载和输送体系.     

The Holevo capacity of a generalized amplitude-damping channel

The Holevo capacity of a generalized amplitude-damping channel is investigated by using a numerical method. It is shown that the Holevo capacity depends on the channel parameters representing the ambient temperature and fidelity. In particular, under a special condition, the Holevo capacity of the generalized amplitude-damping channel can be written as an analytical expression.     

Entanglement-enhanced classical communication through an amplitude-damping channel

We consider the problem of trying to send a single classical bit through an amplitude-damping channel when two transmissions through the channel are available as a resource. It is demonstrated that two entangled transmissions can enhance the receiver's capability of making a correct inference under certain conditions compared with two product-state transmissions.     

多层碳纳米球的研究

用弧光放电法制备了碳的巴基葱.用原子力显微镜（AFM）、扫描隧道显微镜（STM）和透射电镜（TEM）研究了在高定向石墨(HOPG)和金(Au)基底上的巴基葱的行为和电学特性.扫描隧道谱表明,巴基葱的电学特性具有与单壁碳纳米管相似的非线性特性.较小尺寸的巴基葱呈半导体特性,尺寸增大倾向金属线性.AFM/STM图像显示,在HOPG和Au基底上的巴基葱能够聚集成二聚体.利用较小尺寸巴基葱的电学非线性特性,有希望构造纳米电子学的单电子器件.