全文获取类型
收费全文 | 11498篇 |
免费 | 2267篇 |
国内免费 | 3037篇 |
专业分类
化学 | 8604篇 |
晶体学 | 312篇 |
力学 | 795篇 |
综合类 | 326篇 |
数学 | 1506篇 |
物理学 | 5259篇 |
出版年
2024年 | 39篇 |
2023年 | 190篇 |
2022年 | 432篇 |
2021年 | 440篇 |
2020年 | 507篇 |
2019年 | 452篇 |
2018年 | 470篇 |
2017年 | 521篇 |
2016年 | 538篇 |
2015年 | 668篇 |
2014年 | 650篇 |
2013年 | 946篇 |
2012年 | 995篇 |
2011年 | 978篇 |
2010年 | 846篇 |
2009年 | 865篇 |
2008年 | 963篇 |
2007年 | 819篇 |
2006年 | 849篇 |
2005年 | 758篇 |
2004年 | 625篇 |
2003年 | 402篇 |
2002年 | 440篇 |
2001年 | 413篇 |
2000年 | 479篇 |
1999年 | 285篇 |
1998年 | 165篇 |
1997年 | 112篇 |
1996年 | 102篇 |
1995年 | 109篇 |
1994年 | 84篇 |
1993年 | 93篇 |
1992年 | 63篇 |
1991年 | 52篇 |
1990年 | 40篇 |
1989年 | 49篇 |
1988年 | 54篇 |
1987年 | 28篇 |
1986年 | 43篇 |
1985年 | 31篇 |
1984年 | 27篇 |
1983年 | 23篇 |
1982年 | 28篇 |
1981年 | 23篇 |
1980年 | 13篇 |
1979年 | 19篇 |
1978年 | 13篇 |
1977年 | 9篇 |
1976年 | 11篇 |
1974年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
Yue Sun Aidong Xu Kai Wang Xiufang Zhou Haifeng Guo Xiaojia Han 《Entropy (Basel, Switzerland)》2022,24(7)
One of the biggest challenges for the fault diagnosis research of industrial robots is that the normal data is far more than the fault data; that is, the data is imbalanced. The traditional diagnosis approaches of industrial robots are more biased toward the majority categories, which makes the diagnosis accuracy of the minority categories decrease. To solve the imbalanced problem, the traditional algorithm is improved by using cost-sensitive learning, single-class learning and other approaches. However, these algorithms also have a series of problems. For instance, it is difficult to estimate the true misclassification cost, overfitting, and long computation time. Therefore, a fault diagnosis approach for industrial robots, based on the Multiclass Mahalanobis-Taguchi system (MMTS), is proposed in this article. It can be classified the categories by measuring the deviation degree from the sample to the reference space, which is more suitable for classifying imbalanced data. The accuracy, G-mean and F-measure are used to verify the effectiveness of the proposed approach on an industrial robot platform. The experimental results show that the proposed approach’s accuracy, F-measure and G-mean improves by an average of 20.74%, 12.85% and 21.68%, compared with the other five traditional approaches when the imbalance ratio is 9. With the increase in the imbalance ratio, the proposed approach has better stability than the traditional algorithms. 相似文献
32.
XIE Wen-Fang 《理论物理通讯》2006,45(3):535-538
The energy spectrum of the low-lying states of a system of three charged
bosons confined in a two-dimensional harmonic trap is investigated as a
function of the confinement strength
ω0 by means of the exact
diagonalization of the Hamiltonian. The important feature of the low-lying
states of three charged bosons in two-dimensional space is obtained via an
analysis of the energy spectrum. 相似文献
33.
Cross-lingual document retrieval, which aims to take a query in one language to retrieve relevant documents in another, has attracted strong research interest in the last decades. Most studies on this task start with cross-lingual comparisons at the word level and then represent documents via word embeddings, which leads to insufficient structure information. In this work, the cross-lingual comparison at the document level is achieved through the cross-lingual semantic space. Our method, MDL (deep multilabel multilingual document learning), leverages a six-layer fully connected network to project cross-lingual documents into a shared semantic space. The semantic distances can be calculated when the cross-lingual documents are transformed into embeddings in semantic space. The supervision signals are automatically extracted from the data and then used to construct the semantic space via a linear classifier. The ambiguity of manual labels could be avoided and the multilabel supervision signals can be acquired instead of a single label. The representation of the semantic space is enriched by multilabel supervision signals, which improves the discriminative ability of the embeddings. The MDL is easy to extend to other fields since it does not depend on specific data. Furthermore, MDL is more efficient than the models training all languages jointly, since each language is trained individually. Experiments on Wikipedia data showed that the proposed method outperforms the state-of-the-art cross-lingual document retrieval methods. 相似文献
34.
默顿倡导以中层理论为中介来联结社会学的经验研究和一般理论研究,推动社会学理论的合理发展,这一倡导具有合理性。但是默顿试图通过以经验研究为基础优先发展中层理论,然后再通过对中层理论进行归纳来形成一般理论这种经验主义策略进而实现这一目标的想法却可能是错误的。正如中层理论并非从经验事实中归纳得来一样,一般理论也难以从中层理论中归纳而来。我们需要探索一条非经验主义的社会学理论发展道路。 相似文献
35.
SONG Gang ZHANG Kai CHEN YuanYuan LIU HuiLi WU Chao YU Li XIAO JingHua 《中国科学:物理学 力学 天文学(英文版)》2013,(4):680-684
We successfully investigate an optical bistability phenomenon in a layered structure consisting of Kretschmann configuration involving the Kerr-type nonlinear and the silver film. Pure theoretical approaches are employed to investigate that the surface plasmon could easily be coupled and both the reflection and transmission curves versus the incident intensity forms optical bistability. The transmission curves are greatly influenced by the thickness of the second silver film. These results may be useful for designing novel surface plasmon-based optical devices and will be essential for future classical and quantum information processes. 相似文献
36.
De-Yang Zhang Chang-Bin Yu Min-Can Wang Kai Gao Yong-Gui Zhou 《Tetrahedron letters》2012,53(20):2556-2559
A new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep was synthesized from 1-bromo-3-(trifluoromethoxy)benzene in high yield. The key steps included oxidative coupling with anhydrous ferric chloride and optical resolution by (+)-DMTA. The ligand afforded high performance for Ir-catalyzed asymmetric hydrogenation of quinolines with ee up to 92% and TON up to 25,000. It was also successfully applied to the Pd-catalyzed asymmetric hydrogenation of simple indoles with ee up to 87% and Rh-catalyzed asymmetric 1,4-addition of phenylboronic acid to 2-cyclohexenone with 97% ee. 相似文献
37.
Shichang Liu Weiqi Chen Kai Fang Xiangning Jiang Ying Gai 《Rapid communications in mass spectrometry : RCM》2012,26(17):2075-2082
38.
Ling Yang Rong-Zhen Liao Wan-Jian Ding Kai Liu Jian-Guo Yu Ruo-Zhuang Liu 《Theoretical chemistry accounts》2012,131(9):1-12
Mechanisms for the formation of the Schiff base from acetaldehyde and butylamine, glycine and phosphatidylethanolamine based on Dmol3/DFT calculations were realized. For the case of phosphatidylethanolamine, calculations were done under periodic boundary conditions, in an amine-phospholipid monolayer model with two molecules of phosphatidylethanolamine by cell. All models contained explicit aqueous solvent. In the three cases, a neutral amino group is used to model the nucleophilic attack on the carbonyl group of acetaldehyde, and water molecules form hydrogen bond networks. These networks were involved in the reactions by performing as proton-transfer carriers, important in some steps of reactions, and stabilizing reaction intermediates. In all the studied reactions, they take place in two steps, namely: (1) formation of a carbinolamine and (2) its dehydration to the Schiff base, being the dehydration the rate-determining step of the process, consistent with available experimental evidence for similar reactions. The main difference between the studied reactions is found in the value for relative free energy for the intermediates and transition states in the second step; these values are lower in the cases of glycine and phosphatidylethanolamine in comparison with butylamine, due the influence of their molecular environments. Based on the results, the aminophospholipid surface environment and carboxylic group of glycine may boost Schiff base formation via a neighboring catalyst effect. 相似文献
39.
40.
In this paper we show analyticaliy that,in general,nematic liquid crystals (NLC) with curvature strain belong to the C1[1] point group.However,NLC with simple splay deformation or simple bend deformation possess C2V[mm2] symmetry and those with simple twist deformation possess D2[222] symnetry. 相似文献