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91.
92.
Naomichi Furukawa Toshiaki Yoshimura Masami Ohtsu Takeshi Akasaka Shigeru Oae 《Tetrahedron》1980,36(1):73-80
The Michael type additions of diphenyl N-unsubstituted sulfimide (free sulfimide) to various electrophilic olefins were carried out. The reaction with cis- and trans-dibenzoylethylene, dimethyl-fumarate, dimethylmaleate, benzalacetophenone and benzalacetone gave mainly the corresponding trans-2-acylaziridines and trans-enaminoketones. However, phenyl vinyl sulfone or acrylonitrile afforded not the corresponding aziridine but diphenyl-N-2-cyano or N-2-phenylsulfonylethylsulfimide, a simple Michael adduct When optically active (+)-(R)-o-methoxyphenyiphenyl free sulfimide was treated with such an α,β-unsaturated carbonyl compound as benzalacetopbenone, an optically active 2-acylazindine, i.e., (-)-trans-2-benzoyl-3-phenylaziridine was obtained in ca 30% optical purity and its absolute configuration was assigned as (2R,3S) upon chemical transformation to the configuration-ally known 2-phenyl-2-benzoylamino-1-ethanol or by comparing its CD spectrum with that of (1R,2R)-1-phenyl-2-benzoyl-cyclopropane. Meanwhile, (-)-(S)-o-methoxyphenylphenyl free sulfimide was found to react with benzalacetophenone to afford (+)-trans-2-benzoyl-3-phenylaziridine of 25% optical purity. Effects of solvent and temperature on both die distribution of the products ratio and the optical yield were examined. 相似文献
93.
94.
The reaction of singlet oxygen with N-1-(2-alkenylidene)-t- butylamines (
and
) gives the unsaturated hemiperacetal derivatives (
and 4) of the hydroperoxy aldimines (
and
). Several α, β-unsaturated aldimines which are held in the s-trans conformation failed to react with singlet oxygen. 相似文献
95.
96.
Yasuyuki Sanai Yuki Morita Youichi Asano Kenichi Ishizaki Kouzou Kubota 《Journal of polymer science. Part A, Polymer chemistry》2014,52(8):1161-1171
The structural change of the end groups of UV‐cured acrylates with time has been investigated as well as photopolymerization behavior. 2‐Ethylhexyl acrylate, n‐lauryl acrylate, 2‐(2‐ethoxyethoxy)ethyl acrylate, and 2‐ethylhexyl methacrylate were used as a monomer in the current study. In order to mimic industrial conditions, the photopolymerization was conducted with relatively high UV intensity (576 mW/cm2) using a common photoinitiator 1‐hydroxycyclohexyl phenyl ketone. Conversion‐time profile gave a linear first‐order plot suggesting that the steady state was hold throughout the polymerization. Matrix‐assisted laser desorption/ionization time‐of‐flight mass spectra of the resultant polymers indicated the number of the hydroxycyclohexyl chain‐ends decreased with storage time at room temperature. Instead, a lactonic ring appeared to form at the chain‐end by transesterification of the hydroxycyclohexyl group with the ester side chain of the adjacent acrylate according to the results of mass spectrometry and 13C NMR. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1161–1171 相似文献
97.
Flexible transparent fluorinated nanohybrid with innovative heat‐resistance property—new technology proposal for fabrication of transparent materials using “crystalline” polymer
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Muhammad Abdullah Al Mamun Youichi Soutome Qi Meng Atsuhiro Fujimori 《Journal of Polymer Science.Polymer Physics》2015,53(23):1674-1690
A new technology for the production of transparent material, using a “crystalline” polymer, is proposed in this study. In addition, a heat‐resistant transparent flexible plastic film with a high hydrophobic surface and a thermal decomposition temperature near 400 °C was created. Partially fluorinated crystalline polymer with switchboard‐type lamellae results high transparency as a consequence of the formation of a high‐density amorphous structure based on high‐temperature drawing just below the melting point at 250 °C. Melt‐compounding with montmorillonite modified by the long‐chain quaternary phosphonium with high coverage induces formation of a nanohybrid that retains transparency and also results in an increase in the thermal degradation temperature by over 50 °C. Through this technology, which results in heat‐resistance, transparency, and flexibility, the nano‐micro‐millimeter structures of solid‐state polymers are hierarchically controlled, which enables the creation of new materials. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1674–1690 相似文献
98.
99.
100.
Kaho Tanaka Naohiko Akasaka Tomoyuki Kosai Shunya Honda Yuya Ushijima Shintaro Ishida Takeaki Iwamoto 《Molecules (Basel, Switzerland)》2021,26(6)
π-Electron systems of silicon have attracted attention because of their narrow HOMO-LUMO gap and high reactivity, but the structural diversity remains limited. Herein, new dialkylboryl-substituted disilenes were synthesized by the selective desilylation-borylation of the corresponding trimethylsilyl-substituted disilenes. The dialkylboryl-substituted disilenes were fully characterized by a combination of NMR spectroscopy, MS spectrometry, single-crystal X-ray diffraction analysis, and theoretical calculations. The longest-wavelength absorption bands of boryldisilenes were bathochromically shifted compared to the corresponding silyl-substituted disilenes, indicating a substantial conjugation between π(Si=Si) and vacant 2p(B) orbitals. In the presence of 4-(dimethylamino)pyridine (DMAP), the dialkylboryl groups in the boryl-substituted disilenes were easily converted to trimethylsilyl groups, suggesting the dialkylboryl-substituted disilenes in the presence of a base serve as the surrogates of disilenyl anions (disilenides). 相似文献