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81.
82.
Time-discretization scheme for quasi-static Maxwell's equations with a non-linear boundary condition
We study a time dependent eddy current equation for the magnetic field H accompanied with a non-linear degenerate boundary condition (BC), which is a generalization of the classical Silver–Müller condition for a non-perfect conductor. More exactly, the relation between the normal components of electrical E and magnetic H fields obeys the following power law ν×E=ν×(|H×ν|α-1H×ν) for some α∈(0,1]. We establish the existence and uniqueness of a weak solution in a suitable function space under the minimal regularity assumptions on the boundary Γ and the initial data H0. We design a non-linear time discrete approximation scheme based on Rothe's method and prove convergence of the approximations to a weak solution. We also derive the error estimates for the time-discretization. 相似文献
83.
Peter Segl’a Jozef Miklovič Dušan Mikloš Ján Titiš Radovan Herchel Ján Moncol Barbora Kaliňáková Daniela Hudecová Viera Mrázová Tadeusz Lis Milan Melník 《Transition Metal Chemistry》2008,33(8):967-974
Synthesis and characterization of 10 new 2-methylthionicotinate (2-MeSnic) Co(II) complexes, namely, [Co(2-MeSnic)2L2(H2O)2] · nH2O (L is N,N-diethylnicotinamide—Et2nia, ethylnicotinate—Etnic, nicotinamide—nia, isonicotinamide—isonia, N-methylnicotinamide—N-Menia, furo[3,2-c]pyridine—fpy, 2,3-dimethylfuro[3,2-c]pyridine—Me2fpy or benzo[4,5]furo[3,2-c]pyridine—Bfp; n is 0, 1 or 2) as well as [Co(2-MeSnic)2L2] (L is ronicol—ron or 2-methylfuro[3,2-c]pyridine—Mefpy), are reported. The characterizations were based on physico-chemical
and spectroscopic methods. The crystal structure of one of the complexes has been determined. In the molecular complex [Co(2-MeSnic)2(Me2fpy)2(H2O)2], the Co(II) central atom, located at a symmetry centre, is octahedrally coordinated by an oxygen atom of the unidentate
2-MeSnic carboxyl group, the nitrogen atom of the pyridine ring of Me2fpy, a water molecule and the corresponding centrosymmetrically located atoms. Also, biological activity of the complexes
against various strains of bacteria and filamentous fungi has been investigated. It is concluded that by complexation of these
nicotinate derivatives their biological activities are elevated.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
84.
Baran EJ Viera I Torre MH 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,66(1):114-117
The infrared and Raman spectra of the copper(II) complexes [Cu(L-asn)2] and [Cu(L-gln)2] (L-asn=L-asparagine; L-gln=L-glutamine), were recorded and analyzed in relation to its structural peculiarities. Some comparisons between the spectra of these complexes and with those of related systems are made. The characteristics of the carboxylate and amide groups of the bonded ligands are discussed in detail. 相似文献
85.
Ignacio Viera Eduardo Manta Lucía González Graciela Mahler 《Tetrahedron: Asymmetry》2010,21(5):631-635
Novel α,α-disubstituted epoxy esters were prepared in enantiopure form by hydrolytic kinetic resolution (HKR) of the corresponding racemic mixtures using chiral salenCo(III) as catalyst. The methodology provides a convenient route to enantioenriched β,γ-epoxy esters 2a, 2c and 2d. 相似文献
86.
Electrical and dielectric properties, and ionic transport numbers of “pure” and rare earth elements doped Bi5.8PO11.2(BPO), and Bi4Ge3O12(BGO) crystals are studied. Anisotropy of electrical properties in BPO is examined. Relations between the structure, physical
properties, and transport mechanisms in BPO and BGO are discussed.
Published in Russian in Elektrokhimiya, 2009, Vol. 45, No. 6, pp. 687–692.
The article is published in the original.
Published by report at IX Conference “Fundamental Problems of Solid State Ionics”, Chernogolovka, 2008. 相似文献
87.
Peter Segl’a Jozef Miklovič Dušan Mikloš Viera Mrázová Lenka Krupková Daniela Hudecová Zuzana Ondrušová Jozef Švorec Ján Moncol Milan Melník 《Transition Metal Chemistry》2009,34(1):15-22
The synthesis and characterization of six new 2-methylthionicotinate (2-MeSnic) copper(II) monomeric complexes [Cu(2-MeSnic)2L2] (L is furo[3,2-c]pyridine—fpy, 2-methylfuro[3,2-c]pyridine—Mefpy, 2,3-dimethylfuro[3,2-c]pyridine—Me2fpy or benzo[4,5]furo[3,2-c]pyridine—Bfp), [Cu(2-MeSnic)2(fpy)2(H2O)], as well as [Cu(2-MeSnic)2(CF3Phfpy)2(H2O)2] (CF3Phfpy is 2-(3-trifluoromethylphenyl)furo[3,2-c]pyridine) are reported. The characterizations were based on elemental analysis,
infrared, electronic and EPR spectra. The crystal structure of one of the complexes has been determined. The CuII atoms of [Cu(2-MeSnic)2(fpy)2(H2O)] are six-coordinated in a highly distorted tetragonal–bipyramidal arrangement by two nitrogen atoms, one from each fpy,
in trans-positions, by three oxygen atoms of the carboxyl groups of 2-MeSnic ligands (one monodentate, one asymmetrically bidentate),
one axial position being occupied by the oxygen of a water molecule. The antimicrobial effects have been tested on various
strains of bacteria, yeasts and filamentous fungi. A comparison of the IC50 and MIC values has shown a decrease of inhibition activities of tested compounds in the order: [Cu(2-MeSnic)2(Bfp)2] > Bfp > [Cu(2-MeSnic)2(CF3Phfpy)2(H2O)2] > [Cu(2-MeSnic)2(Me2fpy)2] > CF3Phfpy > [Cu(2-MeSnic)2(Mefpy)2] > Me2fpy > [Cu(2-MeSnic)2(fpy)2(H2O)] > [Cu(2-MeSnic)2(H2O)]2 > Mefpy > fpy = 2-MeSnicH = CuSO4.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
88.
Viera Zemanová Marián Slodi?ka 《Journal of Computational and Applied Mathematics》2010,234(7):2062-2068
We study a recovery problem for an unknown boundary data at the boundary part in static electromagnetism. Our computational area is a bounded domain Ω⊂Rn with a Lipschitz continuous boundary. The problem for determining the coefficient λ is considered. This coefficient represents one of the ferromagnetic material characteristics occupying this domain. The existence and uniqueness of a weak solution are proved and a numerical method for its recovery is supported by numerical experiments. 相似文献
89.
Vladimir Labaš Marcel Poulain Marian Kubliha Stanislav Minárik Salem Chaguetmi Jozef Psota Viera Trnovcová 《Journal of Non》2011,357(11-13):2371-2374
Glass samples have been prepared in the NaPO3–KHSO4 binary system with the classical melting, casting and annealing steps. Electrical and dielectrical properties of glass samples were studied. Measurements of DC and AC conductivity and complex electrical permittivity of xNaPO3–(100 ? x)KHSO4 glass system were carried out at temperatures ranging from room temperature to temperature located 15 °C below glass transition temperature Tg. Results showed that changes of NaPO3 concentration considerably affect values of observed parameters. DC conductivity of glass increases as NaPO3 concentration grows until concentration x = 60. However, beyond this value a sharp decrease of DC conductivity was observed. In addition relaxation times showed abrupt changes at concentration x = 60, corresponding to the lowest relaxation times at the temperature 90 °C. 相似文献
90.
Viera Suchá Michal Sivák Peter Schwendt 《Monatshefte für Chemie / Chemical Monthly》1993,124(8-9):809-814
Summary From the reaction systems,B-V2O5-HClO4-H2O andB-V2O5-H2O, whereB is benzylamine (Bz), imidazole (Im) or pyridine (Py), eight new compounds were synthesized: at 20°C, the metavanadate and decavanadates of composition (BzH)VO3, (BzH)6V10O28·3H2O, (ImH)6V10O28·2H2O, (PyH)6V10O28·2H2O, (ImH)4H2V10O28·2H2O and (PyH)4H2V10O28·3H2O, and at 60°C, the hexavanadates of composition (ImH)2V6O16·H2O and (PyH)2V6O16·H2O. ThepH ranges of solutions the polyvanadates can be isolated from, were estimated. The compounds prepared were characterized by chemical analysis and IR spectroscopy. The synthesis of deuterated analogues allowed to assign the IR bands corresponding to vibrations of water in the spectra of deca- and dihydrogendecavanadates and to V-OH vibrations in the spectra of dihydrogendecavanadates.
Benzylammonium-, Imidazolium- und Pyridinium-Polyvanadate. Synthese und Charakterisierung
Zusammenfassung Aus dem ReaktionssystemB-V2O5-HClO4-H2O undB-V2O5-H2O [B=Benzylamin (Bz), Imidazol (Im) oder Pyridin (Py)] wurden acht neue Verbindungen synthetisiert: bei 20°C entstanden die Metavanadate und Decavanadate der Zusammensetzung (BzH)VO3, (BzH)6V10O28·3H2O, (ImH)6V10O28·2H2O, (PyH)6V10O28·2H2O, (ImH)4H2V10O28·2H2O und (PyH)4H2V10O28·3H2O, bei 60°C entstanden die Hexavanadate (ImH)2V6O16·H2O und (PyH)2V6O16·H2O. DiepH-Bereiche, innerhalb derer Polyvanadate isoliert werden können, wurden abgeschätzt. Die Verbindungen wurden mittels chemischer Analyse und IR-Spektroskopie charakterisiert, wobei die Synthese deuterierter Analoga die Zuordnung von Banden unterstützte.相似文献