全文获取类型
收费全文 | 25549篇 |
免费 | 4599篇 |
国内免费 | 2805篇 |
专业分类
化学 | 18360篇 |
晶体学 | 286篇 |
力学 | 1405篇 |
综合类 | 161篇 |
数学 | 2901篇 |
物理学 | 9840篇 |
出版年
2024年 | 56篇 |
2023年 | 522篇 |
2022年 | 947篇 |
2021年 | 929篇 |
2020年 | 1034篇 |
2019年 | 1031篇 |
2018年 | 980篇 |
2017年 | 830篇 |
2016年 | 1282篇 |
2015年 | 1206篇 |
2014年 | 1462篇 |
2013年 | 1859篇 |
2012年 | 2345篇 |
2011年 | 2474篇 |
2010年 | 1667篇 |
2009年 | 1499篇 |
2008年 | 1711篇 |
2007年 | 1488篇 |
2006年 | 1369篇 |
2005年 | 1123篇 |
2004年 | 871篇 |
2003年 | 701篇 |
2002年 | 776篇 |
2001年 | 580篇 |
2000年 | 417篇 |
1999年 | 520篇 |
1998年 | 362篇 |
1997年 | 360篇 |
1996年 | 358篇 |
1995年 | 318篇 |
1994年 | 263篇 |
1993年 | 251篇 |
1992年 | 181篇 |
1991年 | 192篇 |
1990年 | 165篇 |
1989年 | 121篇 |
1988年 | 100篇 |
1987年 | 81篇 |
1986年 | 74篇 |
1985年 | 68篇 |
1984年 | 64篇 |
1983年 | 36篇 |
1982年 | 34篇 |
1981年 | 26篇 |
1980年 | 26篇 |
1978年 | 13篇 |
1976年 | 16篇 |
1975年 | 15篇 |
1973年 | 15篇 |
1968年 | 14篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
Yi Jiang Chuan-Lei Jia Xue-Lin Wang Ke-Ming Wang Hong-Ji Ma 《Applied Surface Science》2006,253(5):2674-2677
A planar optical waveguide has been formed in a LiB3O5 crystal using 6.0 MeV Cu+-ions with a dose of 1 × 1015 ions/cm2 at room temperature. Possible propagating modes were measured at a wavelength of 633 nm using the prism-coupling method. The refractive index profiles of the waveguide were reconstructed by an effective refractive index method and the beam propagation method was used to investigate the properties of the propagation modes in the formed waveguide. The results suggest that the fundamental TE0 and TM0 modes may be well-confined and propagate a longer distance inside the waveguide. The implantation process was also simulated using the transport of ions in matter code (TRIM), which indicates that the nuclear energy deposition may be the main factor for the refractive index change. 相似文献
72.
A fluoroionophore sensor, N-[4-(1-pyrene)butyroyl]-L-tryptophan (PLT), has been reported. It can distinguish lead ion from other 12 metal ions via forming a pyrene dimer and it exhibits a very high sensitivity (0.15 microM) in aqueous solution (Chem. Commun., 2006, 2702). When the indole moiety in PLT was changed to benzene, in forming a new fluoroionophore of N-[4-(1-pyrene)butyroyl]-L-phenylalanine (PLP), it could not form a pyrene dimer in response to Pb(2+) in water. The present study describes the spectroscopic clarification of the intrinsic differences of the binding model between PLP and PLT in binding with Pb(2+). The model shows identical chelating bidentate coordination between COO(-) and Pb(2+) both in PLP-Pb and PLT-Pb; however, there is no indication of the interaction between the phenyl ring and the metal ion or the hydrogen bonding between amide groups in PLP-Pb. These differences in the binding model between PLP-Pb and PLT-Pb illustrate that the indole ring in PLT appears to play a crucial role in the high selectivity and sensitivity of PLT to lead(II) ion. 相似文献
73.
The new phenylpropanoid diglycoside ligusinenoside A ( 1 ), and the two new 8,4′‐oxyneolignan(‘8‐O‐4′‐neolignan’) diglycosides ligusinenosides B ( 2 ) and C ( 3 ), together with nine known compounds, were isolated from the rhizomes of Ligusticum sinensis Oliv. The structures of 1 – 3 were elucidated on the basis of spectroscopic analyses. 相似文献
74.
75.
文章详细描述了航空兵机场塔台辅助指挥系统之通信分系统设计的特点与功能、硬件结构、软件设计原则以及接口通信协议等问题。该分系统设计已在航空兵塔台辅助指挥系统研究中得到应用 ,并达到了良好的控制效果。 相似文献
76.
77.
利用离子速度成像方法,研究CH2I2分子在277—305nm范围内若干波长处的光解离动力学.通过同一束激光经(2+1)共振多光子电离(REMPI)过程探测光解碎片I(2P32)和I(2P12),得到了不同激发波长处的离子速度分布图像,从而获得CH2I2光解产物的能量分配和角分布.实验发现,碎片CH2I自由基有很高的内能激发,约占总可资用能的80%,该能量分配可以较好地用冲击模型来解释.实验还发现,产物I(2P32)和I(2P12)具有很不相同的平动能分布,结合所得到的碎片能量分配和角分布,我们对碎片I(2P32)和I(2P12)生成机理进行了分析,指出CH2I2分子电子激发态的绝热和非绝热解离决定了碎片的平动能分布.
关键词:
CH2I2
离子速度成像
绝热和非绝热解离 相似文献
78.
Kai-li Xiang 《计算数学(英文版)》2002,(2)
1. IntroductionWe consider a class of direct hybrid methods proposed in [11 for solving the second orderinitial value problemy" = f(t,y), y(0),y'(0) given (1.1)The basic method has the formandHere t. = nh and we define t.l.. = t. I aih, i = 1, 2 and n=0,1… 相似文献
79.
Qiu Hong WU He Xiang WANG Kun GAO State Key Laboratory of Applied Organic Chemistry College of Chemistry Chemical Engineering Lanzhou University Lanzhou 《中国化学快报》2006,17(2)
Many Ligularia species have long been used as traditional folk medicine for theirantibiotic, antiphlogistic and antitussive activities1, and were found to be an importantsource of eremophilane. In the course of our search for bioactive sesquiterpenoids, w… 相似文献
80.
D. Fong J. H. Hamilton A. V. Ramayya J. K. Hwang C. Goodin K. Li J. Kormicki J. O. Rasmussen Y. X. Luo S. C. Wu I. Y. Lee A. V. Daniel G. M. Ter-Akopian G. S. Popeko A. S. Fomichev A. M. Rodin Yu. Ts. Oganessian M. Jandel J. Kliman L. Krupa J. D. Cole M. A. Stoyer R. Donangelo W. C. Ma 《Physics of Atomic Nuclei》2006,69(7):1161-1167
The hot bimodal fission of 252Cf is reexamined with new high-statistics data. We constructed a γ-γ-γ coincidence cube for binary fission and LCP-gated γ-γ matrix for ternary fission. By identifying the secondary fission fragments from their γ-ray transitions, we measured the yields for various fission splits. The normal neutron yield distribution is found to be
Gaussian for Xe-Ru. However, the binary fission split of Ba-Mo is found to exhibit a bimodal neutron distribution with the
“hot mode” corresponding to ≈3.1% of the total yield. In α ternary fission, the first measurements of yields for specific fission splits are presented. The Te-α-Ru and Xe-α-Mo neutron yields fit well with a single mode, but the Ba-α-Zr split shows evidence for an enhanced hot mode with an intensity of ≈13.8% of the normal mode.
The text was submitted by the authors in English. 相似文献