染料分子吸附在正、负电性纳米银上的荧光增强及荧光猝死现象

制备了两种不同表面电性的胶态纳米银，选取阴离子型染料分子荧光素钠、既有阴离子基团又有阳离子的染料分子罗丹明B，研究其在两种纳米银表面的荧光增强及荧光猝死现象，当罗丹明B（RhB）分子分别吸附在这两种纳米银上时，对负电性纳米银，观察到荧光猝死、荧光峰红移现象，且在分子的浓度适当时，加入KBr可获得较强的表面增强拉曼光谱：在正电性纳米银上，当分子的浓度较大时观察到荧光猝灭，当分子的浓度较小时观察到荧光增强，而当荧光素钠分子（FS）分别吸附在这两种纳米银上时，在负电性纳米银，观察到荧光猝死；在正电性纳米银上观察荧光急剧增强现象，从分子的结构及纳米银表面局域场增强或无辐射通道的增加对增强和猝灭的原因作了讨论。     

Linear Cavity Erbium—Doped Fibre Laser with Tunable Wavelength Range of 112nm

We report on a linear cavity erbium-doped fibre laser with a large tuning range of 1509-1621nm.We obtain a 1dB flat tuning range of 1538-1613 nm and a 3dB tuning range of 1516-1621 nm.The threshold at 1580 nm is 6.1mW,the slope efficiency is 0.193 and the output power is 18.2mW,when 100mW pump power at 1480nm is provided.High signal-to-noise ratios of better than 60 dB are achieved within all the tuning ranges.     

Effect of a Cr Underlayer on the Magnetic Properties of TbCo Amorphous FIlms with Perpendicular Anisotropy

The effect of the Cr underlayer on the magnetic properties of TbCo amorphous films with perpendicular anisotropy has been investigated.It was found that the Cr underlayer thickness can influence the coercivity of TbCo films.A coercivity as high as 6.3kOe was obtained in 120nm Tb31Co69 films with a 180nm Cr underlayer.This was only 4.4kOe for the same thickness Tb31 CO69 films without the Cr underlayer.Cross-sectional scanning electron microscopy indicated that the TbCo film with the Cr underlayer consisted of a Column structure.It is considered that this heterogeneous structure gives rise to the coercity enhancement of TbCo films in the presence of the Cr underlayer.     

Free Field Reciprocity Calibration in a Convergent Spherical Acoustic Wave of a Focusing Transducer

Based on the reciprocity theorem of the acoustic field,we derive the formula of the reciprocity coefficient of a convergent spherical acoustic wave and we calculate a series of diffraction corrective factor curves of the reciprocity coefficient of transducers.Using these formulae and corrective factors,we calibrate the free field transmitting current response and the free field voltage sensitivity of a focusing transducer using the self-reciprocity method.The experimental results of the reciprocity calibration of the focusing transducer in the frequency range of 2MHz to 5.4MHz are presented.     

傅里叶变换轮廓要中频谱泄漏的讨论

讨论了频谱泄漏对傅里叶变换轮廓术测量精度的影响.由于用傅里叶变换轮廓术进行三维面形测量时,测得的变形光场是空间有限函数,故离散傅里叶变换时先要进行周期拓展,如果拓展周期选择不当,拓展后的条纹将不连续,对之进行傅里叶变换会产生频谱泄漏.文章从理论上推导了拓展周期与变形结构光场频谱泄漏之间的关系.给出了由泄漏引起的视场边缘误差的计算模型和定量分析.提出采用条纹外插以减小泄漏误差的方法,计算机模拟及初步实验证实了该方法的有效性.     

大气对流边界层光传输的实验室模拟

利用湍流池模拟大气对流边界层的光传输,同时测量了到达角起伏和光路上的温度脉动。结果表明,在混合层的上部,对数温度谱偏陡,和大气中的观测结果一致,到达角起伏谱也偏陡,但到达角起伏谱曲线反映了湍流在小尺度范围内具有各向同性的特征,此时利用温度脉动方法得到的折射率结构常数小。当边界层顶部逆温层消失,发展为完全对流状态时,温度谱幂率等于“－5／3”,到达角起伏谱害虫率等于“－8／3”,两种方法测量得到的折射率结构常数一致。     

BINARY AND TERNARY ION EXCHANGE KINETICS SO4^2——Cl^——NO3^——201×7SYSTEM

Kinetics of chloride/sulfate,chloride/nitrate and nitrate/sulfate forward exchanges and reverse exchanges at solution concentrations of 1N,0.2N and 0.02 N on 201×7 strong base anion exchange resin,respectively,have been examined at 25℃.It is found that the forward and the reverse exchange rates of the two given ions at low solution concentration,respectively,under identical conditions can be controlled by different mechanisms,while those at high solution concentration are all controlled by particle diffusion.The ternary exchange rates of sulfate/(chloride+nitrate) and nitrate/(chloride+sulfate)have also been examined.     

锗酸盐晶体压致非晶化的研究

高压拉曼散射研究表明．ＣｕＧｅＯ３，Ｌｉ２ＧｅＯ３和Ｌｉ６Ｇｅ２Ｏ７三种晶体分别在７，１２和１１ＧＰａ压力下转变为非晶。在高于起始转变压力以上一定范围压致非晶是可逆的，ＣｕＧｅＯ３，Ｌｉ２ＧｅＯ３和Ｌｉ６Ｇｅ２Ｏ７压致非晶的不可逆转变压力分别为１４．１，２０和２０ＧＰａ。压致非晶ＣｕＧｅＯ３的重新晶化温度在６００℃附近。锗酸及系列晶体的压致非晶化与它们的成份和结构有关，随着在这一系列晶体中Ｌｉ２Ｏ含量的增加，压致非晶化的压力趋于减小。     

火花熔蚀—电感耦合等离子体光谱法分析地质矿物

火花熔蚀－电感耦合等离子体光谱法（SA－ICP）用于测量锆石中铪－锆比值和锰铁矿瘤中的铈、钴、铁、铅、镍和磷。用信背比和信噪比的序贯单纯形优化法建立了用于高压火花和氩气ICP系统的六个操作参数。将磨细的样品与铜压成饼，并从样品中熔蚀出的分析物和基体元素的原子发射信号的时间相关性给出一种用火花来作选择取样的方法。测量锆石中的铪、锆浓度比的精密度为4％（相对标准偏差）。对于锰铁矿瘤，根据分析线对锰（Ⅱ）257.610纳米线强度比的光谱测定结果达到分析精密度范围为7－14％（相标准偏差）。分析的准确度用参比物USGS诺得（Nod)P-1的标准物加入法来决定，而与锰浓度的测量无关。