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991.
Hao Shen Seungpyo Hong Robert K. Prud’homme Ying Liu 《Journal of nanoparticle research》2011,13(9):4109-4120
We present an experimental study of self-assembled polymeric nanoparticles in the process of flash nanoprecipitation using
a multi-inlet vortex mixer (MIVM). β-Carotene and polyethyleneimine (PEI) are used as a model drug and a macromolecule, respectively, and encapsulated in diblock
copolymers. Flow patterns in the MIVM are microscopically visualized by mixing iron nitrate (Fe(NO3)3) and potassium thiocyanate (KSCN) to precipitate Fe(SCN)
x
(3−x)+. Effects of physical parameters, including Reynolds number, supersaturation rate, interaction force, and drug-loading rate,
on size distribution of the nanoparticle suspensions are investigated. It is critical for the nanoprecipitation process to
have a short mixing time, so that the solvent replacement starts homogeneously in the reactor. The properties of the nanoparticles
depend on the competitive kinetics of polymer aggregation and organic solute nucleation and growth. We report the existence
of a threshold Reynolds number over which nanoparticle sizes become independent of mixing. A similar value of the threshold
Reynolds number is confirmed by independent measurements of particle size, flow-pattern visualization, and our previous numerical
simulation along with experimental study of competitive reactions in the MIVM. 相似文献
992.
Based on the atomic superposition approximation (ATSUP) and first-principles pseudopotential plane-wave methods, the bulk and Mg mono-vacancy positron lifetime of magnesium oxide were calculated using Arponen-Pajamme and Borofiski-Nieminen positron-annihilation-rate interpolation formula respectively. The calculated values are in good agreement with experimental values and the first-principles method gives more convincing results. The positron annihilation density spectra analysis reveals that positrons mainly annihilate with valence electrons of oxygen atoms when the magnesium-vacancy appears within magnesium oxide. 相似文献
993.
The band gap of a photonic crystal (PhC) cavity intrinsically avoids HOM problems. In this paper, we present a new PBG structure based on the possible advantage of using hybrid structures and aperiodic lattices. This novel hybrid and aperiodically ordered cavity was designed for apparently higher Q-factor (more than 10300) and achieving large accelerating field gradient. The HOMs in the cavity are able to be absorbed efficiently. 相似文献
994.
ZHANG Jun JIN YaXin WANG HanBin YE Cong TONG WeiMing & WANG Hao Faculty of Physics Electronic Technology Hubei University Wuhan China 《中国科学:物理学 力学 天文学(英文版)》2011,(7)
Highly textured Ni nanowire arrays were fabricated into anodic aluminum oxide(AAO) templates by pulse DC electrodeposition.The applied voltage and pH value of electrolytes were found strongly affecting the microstructure and magnetic properties of Ni nanowire arrays.Low applied potential and pH value both prefer to form polycrystalline fcc Ni nanowires.Increasing the applied potential or pH value favors the Ni [220] texture and even eventually forms the [220] oriented single crystal Ni wires,while exorbitan... 相似文献
995.
C. Argyropoulos E. Kallos Y. Hao 《Applied Physics A: Materials Science & Processing》2011,103(3):715-719
In this paper, the transient responses of some devices which are based on transformation electromagnetics are studied, such
as invisible cloaks and concentrators, by using the Finite-Difference Time-Domain (FDTD) numerical technique. In particular,
effects of the inherent losses as well as the coating size of the ideal cylindrical cloak on its bandwidth and cloaking performance
are examined. In addition, it is demonstrated that the performance of transformation electromagnetics based devices is affected
by the material parameters in the design, although they may behave nicely under monochromatic plane wave illuminations. The
obtained results are of interest for the future practical implementation of these structures. 相似文献
996.
Compton散射对斜入射激光脉冲在等离子体中传输的影响 总被引:2,自引:1,他引:1
应用多光子非线性Compton散射模型和等效折射指数模型,研究了Compton散射对斜入射激光脉冲在等离子体中传输特性的影响,提出了将入射光和Compton散射光形成的耦合光脉冲作为在等离子体中传输的新机制,用等效耦合折射指数和折射定律分别计算和数值模拟了等离子体中耦合光的反射和折射,结果表明,散射使等离子体中法拉第效应增强,产生了一个与折射界面平行的、较小等幅度附加折射波平面;使等效耦合折射指数的实部和虚部的实参数、折射角和等效折射指数之间的差异明显减小;使用等效耦合折射指数和折射定所得到的反射系数几乎均表现出相同的先增大后迅速减小的规律;使等离子体的反射系数随碰撞频率的增大而迅速减小,透射增强,透射增强的频率位置向高频明显移动。 相似文献
997.
ShaoMin Zhou LiSheng Liu ShiYun Lou YongQiang Wang XiLiang Chen HongLei Yuan YaoMing Hao RuiJian Yuan Ning Li 《Applied Physics A: Materials Science & Processing》2011,102(2):367-371
Large-scale monocrystalline oxide-diluted magnetic semiconductor (ODMS) Zn1−x
Bi
x
O nanorods arrays (NAs) were prepared within a large doping concentration range from 5% to 20% by a simple chemical vapor
deposition. X-ray diffraction and high-resolution transmission electron microscopy reveal the monotonous expansion of the
lattice constants with increasing Bi content, due to the effective Bi doping. In particular, room-temperature ferromagnetic
(RTFM) behavior with Curie temperature over 363.7 K has been observed based on Bi-doped ZnO nanoarrays, whereas undoped ZnO
NAs disappear. The RTFM origin is suggested, in which vacancies can be controlled to tune the FM. The as-formed RTFM NAs would
have potential applications in many areas of advanced nanotechnology, such as new spintronic devices and magneto-optic components. 相似文献
998.
基于抽取和连续投影算法的可见近红外光谱变量筛选 总被引:1,自引:0,他引:1
大多数短波CCD硅检测器为2 048或3 648像元,相邻波长间隔小,预处理算法对其适用性差.本文在600.09~980.47 nm光谱范围内,采用等间隔抽取方法重构光谱矩阵.经不同光谱预处理后,分别采用遗传算法(GA)和连续投影算法(SPA),筛选偏最小二乘法(PLS)建模变量.采用留一法交叉验证评价模型的预测能力,... 相似文献
999.
铕与4-(4-吡啶甲酰基)苯甲酸配合物的合成与荧光性能研究 总被引:2,自引:0,他引:2
以Eu3+为中心离子,4-(4-吡啶甲酰基)苯甲酸(HPFBA)、1,10-菲罗啉(Phen)和三苯基氧膦(TPPO)为配体,合成了新型配合物Eu(PFBA)3(H2O)4,Eu(PFBA)3Phen(H2O)3和Eu(PFBA)3TPPO(H2O)3(PFBA=4-(4-吡啶甲酰基)苯甲酸根).红外光谱表明,形成配合... 相似文献
1000.