漏致势垒降低效应对短沟道应变硅金属氧化物半导体场效应管阈值电压的影响

结合应变硅金属氧化物半导体场效应管(MOSFET)结构,通过求解二维泊松方程,得到了应变Si沟道的电势分布,并据此建立了短沟道应变硅NMOSFET的阈值电压模型.依据计算结果,详细分析了弛豫Si_1－βGe_β中锗组分β、沟道长度、漏电压、衬底掺杂浓度以及沟道掺杂浓度对阈值电压的影响,从而得到漏致势垒降低效应对小尺寸应变硅器件阈值电压的影响,对应变硅器件以及电路的设计具有重要的参考价值. 关键词： 应变硅金属氧化物半导体场效应管 漏致势垒降低 二维泊松方程 阈值电压模型     

热阴极径向温度非均匀性对本征发射度的影响

从热发射理论出发,推导了非均匀发射阴极的均方根本征发射度的一般计算形式。针对一种最常见的温度径向分布近似模型,给出了均方根发射度随温度非均匀性变化趋势的理论数值解。基于有限差分法粒子仿真技术统计了热阴极的本征发射度,仿真结果与理论解一致,验证了非均匀发射热阴极本征均方根发射度一般形式的正确性。结果表明,径向温度非均匀性引起均方根发射度显著变化,非均匀系数为10%时引起均方根发射度下降约15%。本文建立的理论形式和仿真方法可以有效评估束流品质控制目标和工程热设计之间的依赖关系,以指导高效费比的工程设计。     

Surface modification of pitch-based spherical activated carbon by CVD of NH3 to improve its adsorption to uric acid

Surface chemistry of pitch-based spherical activated carbon (PSAC) was modified by chemical vapor deposition of NH₃ (NH₃-CVD) to improve the adsorption properties of uric acid. The texture and surface chemistry of PSAC were studied by N₂ adsorption, pH_PZC (point of zero charge), acid-base titration and X-ray photoelectron spectroscopy (XPS). NH₃-CVD has a limited effect on carbon textural characteristics but it significantly changed the surface chemical properties, resulting in positive effects on uric acid adsorption. After modification by NH₃-CVD, large numbers of nitrogen-containing groups (especially valley-N and center-N) are introduced on the surface of PSAC, which is responsible for the increase of pH_PZC, surface basicity and uric acid adsorption capacity. Pseudo-second-order kinetic model can be used to describe the dynamic adsorption of uric acid on PSAC, and the thermodynamic parameters show that the adsorption of uric acid on PSAC is spontaneous, endothermic and irreversible process in nature.     

微层共挤出(PP+EVOH)/PP阻隔材料的结构与性能研究

利用微层共挤出技术制备了具有交替层状结构的(PP+EVOH)/PP复合材料,其中PP为聚丙烯,EVOH为乙烯-乙烯醇其聚物.通过扫描电子显微镜观察、气体渗透实验、差示扫描量热仪分析以及力学性能测试研究了微层共挤出复合材料的形态结构及其对复合材料气体阻隔性能、力学性能以及结晶性能的影响.研究结果表明,通过微层共挤出技术,PP层和(PP+EVOH)层沿挤出方向交替排列,EVOH在PP基体中的的分散形态由零维球形变为一维纤维状,进而演变为二维片状.这些形态导致微层共挤出材料的氮气渗透系数和断裂伸长率较普通共混物分别下降了两个数量级和提高了27倍,并且显著影响其结晶行为.当层数超过64层后,由于PP层减薄,界面增多,EVOH不仅对(PP+EVOH)层中PP相存在结晶成核作用,而且对PP层也有结晶成核作用.     

Synthesis, properties and electropolymerization of starshaped oligothiophenes with hexakis(fluoren-2-yl)benzene as core

Star-shaped oligothiophenes with hexakis(fluoren-2-yl)benzene (HFB) as cores were designed and synthesized. Grafting thiophene units to HFB results in a bond flattening of the core, and makes the molecules a flipping-twist shape. Their thermal, photophysical and electrochemical properties were studied. Highly cross-linked conjugated polymers can be produced by electropolymerization of T1-T3.     

Adsorption behavior of Pb(II) on montmorillonite

The present work investigated the adsorption and desorption behaviors of Pb(II) on montmorillonite. The adsorption experiments were carried out using batch process. The results show that the adsorption is dependent on the pH value of the medium, and the uptake of Pb(II) increases with the pH increasing in the pH range of 2.0–10.0. The adsorption kinetics is in better agreement with pseudo-second order kinetics, and the adsorption data is a good fit with Langmuir isotherm. The presence of EDTA may result in a decrease of the amount of Pb(II) adsorbed. The presence of electrolyte and EDTA may enhance the desorption of Pb(II) ions adsorbed. The adsorption mechanism of Pb(II) on montmorillonite may be explained in two aspects: the chemical binding between Pb(II) ions and surface hydroxyl groups; and the electrostatic binding between Pb(II) ions and the permanent negatively charged sites of montmorillonite.     

PtRu纳米线的合成及其在直接甲醇燃料电池阳极中的催化活性

 分别以SBA-15和MCM-41介孔分子筛作模板剂,采用浸渍还原法制备了纵横比及合金度不同的双组元PtRu纳米线和纳米棒电催化剂. 透射电镜、 X射线衍射表征和电化学测试结果表明, PtRu纳米线具有较高的合金度和较大的纵横比,在甲醇硫酸溶液中表现出更好的电催化活性. 初步探讨了PtRu纳米线催化剂的合金度和纵横比对其电催化活性和电极性能的影响.     

新型大分子席夫碱配合物的合成和表征

本文用胺基封端聚四氢呋喃(Mn=862)与水杨醛反应，生成新型席夫碱遥爪配体，再与金属离子(Fe³⁺, Co²⁺, Cu²⁺)反应，得到新型大分子席夫碱配合物。用IR、ESR、UV、循环伏安法、拉伸和动态粘弹谱等表征手段对配合物进行了研究。证明所得配合物的配位结构与血红蛋白分子的功能片段的配位结构相似，钴配合物具有与血红蛋白分子相近的可逆化学吸附功能。     

Tetra­aqua(2,2′‐bi­pyridine)­nickel(II) terephthalate

The reaction of nickel(II) nitrate with terephthalic acid and 2,2′‐bi­pyridine in di­methyl­form­amide solution gives the title complex, [Ni(C₁₀H₈N₂)(H₂O)₄](C₈H₄O₄). The Ni^II ion is octahedrally coordinated to one 2,2′‐bi­pyridine and four water mol­ecules and does not coordinate to the terephthalate anion. Hydro­gen bonds between the terephthalate anions and the [Ni(2,2′‐bipy)(H₂O)₄]²⁺ cations produce a two‐dimensional hydrogen‐bonding architecture with double sheets.     

Assembly of MOF Microcapsules with Size‐Selective Permeability on Cell Walls

The assembly of metal–organic frameworks (MOFs) into microcapsules has attracted great interest because of their unique properties. However, it remains a challenge to obtain MOF microcapsules with size selectivity at the molecular scale. In this report, we used cell walls from natural biomaterials as non‐toxic, stable, and inexpensive support materials to assemble MOF/cell wall (CW) microcapsules with size‐selective permeability. By making use of the hollow structure, small pores, and high density of heterogeneous nucleation sites of the cell walls, uniform and continuous MOF layers could be easily obtained by inside/outside interfacial crystallization. The prepared MOF/CW microcapsules have excellent stability and enable the steady, slow, and size‐selective release of small molecules. Moreover, the size selectivity of the microcapsules can be adjusted by changing the type of deposited MOF.