The quadrupole splitting distributions (QSDs) from the Mössbauer spectra of triphylite, ferrisicklerite and purpurite at 298 K and 80 K were obtained by the use of the Voigt-based quadrupole splitting distribution (QSD) method for the first time. QSDs of Fe2+ and Fe3+ are attributed to Fe2+ and Fe3+ at the corresponding octahedrally coordinated sites in the crystal structures of the three phosphate minerals. The influence on the distortion of the M2 site by different next-nearest neighbor (NNN) configurations was discussed based on the Jahn–Teller effect in purpurite, and the authors propose two M2 subsites with different distortions in purpurite. Two QSDs of Fe3+ in the Mössbauer spectra of purpurite are tentatively assigned to Fe3+ at the two M2 subsites, and next-nearest neighbor (NNN) effects were used to interpret the Mössbauer spectra of purpurite. 相似文献
The review (with 95 refs.) starts with an introduction that addresses the need for magnetic actuation in microfluidics. A second section describes the equations governing magnetic micromixing, with subsections on magnetic equations, fluid flow equations, and on convection–diffusion equations. The next section specifically covers magnetically actuated micromixers, with subsections on those actuated by external permanent magnets, by electromagnets, by microstirrers, and on micromixers with integrated electrodes. The conclusion summarizes the state of the art and addresses current challenges and trends.
Graphical abstract In this review, micromixers are classified into four types according to drive mode including external permanent magnet, electromagnet, microstirrer and the integrated electrode. The basic governing equations and operating rules of magnetic micromixers are given. The review is supposed to provide a helpful reference for those intending to study this field.
A rapid, sensitive, and selective method using a quick, easy, cheap, effective, rugged, and safe procedure in combination with high-performance liquid chromatography and tandem mass spectrometry was developed for the analysis of fenaminstrobin in peanut and soil. The average recoveries in all samples fall within 88.1%–10%, having relative standard deviations of 2.5%–14%. The limits of quantitation of fenaminstrobin in peanut shell, peanut kernels, peanut plant, and soil were 0.005, 0.004, 0.01, and 0.002 mg kg?1, respectively. The field trial results show that the half-lives of fenaminstrobin in peanut plant and soil are 1.3–10 and 5.5–20 days, respectively. Residues in peanut kernels were found to be present at <0.004 mg kg?1 levels, based on good agricultural practices recommended by the manufacturer. The risk posed by fenaminstrobin exposure at the recommended dosage is negligible to humans, depending on the risk quotient. 相似文献
In this paper, the existence of periodic traveling wave solutions with a priori unknown velocity is considered for a coupled map lattice dynamical system. By trasforming our problem into one that involves polynomials, explicit 2- and 3-periodic traveling wave solutions are found, while the other solutions can be computed numerically. Since there does not seem to be any reports on explicit traveling wave solutions, we hope that our results will lead to the discovery of many others. 相似文献
Based on the Independent Continuous Mapping method (ICM), a topological optimization model with continuous topological variables is built by introducing three filter functions for element weight, element allowable stress and element stiffness, which transform the 0-1 type discrete topological variables into continuous topological variables between 0 and 1. Two methods for the filter functions are adopted to avoid the structural singularity and recover falsely deleted elements: the weak material element method and the tiny section element method. Three criteria (no structural singularity, no violated constraints and no change of structural weight) are introduced to judge iteration convergence. These criteria allow finding an appropriate threshold by adjusting a discount factor in the iteration procedure. To improve the efficiency, the original optimization model is transformed into a dual problem according to the dual theory and solved in its dual space. By using MSC/Nastran as the structural solver and MSC/Patran as the developing platform, a topological optimization software of frame structures is accomplished. Numerical examples show that the ICM method is very efficient for the topological optimization of frame structures.The project supported by the National Natural Science Foundation of China (10472003) and Beijing Natural Science Foundation (3042002) The English text was polished by Yunming Chen. 相似文献
<正>Tetracycline selective electrode using molecularly imprinted polymer particles as quasi-ionophore was constructed the first time, and its performance was carefully characterized.Due to the specific recognition of tetracycline by the particles,the selectivity coefficients for routine interferences were less than 10~(-4).Benefited from the absence of tetracycline in the sensitive membrane and the optimized composition of the inner filling solution,the limit of detection of the electrode was reduced to about 2.5×10~(-8) mol/ L.It exhibited a good electrode slope 57.6 mV/decade near the theoretical Nernstian one,with a wide linear working range from 6.0×10~(-8) to 1.0×10~(-3) mol/L.The fabricated electrode should be used in pH 2-4,response time of which was less than 200 s when the concentration of tetracycline was higher than 1.0×10~(-6) mol/L and no more than 30 min at the concentration of 1.0×10~(-8) mol/L. 相似文献
The search for a method to fabricate monolithic inorganic columns has attracted significant recent attention due to their unique ability in separation applications of various biomolecules. Silica and polymer based monolithic columns have been prepared, but titania and other metal oxide monoliths have been elusive, primarily due to their fragility. This article describes a new approach for preparing nanostructured titania based columns, which offer better performance over conventional particle packed columns for separating a wide variety of biomolecules including phosphopeptides. TiO2 monolithic aerogels were synthesized in separation columns using in situ sol‐gel reactions in supercritical carbon dioxide (scCO2) followed by calcination, and compared to those prepared in heptanes. The characterization results show that scCO2 is a better solvent for the sol‐gel reactions, providing lower shrinkage with the anatase TiO2 monolith composed of nanofibers with very high surface areas. The monolithic columns show the ability to isolate phosphopeptides with little flow resistance compared to conventional titania particle based microcolumns. 相似文献
In this paper, we present a new self-adaptive alternating direction method for solving a class of variational inequality problems with both linear equality and inequality constraints without the need to add any extra slack variables. The method is simple because it needs only to perform some projections and function evaluations. In addition, to further enhance its efficiency, we adopt a self-adaptive strategy to adjust parameter μ at each iteration. Convergence of the proposed method is proved under certain conditions. Numerical experience illustrates the efficiency of the new method. 相似文献