Biomimetic chemistry of xylomollin

Kingiside aglucon ($\text{2}$$\text{b}$) undergoes stereoselective addition of CH₃OH to its C(3,4) enol ether double bond to give a C(1,3,9) diastereomer of xylomollin ($\text{1}$), a secoiridoid aglucon that has insect antifeedant properties.     

Instrumental neutron activation analysis of Elbe river suspended particulate matter separated according to the settling velocities

Suspended particulate matter in Elbe river water near Hamburg has been separated into different fractions by pouring the samples into special sedimentation tubes called Atterberg cylinders. The fractions are obtained by decanting the water after different settling periods, and by filtrating the decanted part. The analysis is done by neutron activation in the absolute mode, after irradiation periods of 5 min and 3 days. Mean settling velocities of the SPM-mass and the elements determined have been calculated.     

ANOXIC PHOTODAMAGE IN THE PRESENCE OF PORPHYRINS: EVIDENCE FOR THE LACK OF EFFECTS ON MITOCHONDRIAL MEMBRANES

Abstract When isolated mitochondria are irradiated in the presence of 50 μg/ml hematoporphyrin or hematoporphyrin derivative in the respiratory medium, the irradiation is at least twenty-fold less effective in impairing the Ca²⁺ pump in the absence of oxygen than in its presence. This result suggests that photosensitization by non oxygen-depending pathways has few or no effects on cell membranes, a result somewhat at variance with those observed with liposomes.     

Disposable sodium electrodes

In this paper we describe a disposable sodium sensor in double matrix membrane technology. This sensor is prepared from filter paper with an evaporated silver conducting line on one side. For insulation the sensor is laminated with a pre-perforated heat-sealing film. A defined volume of an ion-sensitive polymer matrix membrane cocktail is filled into one hole. So an ion-sensitive coated film sensor in double matrix membrane technology is produced. The double matrix membrane is formed by the polymer matrix membrane and by the additional filter paper matrix. The response behaviour of the sodium electrode is comparable with conventional macro ion-selective electrodes. By this technology a mass production of low cost sensors is possible.     

Correlation between transport and equilibrium properties through the ternary interaction parameter for cosolvent and cononsolvent polymeric systems

A study of the ternary polymer systems dimethyl formamide-ethyl acetate-polystyrene, chloroform-1,4 dioxane-polystyrene and tetrahydrofuran-chloroform-polystyrene was carried out by viscosity and light scattering at 298 K. A good correlation has been found between the excess intrinsic viscosity, unperturbed polymer dimensions, second virial coefficient and the excess Gibbs free energy by using a ternary interaction parameter, dependent on molecular weight. This modification enables the conversion between transport and equilibrium properties.     

Polyhydroxylated nortropanes starting from D-glucose: Synthesis of homochiral (+) and (−)-calystegines B2

The cycloheptano-isoxazoline 1, prepared from D-glucose, is converted to 6,7-dideoxy cycloheptitols which are suitable precursors for the synthesis of enantiomerically pure (+) and (−)-Calystegines B₂.     

Lineare Oligopeptide. 29. Mitt. IR-Konformations-Analyse von Homo-Oligopeptiden im Festzustand und in Lösung

Ohne Zusammenfassung     

Thallium-205, carbon-13 and proton NMR parameters for some monomethylthallium(III) derivatives

Thallium-205, carbon-13 and proton NMR spectra have been determined for some monomethylthallium(III) derivatives CH₃TlX₂ (X  anion) permitting comparison of NMR parameters in the series CH₃TlX₂, (CH₃)₂TlX, (CH₃)₃Tl.     

Synthesis and Conformational Behavior of Rhodium(I) Metallohosts Derived from Diphenylglycoluril

The design and synthesis of molecules containing both a substrate-binding cavity and a nearby catalytically active metal center is a useful approach to the development of synthetic systems that function according to the principles of enzymes. To this end the receptor molecule 2a, derived from diphenylglycoluril, was functionalized with triaryl phosphite ligands to give the receptor ligand 2d. Exchange reactions of 2d with (diketonate)Rh(CO)(2), (diketone = acetylacetone, dibenzoylmethane, or dipivaloylmethane) led to the formation of the metallohosts 3a-c, respectively. The properties and conformational behavior of these metal complexes were studied by NMR techniques. Reaction of compounds 3 with H(2) in the presence of a small excess of additional triphenyl phosphite yields the rhodium(I) hydride complex 5. The metallohosts are capable of binding dihydroxybenzene guests in their cavities by hydrogen bonding and pi-pi stacking interactions. On binding a substrate the conformational behavior of hosts 3a-c was affected considerably.